Hall effect mobility of epitaxial graphene grown on silicon carbide

Epitaxial graphene (EG) films were grown in vacuo by silicon sublimation from the (0001) and (0001¯) faces of 4H-SiC and 6H-SiC. Hall effect mobilities and sheet carrier densities of the films were measured at 300 and 77 K and the data depended on the growth face. About 40% of the samples exhibited holes as the dominant carrier, independent of face. Generally, mobilities increased with decreasing carrier density, independent of carrier type and substrate polytype. The contributions of scattering mechanisms to the conductivities of the films are discussed. The results suggest that for near-intrinsic carrier densities at 300 K epitaxial graphene mobilities will be ∼150 000 cm2 V−1 s−1 on the (0001¯) face and ∼5800 cm2 V−1 s−1 on the (0001) face.

[1]  T. Geballe,et al.  Hall Effect and Conductivity of InSb , 1955 .

[2]  D. Kranzer Mobility of holes of zinc-blende III–V and II–VI compounds , 1974 .

[3]  Friedrich Schäffler,et al.  High-mobility Si and Ge structures , 1997 .

[4]  C. Berger,et al.  Ultrathin epitaxial graphite: 2D electron gas properties and a route toward graphene-based nanoelectronics. , 2004, cond-mat/0410240.

[5]  C. Berger,et al.  Electronic Confinement and Coherence in Patterned Epitaxial Graphene , 2006, Science.

[6]  T. Ando Screening Effect and Impurity Scattering in Monolayer Graphene(Condensed matter: electronic structure and electrical, magnetic, and optical properties) , 2006 .

[7]  C. Berger,et al.  Highly ordered graphene for two dimensional electronics , 2006 .

[8]  M. Katsnelson,et al.  Electron scattering on microscopic corrugations in graphene , 2007, Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences.

[9]  K. Lew,et al.  Etching of 4° and 8° 4H-SiC Using Various Hydrogen-Propane Mixtures in a Commercial Hot-Wall CVD Reactor , 2007 .

[10]  W. K. Chan,et al.  Field effect in epitaxial graphene on a silicon carbide substrate , 2007 .

[11]  C. Berger,et al.  Magnetotransport in high mobility epitaxial graphene , 2007 .

[12]  S. Sarma,et al.  A self-consistent theory for graphene transport , 2007, Proceedings of the National Academy of Sciences.

[13]  Andre K. Geim,et al.  The rise of graphene. , 2007, Nature materials.

[14]  C. Berger,et al.  Weak antilocalization in epitaxial graphene: evidence for chiral electrons. , 2006, Physical review letters.

[15]  D. Jena,et al.  Carrier statistics and quantum capacitance of graphene sheets and ribbons , 2007, 0707.2242.

[16]  E. Williams,et al.  Atomic structure of graphene on SiO2. , 2007, Nano letters.

[17]  S. Xiao,et al.  Intrinsic and extrinsic performance limits of graphene devices on SiO2. , 2007, Nature nanotechnology.

[18]  E. Williams,et al.  Charged Impurity Scattering in Graphene , 2007, 0708.2408.

[19]  C. Berger,et al.  Approaching the dirac point in high-mobility multilayer epitaxial graphene. , 2008, Physical review letters.

[20]  Ralf Graupner,et al.  Raman spectra of epitaxial graphene on SiC(0001) , 2008 .

[21]  P. D. Ye,et al.  Top-gated graphene field-effect-transistors formed by decomposition of SiC , 2008, 0802.4103.

[22]  G. Fudenberg,et al.  Ultrahigh electron mobility in suspended graphene , 2008, 0802.2389.

[23]  Michael G. Spencer,et al.  Measurement of Ultrafast Carrier Dynamics in Epitaxial Graphene , 2007, 0712.0119.

[24]  P. Kim,et al.  Temperature-dependent transport in suspended graphene. , 2008, Physical review letters.

[25]  C. Keast,et al.  Epitaxial Graphene Transistors on SiC Substrates , 2008, IEEE Transactions on Electron Devices.

[26]  H. B. Weber,et al.  Towards wafer-size graphene layers by atmospheric pressure graphitization of silicon carbide. , 2009, Nature materials.

[27]  Charles R. Eddy,et al.  Graphene Formation on SiC Substrates , 2009 .

[28]  D. Kurt Gaskill,et al.  Comparison of epitaxial graphene on Si-face and C-face 4H SiC formed by ultrahigh vacuum and RF furnace production. , 2009, Nano letters.