Interacting metal and ligand based open shell systems: Challenges for experiment and theory
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[1] Jean-Pierre Launay,et al. Electrons in Molecules , 2018, Oxford Scholarship Online.
[2] W. Kaim,et al. Isomeric Diruthenium Complexes of a Heterocyclic and Quinonoid Bridging Ligand: Valence and Spin Alternatives for the Metal/Ligand/Metal Arrangement. , 2016, Inorganic chemistry.
[3] W. Kaim. Electron Transfer Reactivity of Organometallic Compounds Involving Radical-Forming Noninnocent Ligands , 2016 .
[4] M. Mondal,et al. An unprecedented one-step synthesis of octahedral Cu(ii)-bis(iminoquinone) complexes and their reactivity with NaBH4. , 2016, Dalton transactions.
[5] C. Mukherjee,et al. Secondary Interactions versus Intramolecular π–π Interactions in CuII–Diradical Complexes , 2016 .
[6] F. Lloret,et al. Nickel(II) Complex of a Hexadentate Ligand with Two o-Iminosemiquinonato(1-) π-Radical Units and Its Monocation and Dication. , 2016, Inorganic chemistry.
[7] Mei Wang,et al. Structural and Spectroscopic Characterization of Rhenium Complexes Containing Neutral, Monoanionic, and Dianionic Ligands of 2,2'-Bipyridines and 2,2':6,2″-Terpyridines: An Experimental and Density Functional Theory (DFT)-Computational Study. , 2016, Inorganic chemistry.
[8] A. Lough,et al. Structure, magnetic properties and electronic structure of a nickel(II) complex with redox-active 6-(8-quinolylamino)-2,4-bis(tert-butyl)phenol , 2016 .
[9] M. Siegler,et al. Metal-Metal Interactions in Heterobimetallic Complexes with Dinucleating Redox-Active Ligands. , 2016, Angewandte Chemie.
[10] W. Kaim,et al. Electronic, charge and magnetic interactions in three-centre systems , 2015 .
[11] M. Kaupp,et al. Quantum-chemical insights into mixed-valence systems: within and beyond the Robin-Day scheme. , 2014, Chemical Society reviews.
[12] W. Kaim,et al. Structure and Spectroelectrochemical Response of Arene–Ruthenium and Arene–Osmium Complexes with Potentially Hemilabile Noninnocent Ligands , 2014 .
[13] W. Kaim,et al. Correlated coordination and redox activity of a hemilabile noninnocent ligand in nickel complexes. , 2014, Chemistry.
[14] D. D’Alessandro,et al. Radicals in metal–organic frameworks , 2014 .
[15] Soumava Biswas,et al. Effect of ligand substituent coordination on the geometry and the electronic structure of Cu(II)-diradical complexes. , 2014, Inorganic chemistry.
[16] C. Philouze,et al. Unprecedented redox-driven ligand ejection in nickel(II)-diiminosemiquinonate radical complexes. , 2014, Chemical communications.
[17] A. Lever,et al. Binuclear ruthenium complexes of a neutral radical bridging ligand. A new "spin" on mixed valency. , 2013, Inorganic chemistry.
[18] R. Crabtree,et al. Redox-active ligands in catalysis. , 2013, Chemical Society reviews.
[19] Vijayendran K. K. Praneeth,et al. Redoxaktive Liganden in der Katalyse , 2012 .
[20] V. Praneeth,et al. Redox-active ligands in catalysis. , 2012, Angewandte Chemie.
[21] K. Wieghardt,et al. Electronic Structures of the Electron Transfer Series [M(bpy)3]n, [M(tpy)2]n, and [Fe(tbpy)3]n (M = Fe, Ru; n = 3+, 2+, 1+, 0, 1–): A Mössbauer Spectroscopic and DFT Study , 2012 .
[22] W. Kaim,et al. Metal(IV) Complexes [M(LN,O,S)2]n (M = Ru, Os) of a Redox‐Active o‐Amidophenolate Ligand (LN,O,S)2– with Coordinating Thioether Appendix , 2012 .
