Study on the Fabrication of Carbon Nanotube - Mesocarbon Microbead Composites

Carbon nanotube-Mesocarbon microbead composites were synthesized from coal tar pitch with carbon nanotubes (CNTs) as additive. The effect of CNTs addition and process parameters on the growth and morphologies of Mesocarbon microbeads (MCMBs) was investigated. The results show that adding CNTs enhances the nucleation and inhibits the growth and coalescence of MCMBs. Under the same thermal condensation conditions, the MCMBs made in the presence of CNTs tend to have smaller size, lower yield and more uniform size distribution, but more CNTs can lead to poor spherical degrees. Compared with the raw CNTs, the CNTs treated with blended acid can achieve better sphere and more uniform MCMBs with increasing CNTs ratio.

[1]  Mingming Chen,et al.  Preparation and structure analysis of nano-iron/mesocarbon microbead composites made from a coal tar pitch with addition of ferrocene , 2009 .

[2]  Q. Gong,et al.  In situ fabrication of carbon nanotube/mesocarbon microbead composites from coal tar pitch , 2008 .

[3]  Q. Gong,et al.  Preparation and properties of the powder SBR composites filled with CNTs by spray drying process , 2006 .

[4]  Changjun Zhou,et al.  The effect of oxygen on the processing of mesocarbon microbeads to high-density carbon , 2006 .

[5]  Tong-qi Li,et al.  Characteristics of mesocarbon microbeads generated from a coal tar pitch with addition of micro-alumina powder , 2005 .

[6]  W. Kuo,et al.  Influence of adding MCMBs into carbon/carbon composites reinforced by PAN base no-woven carbon fabrics on their microstructure and performances , 2005 .

[7]  Q. Guo,et al.  Carbon/graphite seal materials prepared from mesocarbon microbeads , 2004 .

[8]  A. Varma,et al.  Processing of mesocarbon microbeads to high-performance materials: Part I. Studies towards the sintering mechanism , 2004 .

[9]  S. Pyun,et al.  Mechanism of lithium transport through an MCMB heat-treated at 800-1200 °C , 2002 .

[10]  M. Dresselhaus,et al.  Microstructure and Electrochemical Properties of Boron‐Doped Mesocarbon Microbeads , 2000 .

[11]  H. Sohn,et al.  Anodic performances of mesocarbon microbeads (MCMB) prepared from synthetic naphthalene isotropic pitch , 1999 .

[12]  Y. Korai,et al.  Effects of carbon black addition on preparation of meso-carbon microbeads , 1997 .