Modeling of combined particles and natural organic matter fouling of ultrafiltration membrane

Abstract In this study the combined particles and organic matter (OM) fouling was investigated using kaolinite clay and humic substances. Results confirm the occurrence of a synergistic effect between the particles and the OM leading to a stronger flux decline than the one predicted by the resistance in series model. Moreover, a higher organic matter transmission through the membrane was observed when filtered with kaolinite particles compared to organic matter alone. Experimental data were successfully fitted, thanks to a phenomenological model. The developed model based on the contributions of the two components filtered separately introduces the filtration coefficient describing the capability of the cake layer being formed to hinder or capture OM. Model application to experimental data and data extracted from literature shows a better agreement than values predicted by the classical resistance in series model.

[1]  Robert W. Field,et al.  Critical and sustainable fluxes: Theory, experiments and applications , 2006 .

[2]  Tomihisa Iwasaki,et al.  Some Notes on Sand Filtration , 1937 .

[3]  W. Pronk,et al.  Influence of interactions between NOM and particles on UF fouling mechanisms. , 2008, Water research.

[4]  David C. Stuckey,et al.  Flux and performance improvement in a submerged anaerobic membrane bioreactor (SAMBR) using powdered activated carbon (PAC) , 2008 .

[5]  J. Hermia,et al.  Constant Pressure Blocking Filtration Laws - Application To Power-law Non-newtonian Fluids , 1982 .

[6]  Jianrong Chen,et al.  A critical review of extracellular polymeric substances (EPSs) in membrane bioreactors: Characteristics, roles in membrane fouling and control strategies , 2014 .

[7]  K Schügerl,et al.  Permeation of 6-nitro-3-phenylacetamide benzoic acid (NIPAB) and hydrolysis by penicillin acylase immobilized in emulsion liquid membranes. , 2007, Journal of chemical technology and biotechnology.

[8]  A. Ismail,et al.  Role of natural organic matter (NOM), colloidal particles, and solution chemistry on ultrafiltration performance , 2011 .

[9]  A. Zydney,et al.  HUMIC ACID FOULING DURING MICROFILTRATION , 1999 .

[10]  A. Fane,et al.  Optimization of membrane bioreactors by the addition of powdered activated carbon. , 2013, Bioresource technology.

[11]  Corinne Cabassud,et al.  Engineering of an MBR supernatant fouling layer by fine particles addition: a possible way to control cake compressibility. , 2011, Water research.

[12]  M. Elimelech,et al.  Relating organic fouling of reverse osmosis membranes to intermolecular adhesion forces. , 2006, Environmental science & technology.

[13]  Ho,et al.  A Combined Pore Blockage and Cake Filtration Model for Protein Fouling during Microfiltration. , 2000, Journal of colloid and interface science.

[14]  Fuyi Cui,et al.  Effect of particle size and concentration on the synergistic UF membrane fouling by particles and NOM fractions , 2013 .

[15]  Heng Liang,et al.  Hydraulic irreversibility of ultrafiltration membrane fouling by humic acid: Effects of membrane properties and backwash water composition , 2015 .

[16]  J. M. Thwala,et al.  Factors governing combined fouling by organic and colloidal foulants in cross-flow nanofiltration , 2015 .

[17]  Robert H. Davis,et al.  The behavior of suspensions and macromolecular solutions in crossflow microfiltration , 1994 .

[18]  Greg Foley,et al.  Modelling the effects of particle polydispersity in crossflow filtration , 1995 .

[19]  Andrew L. Zydney,et al.  Mechanisms for BSA fouling during microfiltration , 1995 .

[20]  Menachem Elimelech,et al.  Dynamics of Colloid Deposition in Porous Media: Blocking Based on Random Sequential Adsorption , 1995 .

[21]  Robert H. Davis,et al.  Microfiltration of protein-cell mixtures with crossflushing or backflushing , 2001 .

[22]  Menachem Elimelech,et al.  Synergistic effects in combined fouling of a loose nanofiltration membrane by colloidal materials and natural organic matter , 2006 .

[23]  H. Chu,et al.  Evaluation of different algogenic organic matters on the fouling of microfiltration membranes , 2014 .

[24]  Hardy Temmink,et al.  Why low powdered activated carbon addition reduces membrane fouling in MBRs. , 2010, Water research.

[25]  Tong Zhang,et al.  Effect of activated carbon on fouling of activated sludge filtration , 2006 .

[26]  Silvia Álvarez Blanco,et al.  Fouling dynamics modelling in the ultrafiltration of PEGs , 2008 .

[27]  R. Field,et al.  Review of fouling by mixed feeds in membrane fi ltration applied to water p urifi cation , 2011 .

[28]  Silvia Álvarez Blanco,et al.  Analysis of membrane pore blocking models applied to the ultrafiltration of PEG , 2008 .

[29]  W. Pronk,et al.  Mutual influences between natural organic matter and inorganic particles and their combined effect on ultrafiltration membrane fouling. , 2008, Environmental science & technology.

[30]  A. Kim,et al.  Combined fouling of nanofiltration membranes: Mechanisms and effect of organic matter , 2009 .

[31]  N. Hankins,et al.  Fouling and cleaning of ultrafiltration membranes: A review , 2014 .

[32]  Y. Polyakov Depth filtration approach to the theory of standard blocking: Prediction of membrane permeation rate and selectivity , 2008 .

[33]  Fundamental mechanisms of three-component combined fouling with experimental verification. , 2009, Langmuir : the ACS journal of surfaces and colloids.

[34]  Robert H. Davis,et al.  Microfiltration of protein mixtures and the effects of yeast on membrane fouling , 1999 .