Mechanistic aspects of C-H activation by Pt complexes.

2.3. Hydrocarbon Coordination 2475 2.4. σ Complexes of Alkanes and Arenes 2475 2.5. Principle of Microscopic Reversibility 2476 2.6. Kinetic Isotope Effects 2477 3. Shilov-type Chemistry 2478 3.1. C−H Activation by Pt(II) 2479 3.2. Mechanism of Multiple H/D Exchange 2480 3.3. H/D Exchanges1,2 Shift in Ethane 2481 3.4. Computational Studies of the Shilov System 2481 3.5. C−H Activation by Pt(IV) 2482 4. “Catalytica” System for Catalytic Methane Functionalization 2482