Probing the formation of soluble humins in catalytic dehydration of fructose to 5-hydroxymethylfurfural over HZSM-5 catalyst

[1]  B. Sels,et al.  Rational Positioning of Metal Ions to Stabilize Open Tin Sites in Beta Zeolite for Catalytic Conversion of Sugars. , 2022, Angewandte Chemie.

[2]  Liangfang Zhu,et al.  Mapping out the reaction network of humin formation at the initial stage of fructose dehydration in water , 2022, Green Energy & Environment.

[3]  Changwei Hu,et al.  Insights into the NaCl-Induced Formation of Soluble Humins during Fructose Dehydration to 5-Hydroxymethylfurfural , 2022, Industrial & Engineering Chemistry Research.

[4]  Longlong Ma,et al.  Advances in understanding the humins: formation , prevention and application , 2022, Applications in Energy and Combustion Science.

[5]  J. Beltramini,et al.  Structural features of cotton gin trash derived carbon material as a catalyst for the dehydration of fructose to 5-hydroxymethylfurfural , 2021 .

[6]  S. Kamarudin,et al.  Microporous and mesoporous structure catalysts for the production of 5‐hydroxymethylfurfural (5‐HMF) , 2021, International Journal of Energy Research.

[7]  Shubin Wu,et al.  Relationship between the formation of oligomers and monophenols and lignin structure during pyrolysis process , 2020 .

[8]  Nishu,et al.  Impact of acid-modified ZSM-5 on hydrocarbon yield of catalytic co-pyrolysis of poplar wood sawdust and high-density polyethylene by Py-GC/MS analysis , 2020 .

[9]  Chunlin Chen,et al.  Catalytic self-etherification of 5-hydroxymethylfurfural to 5,5′(oxy-bis(methylene))bis-2-furfural over zeolite catalysts: effect of pore structure and acidity , 2020 .

[10]  Changwei Hu,et al.  Controlling the Reaction Networks for Efficient Conversion of Glucose to 5-Hydroxymethylfurfural. , 2020, ChemSusChem.

[11]  Changwei Hu,et al.  High-Efficiency Synthesis of 5-Hydroxymethylfurfural from Fructose over Highly Sulfonated Organocatalyst , 2020 .

[12]  T. Rosenau,et al.  Current Situation of the Challenging Scale‐Up Development of Hydroxymethylfurfural Production , 2020, ChemSusChem.

[13]  Manato Suda,et al.  Synthesis of 5-hydroxymethylfurfural from highly concentrated aqueous fructose solutions using activated carbon. , 2019, Carbohydrate research.

[14]  Changwei Hu,et al.  Solvent Effect on the Degradative Condensation Side Reactions of Fructose in the Initial Stage of Fructose Dehydration. , 2019, ChemSusChem.

[15]  Michikazu Hara,et al.  Structure‐Function Relationships in Fructose Dehydration to 5‐Hydroxymethylfurfural under Mild Conditions by Porous Ionic Crystals Constructed with Analogous Building Blocks , 2019, ChemCatChem.

[16]  Daniel C W Tsang,et al.  Functionalized zeolite-solvent catalytic systems for microwave-assisted dehydration of fructose to 5-hydroxymethylfurfural , 2019, Microporous and Mesoporous Materials.

[17]  K. Galkin,et al.  When Will 5-Hydroxymethylfurfural, the "Sleeping Giant" of Sustainable Chemistry, Awaken? , 2019, ChemSusChem.

[18]  F. D’Anna,et al.  Task-Specific Organic Salts and Ionic Liquids Binary Mixtures: A Combination to Obtain 5-Hydroxymethylfurfural From Carbohydrates , 2019, Front. Chem..

[19]  Debao Li,et al.  Conversion of fructose into furfural or 5-hydroxymethylfurfural over HY zeolites selectively in γ-butyrolactone , 2019, Applied Catalysis A: General.

[20]  Xianhai Zeng,et al.  Development of Betaine-Based Sustainable Catalysts for Green Conversion of Carbohydrates and Biomass into 5-Hydroxymethylfurfural. , 2019, ChemSusChem.

[21]  F. Xiao,et al.  Creating solvation environments in heterogeneous catalysts for efficient biomass conversion , 2018, Nature Communications.

[22]  C. Wyman,et al.  Unifying Mechanistic Analysis of Factors Controlling Selectivity in Fructose Dehydration to 5-Hydroxymethylfurfural by Homogeneous Acid Catalysts in Aprotic Solvents , 2018 .

[23]  D. Vlachos,et al.  Structural analysis of humins formed in the Brønsted acid catalyzed dehydration of fructose , 2018 .

[24]  M. Castaldi,et al.  Synthesis and characterization of functionalized alumina catalysts with thiol and sulfonic groups and their performance in producing 5-hydroxymethylfurfural from fructose , 2017 .

[25]  Xiawei Guo,et al.  Sulfonated polyaniline as a solid organocatalyst for dehydration of fructose into 5-hydroxymethylfurfural , 2017 .

[26]  T. Tsai,et al.  Catalysis of ordered nanoporous materials for fructose dehydration through difructose anhydride intermediate , 2016 .

[27]  Renliang Huang,et al.  Functionalized silica nanoparticles for conversion of fructose to 5-hydroxymethylfurfural , 2016 .

[28]  Helen Y. Luo,et al.  Lewis Acid Zeolites for Biomass Conversion: Perspectives and Challenges on Reactivity, Synthesis, and Stability. , 2016, Annual review of chemical and biomolecular engineering.

[29]  D. Vlachos,et al.  Molecular structure, morphology and growth mechanisms and rates of 5-hydroxymethyl furfural (HMF) derived humins , 2016 .

