Conductive Elastomers for Stretchable Electronics, Sensors and Energy Harvesters

There have been a wide variety of efforts to develop conductive elastomers that satisfy both mechanical stretchability and electrical conductivity, as a response to growing demands on stretchable and wearable devices. This article reviews the important progress in conductive elastomers made in three application fields of stretchable technology: stretchable electronics, stretchable sensors, and stretchable energy harvesters. Diverse combinations of insulating elastomers and non-stretchable conductive materials have been studied to realize optimal conductive elastomers. It is noted that similar material combinations and similar structures have often been employed in different fields of application. In terms of stretchability, cyclic operation, and overall performance, fields such as stretchable conductors and stretchable strain/pressure sensors have achieved great advancement, whereas other fields like stretchable memories and stretchable thermoelectric energy harvesting are in their infancy. It is worth mentioning that there are still obstacles to overcome for the further progress of stretchable technology in the respective fields, which include the simplification of material combination and device structure, securement of reproducibility and reliability, and the establishment of easy fabrication techniques. Through this review article, both the progress and obstacles associated with the respective stretchable technologies will be understood more clearly.

[1]  J. E. Mark,et al.  Preparation, Characterization, and Physical Properties of Multiwall Carbon Nanotube/Elastomer Composites , 2009 .

[2]  Yu Sun,et al.  Development of Carbon Nanotube-Based Sensors—A Review , 2007, IEEE Sensors Journal.

[3]  J. Rogers,et al.  Stretchable field-effect-transistor array of suspended SnO₂ nanowires. , 2011, Small.

[4]  E. Carone,et al.  New conducting thermoplastic elastomers. I. Synthesis and chemical characterization , 2002 .

[5]  Fengjia Fan,et al.  Stretchable conductors based on silver nanowires: improved performance through a binary network design. , 2013, Angewandte Chemie.

[6]  Xue Feng,et al.  Breathable and Stretchable Temperature Sensors Inspired by Skin , 2015, Scientific Reports.

[7]  J. Dual,et al.  Mechanical characterization of PEDOT : PSS thin films , 2009 .

[8]  Charles R. Szmanda,et al.  Programmable polymer thin film and non-volatile memory device , 2004, Nature materials.

[9]  M. Thakur,et al.  A class of conducting polymers having nonconjugated backbones , 1988 .

[10]  Polyurethane-polyaniline conducting graft copolymer with improved mechanical properties , 2003 .

[11]  J. Lee,et al.  PROGRESS IN PREPARATION, PROCESSING AND APPLICATIONS OF POLYANILINE , 2009 .

[12]  G. Barra,et al.  Polyaniline/thermoplastic polyurethane blends: Preparation and evaluation of electrical conductivity , 2007 .

[13]  Wei Gao,et al.  Highly conductive and stretchable polymer composites based on graphene/MWCNT network. , 2013, Chemical communications.

[14]  Hyungdong Lee,et al.  Directly printed stretchable strain sensor based on ring and diamond shaped silver nanowire electrodes , 2015 .

[15]  W. Vervisch,et al.  Photo-electrical characterizations of plastic solar modules , 2012 .

[16]  Yong Zhu,et al.  Highly Conductive and Stretchable Silver Nanowire Conductors , 2012, Advanced materials.

[17]  Youhong Tang,et al.  Electrically and thermally conductive elastomer/graphene nanocomposites by solution mixing , 2014 .

[18]  Zhibin Yu,et al.  Elastomeric polymer light-emitting devices and displays , 2013, Nature Photonics.

[19]  I. Park,et al.  Highly stretchable and sensitive strain sensor based on silver nanowire-elastomer nanocomposite. , 2014, ACS nano.

[20]  B. Shirinzadeh,et al.  A wearable and highly sensitive pressure sensor with ultrathin gold nanowires , 2014, Nature Communications.

[21]  M. Lima,et al.  Elastomeric Conductive Composites Based on Carbon Nanotube Forests , 2010, Advanced materials.

