Loading of exponentially grown LBL films with silver nanoparticles and their application to generalized SERS detection.

Feature film: Thin films made by exponential layer-by-layer growth display high diffusivity and can be readily infiltrated with inorganic nanoparticles. They can sequestrate molecular systems from solution as a function of the composition of their layers, while providing intense surface-enhanced Raman scattering (SERS) signals (see picture).

[1]  T. Hasegawa Structural analysis of biological aliphatic compounds using surface-enhanced Fourier transform Raman spectroscopy. , 2004, Biopolymers.

[2]  Hyunhyub Ko,et al.  Nanostructured surfaces and assemblies as SERS media. , 2008, Small.

[3]  R. Álvarez-Puebla,et al.  Synthesis of silver nanoparticles with controllable surface charge and their application to surface-enhanced Raman scattering. , 2009, Analytical chemistry.

[4]  Martin Moskovits,et al.  Surface-enhanced Raman spectroscopy for DNA detection by nanoparticle assembly onto smooth metal films. , 2007, Journal of the American Chemical Society.

[5]  C. Domingo,et al.  Functionalization of Ag nanoparticles with dithiocarbamate calix[4]arene as an effective supramolecular host for the surface-enhanced Raman scattering detection of polycyclic aromatic hydrocarbons. , 2006, Langmuir : the ACS journal of surfaces and colloids.

[6]  S. Hays,et al.  Dioxin risks in perspective: past, present, and future. , 2003, Regulatory toxicology and pharmacology : RTP.

[7]  Catherine Picart,et al.  Buildup Mechanism for Poly(l-lysine)/Hyaluronic Acid Films onto a Solid Surface , 2001 .

[8]  C. Domingo,et al.  Sensing polycyclic aromatic hydrocarbons with dithiocarbamate-functionalized ag nanoparticles by surface-enhanced Raman scattering. , 2009, Analytical chemistry.

[9]  M. Steigerwald,et al.  Photovoltage mechanism for room light conversion of citrate stabilized silver nanocrystal seeds to large nanoprisms. , 2008, Journal of the American Chemical Society.

[10]  L. Liz‐Marzán,et al.  Bifunctional Nanocomposites with Long-Term Stability as SERS Optical Accumulators for Ultrasensitive Analysis , 2009 .

[11]  Logan K. Ausman,et al.  Methods for describing the electromagnetic properties of silver and gold nanoparticles. , 2008, Accounts of chemical research.

[12]  Martin Moskovits,et al.  Surface-Enhanced Raman Spectroscopy and Nanogeometry: The Plasmonic Origin of SERS , 2007 .

[13]  K. Kavanagh,et al.  A new generation of sensors based on extraordinary optical transmission. , 2008, Accounts of chemical research.

[14]  C Zocchetti,et al.  Health effects of dioxin exposure: a 20-year mortality study. , 2001, American journal of epidemiology.

[15]  Paula T Hammond,et al.  Exponential growth of LBL films with incorporated inorganic sheets. , 2008, Nano letters.

[16]  P. Etchegoin,et al.  An analytic model for the optical properties of gold. , 2006, The Journal of chemical physics.

[17]  T. Laurence,et al.  Rapid, solution-based characterization of optimized SERS nanoparticle substrates. , 2009, Journal of the American Chemical Society.

[18]  Katrin Kneipp,et al.  Surface-enhanced Raman scattering , 2006 .

[19]  C. Schmuck,et al.  Direct and label-free detection of solid-phase-bound compounds by using surface-enhanced Raman scattering microspectroscopy. , 2007, Angewandte Chemie.

[20]  M. Moskovits Surface-enhanced spectroscopy , 1985 .

[21]  J. Zhao,et al.  Controlled plasmonic nanostructures for surface-enhanced spectroscopy and sensing. , 2008, Accounts of chemical research.

[22]  Ronald A. Hites,et al.  Is Combustion the Major Source of Polychlorinated Dibenzo-p-dioxins and Dibenzofurans to the Environment? A Mass Balance Investigation , 2000 .

[23]  De‐Yin Wu,et al.  Chemical enhancement effects in SERS spectra: A quantum chemical study of pyridine interacting with copper, silver, gold and platinum metals , 2008 .

[24]  Yiping Zhao,et al.  Novel nanostructures for SERS biosensing , 2008 .

[25]  N. Shah,et al.  Surface-enhanced Raman spectroscopy. , 2008, Annual review of analytical chemistry.

[26]  J. Whitlock,et al.  Mechanistic aspects of dioxin action. , 1993, Chemical research in toxicology.

[27]  Henry Du,et al.  Substrates with discretely immobilized silver nanoparticles for ultrasensitive detection of anions in water using surface-enhanced Raman scattering. , 2008, Langmuir : the ACS journal of surfaces and colloids.

