Differential pulse techniques in weakly supported media: Changes in the kinetics and thermodynamics of electrode processes resulting from the supporting electrolyte concentration

[1]  Á. Molina,et al.  The use of differential pulse voltammetries to discriminate between the Butler–Volmer and the simple Marcus–Hush models for heterogeneous electron transfer: The electro-reduction of europium (III) in aqueous solution , 2012 .

[2]  D. Grandoso,et al.  Activity Coefficients of NaBr in Aqueous Mixtures with High Relative Permittivity Cosolvent: Formamide + Water at 298.15 K , 2011 .

[3]  Á. Molina,et al.  Analytical theory of the catalytic mechanism in square wave voltammetry at disc electrodes. , 2011, Physical chemistry chemical physics : PCCP.

[4]  R. Compton,et al.  Electrochemical reactions where the variation of supporting electrolyte concentration is mechanistically revealing: ECE-DISP1 processes in which the chemical step is an isomerisation , 2011 .

[5]  Á. Molina,et al.  Comparison between double pulse and multipulse differential techniques , 2011 .

[6]  R. Compton,et al.  Voltammetry in the absence of excess supporting electrolyte – ECE-DISP1 reactions: The electrochemical reduction of 2-nitrobromobenzene in acetonitrile solvent , 2011 .

[7]  Richard G. Compton,et al.  Measurement of the diffusion coefficients of [Ru(NH3)6]3+ and [Ru(NH3)6]2+ in aqueous solution using microelectrode double potential step chronoamperometry , 2011 .

[8]  R. Compton,et al.  A kinetic and mechanistic study of the electrochemical oxidation of hydroquinone in 1-ethyl-3-methylimidazolium bis(trifluoromethanesulfonyl)imide, [C2mim][NTf2] , 2011 .

[9]  R. Compton,et al.  Cyclic voltammetry in weakly supported media: The reduction of the cobaltocenium cation in acetonitrile – Comparison between theory and experiment , 2010 .

[10]  R. Compton,et al.  Cyclic voltammetry in the absence of excess supporting electrolyte offers extra kinetic and mechanistic insights: comproportionation of anthraquinone and the anthraquinone dianion in acetonitrile. , 2010, Angewandte Chemie.

[11]  R. Compton,et al.  The electrochemical reduction of 1,4-benzoquinone in 1-ethyl-3-methylimidazolium bis(trifluoromethane-sulfonyl)-imide, [C2mim][NTf2]: A voltammetric study of the comproportionation between benzoquinone and the benzoquinone dianion , 2010 .

[12]  R. Compton,et al.  The zero-field approximation for weakly supported voltammetry: A critical evaluation , 2010 .

[13]  R. Compton,et al.  The measurement of the diffusion coefficients of ferrocene and ferrocenium and their temperature dependence in acetonitrile using double potential step microdisk electrode chronoamperometry , 2010 .

[14]  M. Lovrić,et al.  A formal scan rate in staircase and square-wave voltammetry , 2010 .

[15]  R. Compton,et al.  Voltammetry involving amalgam formation and anodic stripping in weakly supported media: Theory and experiment , 2010 .

[16]  Jeongmin T. Han,et al.  Quantitative Voltammetry in Weakly Supported Media. Chronoamperometric Studies on Diverse One Electron Redox Couples Containing Various Charged Species: Dissecting Diffusional and Migrational Contributions and Assessing the Breakdown of Electroneutrality , 2010 .

[17]  Á. Molina,et al.  Theoretical and experimental study of Differential Pulse Voltammetry at spherical electrodes: Measuring diffusion coefficients and formal potentials , 2009 .

[18]  R. Compton,et al.  Quantitative Voltammetry in Weakly Supported Media. Two Electron Transfer, Chronoamperometry of Electrodeposition and Stripping for Cadmium at Microhemispherical Mercury Electrodes , 2009 .

[19]  Richard G. Compton,et al.  How Much Supporting Electrolyte Is Required to Make a Cyclic Voltammetry Experiment Quantitatively “Diffusional”? A Theoretical and Experimental Investigation , 2009 .

[20]  R. Compton,et al.  Numerical Simulation of Potential Step Chronoamperometry at Low Concentrations of Supporting Electrolyte , 2008 .

[21]  N. Tsierkezos.  Electron transfer kinetics for the cobaltocene (+ 1/0) couple at platinum disk electrode in acetonitrile/dichloromethane binary solvent system , 2008 .

[22]  V. Mirceski,et al.  Square-Wave Voltammetry: Theory and Application , 2007 .

[23]  Guigen Zhang,et al.  Simulating the structure and effect of the electrical double layer at nanometre electrodes , 2007 .

[24]  C. Amatore,et al.  Time-dependent diffusion-migration at cylindrical and spherical microelectrodes: steady- and quasi-steady-state analytical solution can be used under transient conditions. , 2007, Analytical chemistry.

[25]  Fan Yang,et al.  Dynamic diffuse double-layer model for the electrochemistry of nanometer-sized electrodes. , 2006, The journal of physical chemistry. B.

[26]  R. Gulaboski,et al.  Theoretical study of a surface electrode reaction preceded by a homogeneous chemical reaction under conditions of square-wave voltammetry , 2005 .