[23] S. Mobin,et al. Correspondence of Ru(III) Ru(II) and Ru(IV) Ru(III) mixed valent states in a small dinuclear complex. , 2012, Chemistry.
[24] J. Autschbach. Perspective: relativistic effects. , 2012, The Journal of chemical physics.
[25] Bas de Bruin,et al. Redox Non-Innocent Ligands: Versatile New Tools to Control Catalytic Reactions , 2012 .
[26] Seth N. Brown. Metrical oxidation states of 2-amidophenoxide and catecholate ligands: structural signatures of metal-ligand π bonding in potentially noninnocent ligands. , 2012, Inorganic chemistry.
[27] Alexander Heckmann,et al. Organische gemischtvalente Verbindungen: ein Spielplatz für Elektronen und Löcher , 2012 .
[28] C. Lambert,et al. Organic mixed-valence compounds: a playground for electrons and holes. , 2012, Angewandte Chemie.
[29] W. Kaim. Concepts for metal complex chromophores absorbing in the near infrared , 2011 .
[30] Richard Eisenberg,et al. Noninnocence in metal complexes: a dithiolene dawn. , 2011, Inorganic chemistry.
[31] Tetsuya Shimizu,et al. Spin-crossover in cobalt(II) compounds containing terpyridine and its derivatives , 2011 .
[32] J. Long,et al. A N2(3-) radical-bridged terbium complex exhibiting magnetic hysteresis at 14 K. , 2011, Journal of the American Chemical Society.
[33] W. Kaim,et al. Manifestations of noninnocent ligand behavior. , 2011, Inorganic chemistry.
[34] L. Bogani,et al. Cobalt complexes with "Click"-derived functional tripodal ligands: spin crossover and coordination ambivalence. , 2011, Inorganic chemistry.
[35] Wojciech I Dzik,et al. Open-shell organometallics: reactivity at the ligand , 2011 .
[36] O. Wenger,et al. Organic mixed valence. , 2011, Chemical reviews.
[37] W. Kaim,et al. Reversible Intramolecular Single-Electron Oxidative Addition Involving a Hemilabile Noninnocent Ligand , 2011 .
[38] W. Kaim,et al. Quantum chemical interpretation of redox properties of ruthenium complexes with vinyl and TCNX type non-innocent ligands , 2010 .
[39] A. Lever. Electronic characteristics of an extensive series of ruthenium complexes with the non-innocent o-benzoquinonediimine ligand: A pedagogical approach , 2010 .
[40] W. Kaim,et al. Non-innocent ligands in bioinorganic chemistry—An overview , 2010 .
[41] Scott R. Wilson,et al. Oxidation of Dihydrogen by Iridium Complexes of Redox-Active Ligands , 2010 .
[42] W. Kaim,et al. Spectroelectrochemistry: the best of two worlds. , 2009, Chemical Society reviews.
[43] A. Poddel’sky,et al. Transition metal complexes with bulky 4,6-di-tert-butyl-N-aryl(alkyl)-o-iminobenzoquinonato ligands: Structure, EPR and magnetism , 2009 .
[44] Joel S. Miller,et al. Oxidation leading to reduction: redox-induced electron transfer (RIET). , 2009, Angewandte Chemie.
[45] Joel S. Miller,et al. Oxidation führt zu Reduktion – redoxinduzierter Elektronentransfer (RIET) , 2009 .
[46] T. Weyhermüller,et al. Targeted oxidase reactivity with a new redox-active ligand incorporating N2O2 donor atoms. Complexes of Cu(II), Ni(II), Pd(II), Fe(III), and V(V). , 2008, Inorganic chemistry.
[47] W. Kaim,et al. Stabilizing the elusive ortho-quinone/copper(I) oxidation state combination through pi/pi interaction in an isolated complex. , 2008, Journal of the American Chemical Society.
