MnSe/Co0.85Se/N‐CNFs as Binder‐Free Anodes for Sodium/Potassium‐Ion Batteries

MnSe and Co0.85Se embedded in nitrogen‐doped carbon nanofibers (MnSe/Co0.85Se/N‐CNFs) were synthesized by electrospinning and high‐temperature calcination, and evaluated for the first time as sodium/potassium‐ion battery anode material via constant current charge/discharge, cyclic voltammetry, electrochemical impedance spectroscopy.Ex‐situ XRD revealed the potassium storage mechanism of MnSe/Co0.85Se/N‐CNFs, indicating that its capacity was mainly provided by the conversion reaction. Compared with MnSe/N‐CNFs and Co0.85Se/N‐CNFs, the reversible capacity and cycling performance of MnSe/Co0.85Se/N‐CNFs were significantly improved due to the synergistic effect of bimetals. The MnSe/Co0.85Se/N‐CNFs electrode showed a charging capacity of 262.3 mAh g−1 after 700 cycles at 1 A g−1 in Na‐ion batteries and a discharge capacity of 183.4 mAh g−1 after 400 cycles at 0.1 A g−1 in K‐ion batteries, The results showed that binder‐free binary metal MnSe/Co0.85Se/N‐CNFs have a certain development prospect as anode for sodium/potassium‐ion batteries.

[1]  Dunmin Lin,et al.  Multilevel spatial confinement of transition metal selenides porous microcubes for efficient and stable potassium storage. , 2023, Journal of colloid and interface science.

[2]  Yun Chan Kang,et al.  Solution-phase selenization engineering of zeolitic imidazolate framework (ZIF)-67-derived Co0.85Se@nitrogen-doped carbon for potassium-ion storage , 2022, Applied Surface Science.

[3]  Litao Sun,et al.  Roadmap for flexible solid-state aqueous batteries: From materials engineering and architectures design to mechanical characterizations , 2022, Materials Science and Engineering: R: Reports.

[4]  K. Yin,et al.  Advanced Multifunctional Aqueous Rechargeable Batteries Design: From Materials and Devices to Systems , 2021, Advanced materials.

[5]  Y. Kang,et al.  Synthesis of MnSe@C yolk‐shell nanospheres via a water vapor‐assisted strategy for use as anode in sodium‐ion batteries , 2021, International Journal of Energy Research.

[6]  Dianlong Wang,et al.  Stress-release design for high-capacity and long-time lifespan aqueous zinc-ion batteries , 2021 .

[7]  Suo Guoquan,et al.  Improvement in potassium ion batteries electrodes: recent developments and efficient approaches , 2021 .

[8]  Hongxia Wang,et al.  Bimetallic Ni/Co-ZIF-67 derived NiCo2Se4/N-doped porous carbon nanocubes with excellent sodium storage performance , 2020 .

[9]  Guofu Zhou,et al.  MnSe embedded in carbon nanofibers as advanced anode material for sodium ion batteries , 2020, Nanotechnology.

[10]  Qin-Chao Wang,et al.  NiCo2Se4 as an anode material for sodium-ion batteries , 2020 .

[11]  Hui Wang,et al.  Prussian blue analogs (PBA) derived porous bimetal (Mn, Fe) selenide with carbon nanotubes as anode materials for sodium and potassium ion batteries , 2020 .

[12]  Teng Zhang,et al.  Transition metal chalcogenide anodes for sodium storage , 2020 .

[13]  G. Diao,et al.  Hierarchical N‐Doped HMCN/CNT Hybrid Carbon Frameworks Assembling Cobalt Selenide Nanoparticles for Advanced Properties of Lithium/Sodium Storage , 2019, Advanced Materials Interfaces.

[14]  Jiamu Huang,et al.  MOF-derived α-MnSe/C composites as anode materials for Li-ion batteries , 2019 .

[15]  Hang Hu,et al.  Engineering of nanonetwork-structured carbon to enable high-performance potassium-ion storage. , 2019, Journal of colloid and interface science.

[16]  S. Liang,et al.  A Confined Replacement Synthesis of Bismuth Nanodots in MOF Derived Carbon Arrays as Binder‐Free Anodes for Sodium‐Ion Batteries , 2019, Advanced science.

[17]  X. Lou,et al.  Synthesis of CuS@CoS2 Double-Shelled Nanoboxes with Enhanced Sodium Storage Properties. , 2019, Angewandte Chemie.

[18]  J. Zhao,et al.  Binder-Free Hierarchical Urchin-like Manganese–Cobalt Selenide with High Electrochemical Energy Storage Performance , 2019, ACS Applied Energy Materials.

[19]  Yagang Yao,et al.  Direct Ink Writing of Adjustable Electrochemical Energy Storage Device with High Gravimetric Energy Densities , 2019, Advanced Functional Materials.

[20]  X. Lou,et al.  Synthesis of Cobalt Sulfide Multi-shelled Nanoboxes with Precisely Controlled Two to Five Shells for Sodium-Ion Batteries. , 2019, Angewandte Chemie.

[21]  Hun‐Gi Jung,et al.  Kinetic and Electrochemical Reaction Mechanism Investigations of Rodlike CoMoO4 Anode Material for Sodium-Ion Batteries. , 2019, ACS applied materials & interfaces.

[22]  Wenpei Kang,et al.  ZnSxSe1-x/N-C (x = 0.24) hierarchical nanosphere with improved energy storage capability as sodium-ion battery anode , 2019, Journal of Alloys and Compounds.