[27]  H. White,et al.  The role of the electrical double layer and ion pairing on the electrochemical oxidation of hexachloroiridate(III) at Pt electrodes of nanometer dimensions. , 2004, Langmuir : the ACS journal of surfaces and colloids.

[28]  V. Mirceski,et al.  Studying electrode mechanism and analytical determination of cocaine and its metabolites at the mercury electrode using square-wave voltammetry☆ , 2004 .

[29]  Emily A Hueske,et al.  Scanning electrochemical microscopy. 48. Hg/Pt hemispherical ultramicroelectrodes: fabrication and characterization. , 2003, Analytical chemistry.

[30]  J. Wadhawan,et al.  A Computational and Experimental Study of the Cyclic Voltammetry Response of Partially Blocked Electrodes. Part II: Randomly Distributed and Overlapping Blocking Systems , 2003 .

[31]  M. Lovrić,et al.  Quasi-reversible EC reactions at spherical microelectrodes analysed by square-wave voltammetry , 2002 .

[32]  M. Lovrić,et al.  Square-wave voltammetry of quasi-reversible electrode processes with coupled homogeneous chemical reactions , 2002 .

[33]  K. B. Oldham,et al.  How valid is the electroneutrality approximation in the theory of steady-state voltammetry? , 2001 .

[34]  M. Bazant,et al.  Asymptotic Analysis of Diffuse-Layer Effects on Time-Dependent Interfacial Kinetics , 2000, cond-mat/0006104.

[35]  Á. Molina,et al.  Square wave voltammetry for a pseudo-first-order catalytic process at spherical electrodes , 2000 .

[36]  Zbigniew Stojek,et al.  Voltammetry in solutions of low ionic strength. Electrochemical and analytical aspects , 1999 .

[37]  David J. Gavaghan,et al.  An exponentially expanding mesh ideally suited to the fast and efficient simulation of diffusion processes at microdisc electrodes. 1. Derivation of the mesh , 1998 .

[38]  David J. Gavaghan,et al.  An exponentially expanding mesh ideally suited to the fast and efficient simulation of diffusion processes at microdisc electrodes. 3. Application to voltammetry , 1998 .

[39]  A. Ribeiro,et al.  Diffusion coefficients in aqueous solutions of potassium chloride at high and low concentrations , 1998 .

[40]  J GavaghanD,et al.  微小ディスク電極における拡散過程の迅速な効率のよいシミュレーションに理想的にふさわしい指数的に展開するメッシュ 3 ボルタンメトリーへの適用 , 1998 .

[41]  Wojciech Hyk,et al.  Migrational chronoamperometry for various reaction stoichiometries and a variety of types of supporting electrolytes , 1997 .

[42]  J. Osteryoung,et al.  Voltammetric reduction of hydrogen ion in solutions of polyprotic strong acids with and without supporting electrolyte , 1997 .

[43]  K. B. Oldham.  Limiting Currents for Steady-State Electrolysis of an Equilibrium Mixture, with and without Supporting Inert Electrolyte. , 1997, Analytical chemistry.

[44]  M. Bos,et al.  Voltammetric investigation of the complexation equilibria in the presence of a low level of supporting electrolyte Part 1: Steady-state current-potential curves for inert complexes , 1997 .

[45]  Wojciech Hyk,et al.  Migrational chronoamperometry of uncharged substrates. influence of electron transfer rate , 1996 .

[46]  A. Jaworski,et al.  Chronoamperometry and pulse voltammetry of uncharged species at microelectrodes in the presence of a very low amount of supporting electrolyte , 1995 .

[47]  D. Pletcher,et al.  A further microelectrode study of the influence of electrolyte concentration on the kinetics of redox couples , 1994 .

[48]  H. White,et al.  Theory of the voltammetric response of electrodes of submicron dimensions. Violation of electroneutrality in the presence of excess supporting electrolyte , 1993 .

[49]  J. Heinze,et al.  The Crank-Nicolson technique—an efficient algorithm for the simulation of electrode processes at macro- and microelectrodes , 1993 .

[50]  Howard Reiss,et al.  A numerical study of the equilibrium and nonequilibrium diffuse double layer in electrochemical cells , 1992 .

[51]  H. White,et al.  Effect of the electrical double layer on voltammetry at microelectrodes , 1990 .

[52]  R. Wightman,et al.  Electrochemical kinetics at microelectrodes: Part V. Migrational effects on steady or quasi-steady-state voltammograms , 1988 .

[53]  R. Wightman,et al.  Electrochemical kinetics at microelectrodes: Part IV. Electrochemistry in media of low ionic strength , 1987 .

[54]  G. Ritzoulis,et al.  Densities, viscosities, and dielectric constants of acetonitrile + toluene at 15, 25, and 35 .degree.C , 1986 .

[55]  R. A. Osteryoung,et al.  Square wave voltammetry and other pulse techniques for the determination of kinetic parameters. The reduction of zinc(II) at mercury electrodes , 1983 .

[56]  R. Buck.  Steady-state space charge effects in symmetric cells with concentration polarized electrodes , 1973 .

[57]  Yukio Saito,et al.  A Theoretical Study on the Diffusion Current at the Stationary Electrodes of Circular and Narrow Band Types , 1968 .

[58]  J. Crank,et al.  A practical method for numerical evaluation of solutions of partial differential equations of the heat-conduction type , 1947, Mathematical Proceedings of the Cambridge Philosophical Society.