Structural and Electrical Characterization of Solution-Processed Electrodes for Piezoelectric Polymer Film Sensors

Solution-processable graphene and carbon nanotube-based electrode materials were used here to provide electrodes on flexible piezoelectric polyvinylidenefluoride sensors. Piezoelectric sensitivity measurements, image-based analysis, adhesion tests, and sheet resistance measurements were applied to these printable sensors to rigorously analyze their performance and structure. The printable sensors showed electrical performance similar to metallized sensors, whereas the adhesion of the solution-processed materials to the substrate is not as high as that of the evaporated metal films. This also affects the measured sensor sensitivity values. The measurements based on optical images were found to be a promising method to capture detailed information about the electrode surface structure.

[1]  S. Evoy,et al.  A review of piezoelectric polymers as functional materials for electromechanical transducers , 2014 .

[2]  K. J. Stout,et al.  Three-Dimensional Surface Topography , 2000 .

[3]  Mari Zakrzewski,et al.  Solution-processible electrode materials for a heat-sensitive piezoelectric thin-film sensor , 2012 .

[4]  H. Schmidt,et al.  Piezoelectric polymer electrets , 1996 .

[5]  Gábor Harsányi,et al.  Polymer films in sensor applications: A review of present uses and future possibilities , 2000 .

[6]  P. Avouris,et al.  Carbon-based electronics. , 2007, Nature nanotechnology.

[7]  R. Baughman,et al.  Carbon Nanotubes: Present and Future Commercial Applications , 2013, Science.

[8]  Wolfgang Clemens,et al.  OE-A Roadmap for Organic and Printed Electronics , 2013 .

[9]  T. Furukawa,et al.  Piezoelectricity and pyroelectricity in polymers , 1989 .

[10]  N. S. Hoang,et al.  A Low-Cost , 1997 .

[11]  Sampo Tuukkanen,et al.  Low-cost, solution processable carbon nanotube supercapacitors and their characterization , 2014 .

[12]  J. I. Brauman Polymers , 1991, Science.

[13]  J. Lekkala,et al.  Film-Type Sensor Materials PVDF and EMFi in Measurement of Cardiorespiratory Signals— A Review , 2012, IEEE Sensors Journal.

[14]  Mari Zakrzewski,et al.  Printable, Transparent, and Flexible Touch Panels Working in Sunlight and Moist Environments , 2014 .

[15]  Lyndon N. Smith,et al.  In vivo measurement of skin microrelief using photometric stereo in the presence of interreflections. , 2013, Journal of the Optical Society of America. A, Optics, image science, and vision.

[16]  Jukka Lekkala,et al.  Plantar shear stress measurements - A review. , 2014, Clinical biomechanics.

[17]  Sampo Tuukkanen,et al.  Characteristics of Piezoelectric Polymer Film Sensors With Solution-Processable Graphene-Based Electrode Materials , 2015, IEEE Sensors Journal.

[18]  Maurizio Valle,et al.  Electromechanical characterization of piezoelectric PVDF polymer films for tactile sensors in robotics applications , 2011 .

[19]  Marja Mettänen,et al.  Measurement of Print Quality: Joint Statistical Analysis of Paper Topography and Print Defects , 2010 .

[20]  Robert J. Woodham,et al.  Photometric method for determining surface orientation from multiple images , 1980 .

[21]  A. Authier,et al.  Physical properties of crystals , 2007 .

[22]  Satu Kärki,et al.  Development of a piezoelectric polymer film sensor for plantar normal and shear stress measurements , 2009 .

[23]  A. Ferrari,et al.  Graphene Photonics and Optoelectroncs , 2010, CLEO 2012.

[24]  Steven M. Seitz,et al.  Shape and Spatially-Varying BRDFs from Photometric Stereo , 2005, IEEE Transactions on Pattern Analysis and Machine Intelligence.

[25]  Don Berlincourt,et al.  3 – Piezoelectric and Piezomagnetic Materials and Their Function in Transducers , 1964 .

[26]  K. Novoselov,et al.  A roadmap for graphene , 2012, Nature.

[27]  M. Honkanen,et al.  Stretching of solution processed carbon nanotube and graphene nanocomposite films on rubber substrates , 2014 .

[28]  S. Lang,et al.  Review of some lesser-known applications of piezoelectric and pyroelectric polymers , 2006 .