Thermal Willis Coupling in Spatiotemporal Diffusive Metamaterials.

Willis coupling generically stems from bianisotropy or chirality in wave systems. Nevertheless, those schemes are naturally unavailable in diffusion systems described by a single constitutive relation governed by the Fourier law. Here, we report spatiotemporal diffusive metamaterials by modulating thermal conductivity and mass density in heat transfer. The Fourier law should be modified after homogenizing spatiotemporal parameters, featuring thermal Willis coupling between heat flux and temperature change rate. Thermal Willis coupling drives asymmetric heat diffusion, and the diffusion direction is reversible at a critical point determined by the degree of spatiotemporal modulation. Moreover, thermal Willis coupling stands robustly even when only thermal conductivity is modulated. These results may have potential applications for directional diffusion and offer insights into asymmetric manipulation of nonequilibrium mass and energy transfer.