Fire spalling of ultra-high performance concrete: From a global analysis to microstructure investigations

Abstract This article presents the behaviour under fire of a specific ultra-high performance concrete (UHPC) called BCV. Several compositions with synthetic additions such, as polypropylene (PP) fibres and powder or acrylic (PAN) fibres, are mixed to produce these specimens. As a first step, a blowtorch test on prismatic specimens shows that small PP fibres are more efficient in resisting fire. Next, scanning electron microscopic observations after heating reveal significant behavioural differences between PP fibres and PAN fibres during their vaporisation process. Lastly, a mercury intrusion porosimetry investigation following a heating cycle at 350°C indicates that concrete porosity is not a sufficient parameter for determining whether or not a given material composition is resistant to fire spalling. A critical factor dependent on pore size distribution, is proposed herein; its threshold value, i.e. under which the material exhibits a very high probability of being prone to fire spalling, is also estimated.

[1]  D. Santos,et al.  A microstructural approach to adherence mechanism of poly(vinyl alcohol) modified cement systems to ceramic tiles , 2007 .

[2]  G. A. Khoury,et al.  Concrete spalling assessment methodologies and polypropylene fibre toxicity analysis in tunnel fires , 2008 .

[3]  G. A. Khoury,et al.  Polypropylene fibres in heated concrete. Part 2. Pressure relief mechanisms and modelling criteria , 2008 .

[4]  François Toutlemonde,et al.  The nano-mechanical signature of Ultra High Performance Concrete by statistical nanoindentation techniques , 2008 .

[5]  Luc Taerwe,et al.  On the Mechanism of Polypropylene Fibres in Preventing Fire Spalling in Self-Compacting and High-performance Cement Paste , 2008 .

[6]  Z. Bažant,et al.  Concrete at High Temperatures: Material Properties and Mathematical Models , 1996 .

[7]  James R. Lawson,et al.  Effects of elevated temperature exposure on heating characteristics, spalling, and residual properties of high performance concrete , 2001 .

[8]  Jean-Christophe Mindeguia,et al.  Temperature, Pore Pressure and Mass Variation of Concrete Subjected to High Temperature -- Experimental and Numerical Discussion on Spalling Risk , 2010 .

[9]  Venkatesh Kodur,et al.  Optimization of the type and amount of polypropylene fibres for preventing the spalling of lightweight concrete subjected to hydrocarbon fire , 2004 .

[10]  Wei Sun,et al.  EFFECT OF HIGH TEMPERATURE AND COOLING REGIMES ON THE COMPRESSIVE STRENGTH AND PORE PROPERTIES OF HIGH PERFORMANCE CONCRETE , 2000 .

[11]  A. Noumowé,et al.  Transient heating effect on high strength concrete , 1996 .

[12]  T. Harmathy,et al.  Effect of Moisture on the Fire Endurance of Building Elements , 1965 .

[13]  H. L. Malhotra The effect of temperature on the compressive strength of concrete , 1956 .

[14]  Franz-Josef Ulm,et al.  THE "CHUNNEL" FIRE. II: ANALYSIS OF CONCRETE DAMAGE , 1999 .

[15]  T Sedran,et al.  Optimization of ultra-high-performance concrete by the use of a packing model , 1994 .

[16]  A. Mansur,et al.  Surface interactions of chemically active ceramic tiles with polymer-modified mortars , 2011 .

[17]  L. Boström,et al.  Fire spalling : Theories and Experiments , 2007 .

[18]  G. A. Khoury,et al.  Polypropylene fibres in heated concrete. Part 1: Molecular structure and materials behaviour , 2008 .

[19]  Kristian Dahl Hertz,et al.  Limits of spalling of fire-exposed concrete , 2003 .

[20]  Sidney Diamond,et al.  Mercury porosimetry: An inappropriate method for the measurement of pore size distributions in cement-based materials , 2000 .