[48] A. Lever,et al. Spectroscopic, electrochemical, and computational aspects of the charge distribution in Ru(acac)2(R-o-benzoquinonediimine) complexes. , 2008, Inorganic chemistry.
[49] Abhishek Dey,et al. Mixed valent sites in biological electron transfer. , 2008, Chemical Society reviews.
[50] R. B. Sunoj,et al. Mixed-valent metals bridged by a radical ligand: fact or fiction based on structure-oxidation state correlations. , 2008, Journal of the American Chemical Society.
[51] T. Rauchfuss,et al. Redox-switched oxidation of dihydrogen using a non-innocent ligand. , 2008, Journal of the American Chemical Society.
[52] Javier J. Concepcion,et al. Observation of three intervalence-transfer bands for a class II-III mixed-valence complex of ruthenium. , 2008, Angewandte Chemie.
[53] C. Creutz,et al. Mixed Valence Complexes of d5‐d6 Metal Centers , 2007 .
[54] W. Kaim,et al. Unkonventionelle gemischtvalente Komplexe des Rutheniums und Osmiums , 2007 .
[55] W. Kaim,et al. Unconventional mixed-valent complexes of ruthenium and osmium. , 2007, Angewandte Chemie.
[56] W. Kaim,et al. Mixed valency in ruthenium complexes—Coordinative aspects , 2007 .
[57] R. B. Sunoj,et al. Theoretical and experimental evidence for a new kind of spin-coupled singlet species: isomeric mixed-valent complexes bridged by a radical anion ligand. , 2005, Angewandte Chemie.
[58] W. Kaim,et al. Theoretische und experimentelle Hinweise auf einen neuen Typ spingekoppelter Singulett‐Spezies: isomere gemischtvalente Komplexe mit verbrückendem Radikalanion‐Liganden , 2005 .
[59] M. Kaupp,et al. Where is the spin? Understanding electronic structure and g-tensors for ruthenium complexes with redox-active quinonoid ligands. , 2005, Journal of the American Chemical Society.
[60] T. Schleid,et al. Dreispinsystem mit neuer Wendung: ein Bis(semichinonato)kupfer‐Komplex mit nichtplanarer Konfiguration am Kupfer(II)‐Zentrum , 2005 .
[61] W. Kaim,et al. Three-spin system with a twist: a bis(semiquinonato)copper complex with a nonplanar configuration at the copper(II) center. , 2005, Angewandte Chemie.
[62] C. Sangregorio,et al. Quinonoid metal complexes: toward molecular switches. , 2004, Accounts of chemical research.
[63] W. Kaim,et al. First crystal structure determination and high-frequency EPR study of an organoarsanecopper radical complex , 2003 .
[64] F. Neese,et al. Analysis and interpretation of metal-radical coupling in a series of square planar nickel complexes: correlated Ab initio and density functional investigation of [Ni(L(ISQ))(2)] (L(ISQ)=3,5-di-tert-butyl-o-diiminobenzosemiquinonate(1-)). , 2003, Journal of the American Chemical Society.
[65] W. Kaim. The chemistry and biochemistry of the copper–radical interaction , 2003 .
[66] W. Kaim,et al. Synthesis and Spectroelectrochemical Characterization of a Novel Oxalate-Bridged Binuclear Ruthenium(III) Complex , 2003 .
[67] C. Su,et al. Long-range electronic coupling in various oxidation states of a C4-linked tris(beta-diketonato)ruthenium dimer. , 2003, Angewandte Chemie.
[68] W. Kaim,et al. Weitreichende elektronische Kopplung in unterschiedlichen Oxidationszuständen eines C4‐verknüpften Tris(β‐diketonato)ruthenium‐Dimers , 2003 .
[69] F. Basuli,et al. Structural systematics for o-C(6)H(4)XY ligands with X,Y= O, NH, and S donor atoms. o-iminoquinone and o-iminothioquinone complexes of ruthenium and osmium. , 2002, Inorganic chemistry.
[70] W. Kaim. The coordination chemistry of 1,2,4,5-tetrazines , 2002 .
