Study of the pixel-pitch reduction for HgCdTe infrared dual-band detectors

The third generation of HgCdTe infrared-detector focal-plane arrays (FPAs) should be able to detect simultaneously in two spectral bands. The feasibility of this type of dual-band detectors has already been shown in our laboratory with a pixel size of 50 µm in the 3–5-µm wavelength range. To improve the detector resolution, it is necessary to decrease the pixel pitch. Dry etching is a key process technology to fulfill this goal because of the high aspect-ratio structures needed (typically 10–15-µm deep and 2–5-µm wide trenches). In this paper, we present results of a parametric study on HgCdTe dry etching, as well as results obtained on detector arrays made with the dry-etching technique. The etching study has been done in a microwave plasma reactor with the aim of controlling the surface roughness, the etch rate, and the slope of the trench side. We show how these parameters are influenced by the reactive gas-mixture composition (based on CH4, H2, and Ar) and the substrate self-bias. We show how polymer film deposition can prevent etching from occurring but can improve anisotropy. We show some examples of results obtained when manufacturing the trenches that separate the pixels, keeping a high fill factor, and anisotropic etching. We also show results of the material surface characterizations done with scanning electron microscopy (SEM) and Hall effect measurements. These studies allow us to evaluate and compare the damages done to the HgCdTe surface with different etching conditions. Our best process allows us to make a light electrical damage, confined to less than a micron deep in the material. Using the dry-etching process, we have developed detector arrays fabricated with a pixel pitch as low as 30 µm. We finally present the results of the first electrical characterizations made on these arrays, showing promising results for the development of high-resolution dual-band detectors.

[1]  G. Destefanis,et al.  Electrical doping of HgCdTe by ion implantation and heat treatment , 1988 .

[2]  H. Wilson,et al.  Stoichiometric dry etching of mercury cadmium telluride using a secondary afterglow reactor , 1989 .

[3]  P. Leech,et al.  Novel CH4/H2 metalorganic reactive ion etching of Hg1−xCdxTe , 1991 .

[4]  J. Elkind,et al.  Reactive ion etching of HgCdTe with methane and hydrogen , 1992 .

[5]  Jan Franc,et al.  Deep p-n junction in Hg1-xCdxTe created by ion milling , 1993 .

[6]  E. Dobisz,et al.  Electron cyclotron resonance reactive ion etching of fine features in HgxCd1−xTe using CH4/H2 plasmas , 1993 .

[7]  M. Seelmann-Eggebert,et al.  Reaction chemistry and resulting surface structure of HgCdTe etched in CH4/H2 and H2 ECR plasmas , 1995 .

[8]  M. Seelmann-Eggebert,et al.  Dry etching of Hg1−xCdxTe using CH4/H2/Ar/N2 electron cyclotron resonance plasmas , 1996 .

[9]  A. Tóth,et al.  Type conversion of p-(HgCd)Te using and Ar reactive ion etching , 1996 .

[10]  Pradip Mitra,et al.  Simultaneous MW/LW dual-band MOVPE HgCdTe 64x64 FPAs , 1998, Defense, Security, and Sensing.

[11]  E. A. Patten,et al.  Molecular beam epitaxial growth and performance of HgCdTe-based simultaneous-mode two-color detectors , 1998 .

[12]  C. Eddy,et al.  Plasma etch-induced conduction changes in gallium nitride , 1999 .

[13]  Jean-Paul Chamonal,et al.  Single- and two-color infrared focal plane arrays made by MBE in HgCdTe , 2000, SPIE Optics + Photonics.

[14]  B. Nener,et al.  HgCdTe photovoltaic detectors fabricated using a new junction formation technology , 2000 .

[15]  Michael A. Kinch HDVIP FPA technology at DRS Infrared Technologies , 2001, SPIE Defense + Commercial Sensing.

[16]  M. Zandian,et al.  A novel simultaneous unipolar multispectral integrated technology approach for HgCdTe IR detectors and focal plane arrays , 2001 .

[17]  Pierre Castelein,et al.  Recent development in infrared FPAs with multispectral 1282 IRCMOS , 2002, SPIE OPTO.

[18]  Small two-dimensional arrays of mid-wavelength infrared HgCdTe diodes fabricated by reactive ion etching-induced p-to-n-type conversion , 2003 .

[19]  William A. Radford,et al.  The effect of electron cyclotron resonance plasma parameters on the aspect ratio of trenches in HgCdTe , 2003 .