[28]  M. van den Berg,et al.  The toxicokinetics and metabolism of polychlorinated dibenzo-p-dioxins (PCDDs) and dibenzofurans (PCDFs) and their relevance for toxicity. , 1994, Critical reviews in toxicology.

[29]  Luis M Liz-Marzán,et al.  Au@pNIPAM colloids as molecular traps for surface-enhanced, spectroscopic, ultra-sensitive analysis. , 2009, Angewandte Chemie.

[30]  Jürgen Popp,et al.  SERS: a versatile tool in chemical and biochemical diagnostics , 2008, Analytical and bioanalytical chemistry.

[31]  L. Liz‐Marzán,et al.  Formation of Silver Nanoprisms with Surface Plasmons at Communication Wavelengths , 2006 .

[32]  K. Kneipp,et al.  SERS--a single-molecule and nanoscale tool for bioanalytics. , 2008, Chemical Society reviews.

[33]  A. Kraus,et al.  Reductive dehalogenation of chlorinated dioxins by an anaerobic bacterium , 2003, Nature.

[34]  H. Tokiwa,et al.  Structure, Energy, Vibrational Frequencies, and Potential Energy Curve of 2,3,7,8-Tetrachlorinated Dibenzo-p-dioxin: Ab Initio MO Studies , 1996 .

[35]  M. Kogevinas,et al.  Cancer mortality in workers exposed to phenoxy herbicides, chlorophenols, and dioxins. An expanded and updated international cohort study. , 1997, American journal of epidemiology.

[36]  Luis M Liz-Marzán,et al.  Design of SERS-encoded, submicron, hollow particles through confined growth of encapsulated metal nanoparticles. , 2009, Journal of the American Chemical Society.

[37]  R. Álvarez-Puebla,et al.  Role of nanoparticle surface charge in surface-enhanced Raman scattering. , 2005, The journal of physical chemistry. B.

[38]  Pablo G. Etchegoin,et al.  Surface Enhanced Raman Scattering Enhancement Factors: A Comprehensive Study , 2007 .

[39]  C. Nakamura,et al.  Simple and high-sensitivity detection of dioxin using dioxin-binding pentapeptide. , 2007, Biosensors & bioelectronics.

[40]  George C Schatz,et al.  TDDFT studies of absorption and SERS spectra of pyridine interacting with Au20. , 2006, The journal of physical chemistry. A.

[41]  R. V. Van Duyne,et al.  Probing the structure of single-molecule surface-enhanced Raman scattering hot spots. , 2008, Journal of the American Chemical Society.

[42]  N. Kotov,et al.  Reversible loading and unloading of nanoparticles in "exponentially" growing polyelectrolyte LBL films. , 2008, Journal of the American Chemical Society.

[43]  C. Mirkin,et al.  Mechanistic study of photomediated triangular silver nanoprism growth. , 2008, Journal of the American Chemical Society.

[44]  C. Domingo,et al.  Nanosensors based on viologen functionalized silver nanoparticles: few molecules surface-enhanced Raman spectroscopy detection of polycyclic aromatic hydrocarbons in interparticle hot spots. , 2009, Analytical chemistry.

[45]  L. Brus Noble metal nanocrystals: plasmon electron transfer photochemistry and single-molecule Raman spectroscopy. , 2008, Accounts of chemical research.

[46]  R. Álvarez-Puebla,et al.  Surface-enhanced Raman scattering for ultrasensitive chemical analysis of 1 and 2-naphthalenethiols. , 2004, The Analyst.

[47]  C. Schmuck,et al.  Direkte und markierungsfreie Detektion von festphasengebundenen Substanzen durch oberflächenverstärkte Raman‐Streuung , 2007 .

[48]  H. Fenniri,et al.  Synthesis and SERS Properties of Nanocrystalline Gold Octahedra Generated from Thermal Decomposition of HAuCl4 in Block Copolymers , 2006 .

[49]  Gero Decher,et al.  Fuzzy Nanoassemblies: Toward Layered Polymeric Multicomposites , 1997 .

[50]  Mathieu Kociak,et al.  Zeptomol detection through controlled ultrasensitive surface-enhanced Raman scattering. , 2009, Journal of the American Chemical Society.

[51]  Martin Moskovits,et al.  Free-surface microfluidic control of surface-enhanced Raman spectroscopy for the optimized detection of airborne molecules , 2007, Proceedings of the National Academy of Sciences.

[52]  Deirdre M. Ledwith,et al.  Optical Properties and Growth Aspects of Silver Nanoprisms Produced by a Highly Reproducible and Rapid Synthesis at Room Temperature , 2008 .