[71] A. Lever,et al. Ruthenium d-orbital delocalization in bis(bipyridine)ruthenium derivatives of redox active quinonoid ligands , 2002 .
[72] F. Neese,et al. Theoretical evidence for the singlet diradical character of square planar nickel complexes containing two o-semiquinonato type ligands. , 2002, Inorganic chemistry.
[73] W. Kaim. Complexes with 2,2â²-azobispyridine and related 'S-frame' bridging ligands containing the azo function , 2001 .
[74] T. Meyer,et al. The localized-to-delocalized transition in mixed-valence chemistry. , 2001, Chemical reviews.
[75] C. Pierpont. Studies on charge distribution and valence tautomerism in transition metal complexes of catecholate and semiquinonate ligands , 2001 .
[76] K. Wieghardt,et al. Electronic structure of bis(o-iminobenzosemiquinonato)metal complexes (Cu, Ni, Pd). The art of establishing physical oxidation states in transition-metal complexes containing radical ligands. , 2001, Journal of the American Chemical Society.
[77] Fr'ed'eric Naud,et al. Hemilability of Hybrid Ligands and the Coordination Chemistry of Oxazoline-Based Systems. , 2001, Angewandte Chemie.
[78] P. Braunstein,et al. Hemilabilität von Hybridliganden und die Koordinationschemie von Oxazolinliganden , 2001 .
[79] A. Lever,et al. Comparison of o-benzoquinonediimine with bipyridine and bipyrazine in electronic coupling to ruthenium(II), as a function of spectator ligand , 2000 .
[80] W. Kaim,et al. Exploration of mixed-valence chemistry: inventing new analogues of the Creutz-Taube ion. , 2000, Accounts of chemical research.
[81] W. Kaim,et al. The valence-localized decacyanodiruthenium(III,II) analogue of the Creutz–Taube ion. Completing the full d5/d6 triad [(NC)5M(μ-pz)M(CN)5]5−, M=Fe,Ru,Os; pz=pyrazine , 2000 .
[82] M. Albrecht,et al. Sensitive Valence Tautomer Equilibrium of Paramagnetic Complexes [(L)Cun+(Qn−)] (n=1 or 2; Q=Quinones) Related to Amine Oxidase Enzymes , 1999 .
[83] W. Kaim,et al. Coordination compounds of pteridine, alloxazine and flavin ligands: structures and properties , 1999 .
[84] A. Lever,et al. TRENDS IN METAL-LIGAND ORBITAL MIXING IN GENERIC SERIES OF RUTHENIUM N-DONOR LIGAND COMPLEXES : EFFECT ON ELECTRONIC SPECTRA AND REDOX PROPERTIES , 1998 .
[85] M. Ward. Metal-metal interactions in binuclear complexes exhibiting mixed valency; molecular wires and switches , 1995 .
[86] W. Kaim,et al. When Is an Odd-Electron Dinuclear Complex a Mixed-Valent Species? Tuning of Ligand-to-Metal Spin Shifts in Diruthenium(III,II) Complexes of Noninnocent Bridging Ligands OC(R)NNC(R)O , 1995 .
[87] A. Lever,et al. The ground and excited state electronic structures of ruthenium quinones and related species , 1993 .
[88] W. Kaim,et al. Spectroscopy of mixed valent states in dinuclear ions and metalloproteins , 1993 .
[89] A. Lever,et al. Substituent Effects and Bonding Characteristics in o- Benzoquinonediiminebis(bipyrdine) Ruthenium(II) Complexes , 1993 .
[90] A. Lever,et al. The Control of Orbital Mixing in Ruthenium Complexes Containing Quinone Related Ligands , 1991 .
[91] P. Knowles,et al. A Cu(I)-semiquinone state in substrate-reduced amine oxidases , 1991, Nature.
[92] W. Kaim,et al. Stability rules for d5/d6 mixed-valent dimers. Effects from the donor/acceptor capability of the metal (ruthenium vs osmium) and from the occupancy of the mediating ligand orbital (LUMO vs HOMO) , 1990 .