[30]  S. Opalka,et al.  Influence of the Si/Al ratio and Al distribution on the H-ZSM-5 lattice and Brønsted acid site characteristics , 2016 .

[31]  D. Vlachos,et al.  Mechanism of Brønsted acid-catalyzed glucose dehydration. , 2015, ChemSusChem.

[32]  D. Stosic,et al.  Hierarchical ZSM-5, Beta and USY zeolites: Acidity assessment by gas and aqueous phase calorimetry and catalytic activity in fructose dehydration reaction , 2014 .

[33]  Junhui Li,et al.  The deactivation mechanism of two typical shape-selective HZSM-5 catalysts for alkylation of toluene with methanol , 2014 .

[34]  D. Vlachos,et al.  Kinetics of Homogeneous Brønsted Acid Catalyzed Fructose Dehydration and 5-Hydroxymethyl Furfural Rehydration: A Combined Experimental and Computational Study , 2014 .

[35]  G. Morales,et al.  Sulfonic acid heterogeneous catalysts for dehydration of C6-monosaccharides to 5-hydroxymethylfurfural in dimethyl sulfoxide , 2014 .

[36]  James P. Lewis,et al.  Selective catalytic production of 5-hydroxymethylfurfural from glucose by adjusting catalyst wettability. , 2014, ChemSusChem.

[37]  B. Shanks,et al.  Catalytic dehydration of C6 carbohydrates for the production of hydroxymethylfurfural (HMF) as a versatile platform chemical , 2014 .

[38]  D. Vlachos,et al.  Elucidating the Roles of Zeolite H-BEA in Aqueous-Phase Fructose Dehydration and HMF Rehydration , 2013 .

[39]  N. Matubayasi,et al.  Solvent effect on pathways and mechanisms for D-fructose conversion to 5-hydroxymethyl-2-furaldehyde: in situ 13C NMR study. , 2013, The journal of physical chemistry. A.

[40]  E. Hensen,et al.  Mechanism of Brønsted acid-catalyzed conversion of carbohydrates , 2012 .

[41]  T. A. Nijhuis,et al.  Fructose dehydration to 5-hydroxymethylfurfural over solid acid catalysts in a biphasic system. , 2012, ChemSusChem.

[42]  B. Wichterlová,et al.  Synthesis of ZSM-5 Zeolites with Defined Distribution of Al Atoms in the Framework and Multinuclear MAS NMR Analysis of the Control of Al Distribution , 2012 .

[43]  Z. Sobalík,et al.  Siting and Distribution of Framework Aluminium Atoms in Silicon-Rich Zeolites and Impact on Catalysis , 2012 .

[44]  Anmin Zheng,et al.  Bronsted/Lewis Acid Synergy in H-ZSM-5 and H-MOR Zeolites Studied by (1)H and (27)Al DQ-MAS Solid-State NMR Spectroscopy , 2011 .

[45]  A. Bell,et al.  A study of the acid-catalyzed hydrolysis of cellulose dissolved in ionic liquids and the factors influencing the dehydration of glucose and the formation of humins. , 2011, ChemSusChem.

[46]  D. Vlachos,et al.  Converting fructose to 5-hydroxymethylfurfural: a quantum mechanics/molecular mechanics study of the mechanism and energetics. , 2011, Carbohydrate research.

[47]  Xinwen Guo,et al.  Effects of steam and TEOS modification on HZSM-5 zeolite for 2,6-dimethylnaphthalene synthesis by methylation of 2-methylnaphthalene with methanol , 2010 .

[48]  John M Woodley,et al.  Efficient microwave-assisted synthesis of 5-hydroxymethylfurfural from concentrated aqueous fructose. , 2009, Carbohydrate research.

[49]  Hiroyuki Yoshida,et al.  Kinetics of the Decomposition of Fructose Catalyzed by Hydrochloric Acid in Subcritical Water: Formation of 5-Hydroxymethylfurfural, Levulinic, and Formic Acids , 2007 .

[50]  Ulrich Simon,et al.  The acid properties of H-ZSM-5 as studied by NH3-TPD and 27Al-MAS-NMR spectroscopy , 2007 .

[51]  S. Nakata,et al.  Detection of active sites for paraffin cracking on USY zeolite by 27Al MQMAS NMR operated at high magnetic field 16 T , 2005 .

[52]  Gerard Avignon,et al.  Dehydration of fructose to 5-hydroxymethylfurfural over H-mordenites , 1996 .

[53]  C. Moreau,et al.  Preparation of 5-hydroxymethylfurfural from fructose and precursors over H-form zeolites , 1994 .

[54]  J. Smith,et al.  Silicalite, a new hydrophobic crystalline silica molecular sieve , 1978, Nature.

[55]  Farzad Seidi,et al.  Catalytic fructose dehydration to 5-hydroxymethylfurfural on the surface of sulfonic acid modified ordered mesoporous SBA-16 , 2023, Fuel.

[56]  Shuai Wang,et al.  Efficient dehydration of fructose into 5-HMF using a weakly-acidic catalyst prepared from a lignin-derived mesoporous carbon , 2022, Fuel.

[57]  B. Likozar,et al.  A review of bio-refining process intensification in catalytic conversion reactions, separations and purifications of hydroxymethylfurfural (HMF) and furfural , 2022, Chemical Engineering Journal.

[58]  M. Ju,et al.  Biorefinery roadmap based on catalytic production and upgrading 5-hydroxymethylfurfural , 2020 .

[59]  T. Tsai,et al.  Design of sulfonated mesoporous silica catalyst for fructose dehydration guided by difructose anhydride intermediate incorporated reaction network , 2016 .

[60]  Xin Pu,et al.  Acid properties and catalysis of USY zeolite with different extra-framework aluminum concentration , 2015 .