Spontaneous and Directional Transportation of Gas Bubbles on Superhydrophobic Cones

Understanding the behavior of gas bubbles in aqueous media and realizing their spontaneous and directional manipulation are of vital importance in both scientific research and industrial applications, owing to their significant influences on many processes, such as waste water treatment, gas evolution reactions, and the recovery of valuable minerals. However, the behaviors of gas bubbles in aqueous media are mainly dominated by the buoyant force, which greatly impedes gas bubble transportation to any other direction except upward. Consequently, the spontaneous and directional transportation of gas bubbles in aqueous media is still identified as a big issue. Here, superhydrophobic copper cones have been successfully fabricated by integrating low‐surface‐tension chemical coatings with conical morphology. The generated superhydrophobic copper cones are capable of transporting gas bubbles from their tip to the base spontaneously and directionally underwater, even when they are vertically fixed with tips pointing up. The present study will inspire people to develop novel strategies to achieve efficient manipulation of gas bubbles in practical applications.

[1]  Lei Jiang,et al.  Under-water unidirectional air penetration via a Janus mesh. , 2015, Chemical communications.

[2]  Jingming Wang,et al.  Bioinspired Gas Bubble Spontaneous and Directional Transportation Effects in an Aqueous Medium , 2015, Advanced materials.

[3]  Lei Jiang,et al.  Under‐Water Superaerophobic Pine‐Shaped Pt Nanoarray Electrode for Ultrahigh‐Performance Hydrogen Evolution , 2015 .

[4]  Lei Jiang,et al.  Cactus Stem Inspired Cone‐Arrayed Surfaces for Efficient Fog Collection , 2014 .

[5]  D. Chan,et al.  Probing the Hydrophobic Interaction between Air Bubbles and Partially Hydrophobic Surfaces Using Atomic Force Microscopy , 2014 .

[6]  Kim Lefmann,et al.  Visualisation by high resolution synchrotron X-ray phase contrast micro-tomography of gas films on submerged superhydrophobic leaves. , 2014, Journal of structural biology.

[7]  C. Fairfield Cavitation damage to potential sewer and drain pipe materials , 2014 .

[8]  Matteo Giacopini,et al.  Numerical investigation of the cavitation damage in the wet cylinder liner of a high performance motorbike engine , 2014 .

[9]  Lei Jiang,et al.  Facile and Large‐Scale Fabrication of a Cactus‐Inspired Continuous Fog Collector , 2014 .

[10]  Lei Jiang,et al.  Bioinspired Conical Copper Wire with Gradient Wettability for Continuous and Efficient Fog Collection , 2013, Advanced materials.

[11]  Lei Jiang,et al.  Manipulating and dispensing micro/nanoliter droplets by superhydrophobic needle nozzles. , 2013, ACS nano.

[12]  Lin Feng,et al.  Structured cone arrays for continuous and effective collection of micron-sized oil droplets from water , 2013, Nature Communications.

[13]  G. M. Lazzerini,et al.  Large Work Function Shift of Gold Induced by a Novel Perfluorinated Azobenzene‐Based Self‐Assembled Monolayer , 2013, Advanced materials.

[14]  Lei Jiang,et al.  A multi-structural and multi-functional integrated fog collection system in cactus , 2012, Nature Communications.

[15]  Raymond R Dagastine,et al.  Repulsive van der Waals forces in soft matter: why bubbles do not stick to walls. , 2011, Physical review letters.

[16]  G. Evans,et al.  Hydrogen bubble flotation of silica , 2010 .

[17]  W. Barthlott,et al.  The Salvinia Paradox: Superhydrophobic Surfaces with Hydrophilic Pins for Air Retention Under Water , 2010, Advanced materials.

[18]  S. Oshita,et al.  Evidence of the existence and the stability of nano-bubbles in water , 2010 .

[19]  Jin Zhai,et al.  Directional water collection on wetted spider silk , 2010, Nature.

[20]  Lei Jiang,et al.  Air bubble bursting effect of lotus leaf. , 2009, Langmuir : the ACS journal of surfaces and colloids.

[21]  M. Toprak,et al.  Nature‐Inspired Boiling Enhancement by Novel Nanostructured Macroporous Surfaces , 2008 .

[22]  Feng-Ming Chang,et al.  Tiny bubble removal by gas flow through porous superhydrophobic surfaces: Ostwald ripening , 2008 .

[23]  D. Fornasiero,et al.  The terminal rise velocity of 10-100 microm diameter bubbles in water. , 2008, Journal of colloid and interface science.

[24]  Lei Jiang,et al.  Dual‐Responsive Surfaces That Switch between Superhydrophilicity and Superhydrophobicity , 2006 .

[25]  D. Quéré,et al.  Drops on a conical wire , 2004, Journal of Fluid Mechanics.

[26]  Z.L. Wang,et al.  Single‐Crystalline Scroll‐Type Nanotube Arrays of Copper Hydroxide Synthesized at Room Temperature , 2003 .

[27]  H. Ødegaard The use of dissolved air flotation in municipal wastewater treatment. , 2001, Water science and technology : a journal of the International Association on Water Pollution Research.

[28]  M. P. Schwarz,et al.  CDF simulation of bubble-particle collisions in mineral flotation cells , 2000 .

[29]  N. Ishida,et al.  Nano Bubbles on a Hydrophobic Surface in Water Observed by Tapping-Mode Atomic Force Microscopy , 2000 .

[30]  Masanobu Sakamoto,et al.  Attraction between hydrophobic surfaces with and without gas phase , 2000 .

[31]  W. Lauterborn,et al.  Cavitation erosion by single laser-produced bubbles , 1998, Journal of Fluid Mechanics.

[32]  Muluneh Yitayew,et al.  Low-head bubbler irrigation systems. Part II. Air lock problems , 1995 .

[33]  George M. Whitesides,et al.  Comparison of the Structures and Wetting Properties of Self-Assembled Monolayers of n- Alkanethiols on the Coinage Metal Surfaces, Cu, Ag, Au' , 1991 .

[34]  J. Dukovic,et al.  The Influence of Attached Bubbles on Potential Drop and Current Distribution at Gas‐Evolving Electrodes , 1987 .

[35]  Joseph T. Fuss,et al.  Design and application of vacuum degassers , 1986 .

[36]  Yonghao Zhang,et al.  Microdroplet Technology: Principles and Emerging Applications in Biology and Chemistry , 2012 .

[37]  J. C. Schouten,et al.  Pressure drop of gas–liquid Taylor flow in round micro-capillaries for low to intermediate Reynolds numbers , 2009 .