[93] A. Dei,et al. Dinuclear ruthenium complexes with bridging 1,4,5,8-tetraoxonaphthalene : redox properties and mixed-valence interactions , 1990 .
[94] S. Ernst,et al. Energy level tailoring in ruthenium(II) polyazine complexes based on calculated and experimental ligand properties , 1989 .
[95] S. Ernst,et al. Stable binuclear o- and p-semiquinone complexes of [Ru(bpy)2]2+. Radical ion versus mixed-valence dimer formulation , 1989 .
[96] A. Lever,et al. Bis(dioxolene)(bipyridine)ruthenium redox series , 1988 .
[97] W. Kaim. The transition metal coordination chemistry of anion radicals , 1987 .
[98] A. Lever,et al. Catechol-quinone redox series involving bis(bipyridine)ruthenium(II) and tetrakis(pyridine)ruthenium(II) , 1986 .
[99] D. Richardson,et al. Mixed-valence molecules: Electronic delocalization and stabilization , 1984 .
[100] J. Ammeter,et al. The Creutz-Taube complex revisited: a single-crystal EPR study , 1984 .
[101] H. Taube. Elektronenübertragung zwischen Metallkomplexen – ein Rückblick (Nobel‐Vortrag) , 1984 .
[102] H. Taube. Electron Transfer between Metal Complexes — A Retrospective View (Nobel Lecture) , 1984 .
[103] L. Yellowlees,et al. Ligand-ligand inter-valence charge-transfer absorption in reduced ruthenium(II) bipyridine complexes , 1982 .
[104] C. Pierpont,et al. Transition metal complexes of o-benzoquinone, o-semiquinone, and catecholate ligands , 1981 .
[105] T. Rauchfuss,et al. Metal complexes of hemilabile ligands. Reactivity and structure of dichlorobis(o-(diphenylphosphino)anisole)ruthenium(II) , 1980 .
[106] H. Mcconnell,et al. Intramolecular Charge Transfer in Aromatic Free Radicals , 1961 .
[107] W. Kaim,et al. RuII(α-diimine) or RuIII(α-diimine·–)? Structural, Spectroscopic, and Theoretical Evidence for the Stabilization of a Prominent Metal-to-Ligand Charge-Transfer Excited-State Configuration in the Ground State† , 2014 .
[108] W. Kaim. The Shrinking World of Innocent Ligands: Conventionaland Non‐Conventional Redox‐Active Ligands , 2012 .
[109] D. Astruc. Organometallic chemistry and catalysis , 2007 .
[110] F. Neese,et al. Molecular and electronic structure of four- and five-coordinate cobalt complexes containing two o-phenylenediamine- or two o-aminophenol-type ligands at various oxidation levels: an experimental, density functional, and correlated ab initio study. , 2004, Chemistry.
[111] S. I. Gorelsky,et al. Ruthenium Complexes of Non-Innocent Ligands: Aspects of Charge Transfer Spectroscopy , 2004 .
[112] D. Astruc,et al. Electron Transfer and Radical Processes in Transition-Metal Chemistry , 1995 .
[113] Robert J. Crutchley,et al. Intervalence Charge Transfer and Electron Exchange Studies of Dinuclear Ruthenium Complexes , 1994 .
[114] W. Kaim,et al. The coordination chemistry of TCNE, TCNQ and related polynitrileπ acceptors , 1994 .
[115] W. Kaim. Thermal and light induced electron transfer reactions of main group metal hydrides and organometallics , 1994 .
[116] S. Ernst,et al. ESR of homo- and heteroleptic mono- and dinuclear tris(.alpha.-diimine)ruthenium radical complexes , 1990 .
[117] A. Lever,et al. Complexes of 2,2'-azopyridine with iron(II), cobalt(II), nickel(II), copper(I), and copper(II). Infrared study , 1969 .
[118] Peter Day,et al. Mixed Valence Chemistry-A Survey and Classification , 1968 .