[23]  Jian Yang,et al.  Metal-organic framework-derived Co0.85Se nanoparticles in N-doped carbon as a high-rate and long-lifespan anode material for potassium ion batteries , 2018, Materials Today Energy.

[24]  Feng Wu,et al.  Hierarchical porous Co0.85Se@reduced graphene oxide ultrathin nanosheets with vacancy-enhanced kinetics as superior anodes for sodium-ion batteries , 2018, Nano Energy.

[25]  Jintao Zhang,et al.  Necklace‐Like Structures Composed of Fe3N@C Yolk–Shell Particles as an Advanced Anode for Sodium‐Ion Batteries , 2018, Advanced materials.

[26]  Huaihe Song,et al.  Flexible Co0.85Se nanosheets/graphene composite film as binder-free anode with high Li- and Na-Ion storage performance , 2018 .

[27]  Jin Koo Kim,et al.  Excellent sodium-ion storage performances of CoSe2 nanoparticles embedded within N-doped porous graphitic carbon nanocube/carbon nanotube composite , 2017 .

[28]  Jianneng Liang,et al.  Ultrafine MoO2‐Carbon Microstructures Enable Ultralong‐Life Power‐Type Sodium Ion Storage by Enhanced Pseudocapacitance , 2017 .

[29]  D. Yan,et al.  MnO@C nanorods derived from metal-organic frameworks as anode for superiorly stable and long-life sodium-ion batteries , 2017 .

[30]  J. Chai,et al.  Graphene‐Encapsulated Copper tin Sulfide Submicron Spheres as High‐Capacity Binder‐Free Anode for Lithium‐Ion Batteries , 2017 .

[31]  Tao Zhou,et al.  A Polymetallic Metal‐Organic Framework‐Derived Strategy toward Synergistically Multidoped Metal Oxide Electrodes with Ultralong Cycle Life and High Volumetric Capacity , 2017 .

[32]  L. Nazar,et al.  Methods and Protocols for Electrochemical Energy Storage Materials Research , 2017 .

[33]  D. A. D. Corte,et al.  Microsized Sn as Advanced Anodes in Glyme‐Based Electrolyte for Na‐Ion Batteries , 2016, Advanced materials.

[34]  H. Alshareef,et al.  SnSe2 2D Anodes for Advanced Sodium Ion Batteries , 2016 .

[35]  Yuanyuan Guo,et al.  Controllable Preparation of Square Nickel Chalcogenide (NiS and NiSe2) Nanoplates for Superior Li/Na Ion Storage Properties. , 2016, ACS applied materials & interfaces.

[36]  Xiaofeng Fan,et al.  Array of nanosheets render ultrafast and high-capacity Na-ion storage by tunable pseudocapacitance , 2016, Nature Communications.

[37]  Y. Kang,et al.  One-Pot Synthesis of CoSex -rGO Composite Powders by Spray Pyrolysis and Their Application as Anode Material for Sodium-Ion Batteries. , 2016, Chemistry.

[38]  Hongyang Zhao,et al.  Synthesis of High-Quality α-MnSe Nanostructures with Superior Lithium Storage Properties. , 2016, Inorganic chemistry.

[39]  Koichi Yamashita,et al.  Black Phosphorus as a High-Capacity, High-Capability Negative Electrode for Sodium-Ion Batteries: Investigation of the Electrode/Electrolyte Interface , 2016 .

[40]  Jie Cai,et al.  A Hierarchical N/S‐Codoped Carbon Anode Fabricated Facilely from Cellulose/Polyaniline Microspheres for High‐Performance Sodium‐Ion Batteries , 2016 .

[41]  Zaiping Guo,et al.  Boosted Charge Transfer in SnS/SnO2 Heterostructures: Toward High Rate Capability for Sodium-Ion Batteries. , 2016, Angewandte Chemie.

[42]  Jianhua Qian,et al.  Preparation and characterisation of rutile titanium dioxide of special hollow microspheres , 2016 .

[43]  Se Youn Cho,et al.  Sodium‐Ion Storage in Pyroprotein‐Based Carbon Nanoplates , 2015, Advanced materials.

[44]  Zhian Zhang,et al.  Hierarchical MoSe2 Nanosheets/Reduced Graphene Oxide Composites as Anodes for Lithium‐Ion and Sodium‐Ion Batteries with Enhanced Electrochemical Performance , 2015 .

[45]  Qian Sun,et al.  Cu2Se with facile synthesis as a cathode material for rechargeable sodium batteries. , 2013, Chemical communications.

[46]  K. Müllen,et al.  Efficient Synthesis of Heteroatom (N or S)‐Doped Graphene Based on Ultrathin Graphene Oxide‐Porous Silica Sheets for Oxygen Reduction Reactions , 2012 .

[47]  Shaokun Chong,et al.  An Α-Mnse Nanorod as Anode for Superior Potassium-Ion Storage Via Synergistic Effects of Physical Encapsulation and Chemical Bonding , 2022, SSRN Electronic Journal.

[48]  Guoxue Liu,et al.  Metal–organic-frameworks-engaged formation of Co0.85Se@C nanoboxes embedded in carbon nanofibers film for enhanced potassium-ion storage , 2020 .

[49]  C. Shi,et al.  Ultrasmall Fe2GeO4 nanodots anchored on interconnected carbon nanosheets as high-performance anode materials for lithium and sodium ion batteries , 2018 .