[22]  P. Ghosh,et al.  Conducting carbon black filled EPDM vulcanizates: assessment of dependence of physical and mechanical properties and conducting character on variation of filler loading , 2000 .

[23]  M. Paoli,et al.  An elastomeric conductor based on polyaniline prepared by mechanical mixing , 1999 .

[24]  K. Hata,et al.  A stretchable carbon nanotube strain sensor for human-motion detection. , 2011, Nature nanotechnology.

[25]  Haixiong Tang,et al.  Scalable Synthesis of Morphotropic Phase Boundary Lead Zirconium Titanate Nanowires for Energy Harvesting , 2014, Advanced materials.

[26]  S. Wagner,et al.  An elastically stretchable TFT circuit , 2004, IEEE Electron Device Letters.

[27]  Guoqiang Liu,et al.  Flexible piezoelectric nanogenerators based on ZnO nanorods grown on common paper substrates. , 2012, Nanoscale.

[28]  王军波,et al.  Direct-Write Piezoelectric Polymeric Nanogenerator with High Energy Conversion Efficiency , 2010 .

[29]  Guggi Kofod,et al.  Soft Conductive Elastomer Materials for Stretchable Electronics and Voltage Controlled Artificial Muscles , 2013, Advanced materials.

[30]  T. Hino,et al.  Effect of temperature and moisture on electrical conductivity in polyaniline/polyurethane (PANI/PU) blends , 2006 .

[31]  T. Someya,et al.  Conformable, flexible, large-area networks of pressure and thermal sensors with organic transistor active matrixes. , 2005, Proceedings of the National Academy of Sciences of the United States of America.

[32]  Zhenan Bao,et al.  Skin-inspired electronic devices , 2014 .

[33]  S. Bose,et al.  Recent advances in graphene based polymer composites , 2010 .

[34]  Yonggang Huang,et al.  Printed Assemblies of Inorganic Light-Emitting Diodes for Deformable and Semitransparent Displays , 2009, Science.

[35]  W. Xu,et al.  Organic Thermoelectric Materials: Emerging Green Energy Materials Converting Heat to Electricity Directly and Efficiently , 2014, Advanced materials.

[36]  Guenter Gauglitz,et al.  Direct optical sensors: principles and selected applications , 2005, Analytical and bioanalytical chemistry.

[37]  Tricia Breen Carmichael,et al.  Stretchable Light‐Emitting Electrochemical Cells Using an Elastomeric Emissive Material , 2012, Advanced materials.

[38]  Stephanie J. Benight,et al.  Stretchable and self-healing polymers and devices for electronic skin , 2013 .

[39]  Niyazi Serdar Sariciftci,et al.  Organic solar cells: An overview , 2004 .

[40]  Jin-Seo Noh,et al.  Highly conductive and stretchable poly(dimethylsiloxane):poly(3,4-ethylenedioxythiophene):poly(styrene sulfonic acid) blends for organic interconnects , 2014 .

[41]  Zhong Lin Wang,et al.  Piezoelectric Nanogenerators Based on Zinc Oxide Nanowire Arrays , 2006, Science.

[42]  J. E. Mark,et al.  Effects of filler particle/elastomer distribution and interaction on composite mechanical properties , 2002 .

[43]  Nae-Eung Lee,et al.  An All‐Elastomeric Transparent and Stretchable Temperature Sensor for Body‐Attachable Wearable Electronics , 2016, Advanced materials.

[44]  D. Khang,et al.  Electrical and mechanical characterization of stretchable multi-walled carbon nanotubes/polydimethylsiloxane elastomeric composite conductors , 2012 .

[45]  P. C. G. Isaac,et al.  Electrical Resistance Strain Gauges , 1950 .

[46]  L. Frormann,et al.  Fabrication of Extrinsically Conductive Silicone Rubbers with High Elasticity and Analysis of Their Mechanical and Electrical Characteristics , 2010 .

[47]  John A Rogers,et al.  Three-dimensional nanonetworks for giant stretchability in dielectrics and conductors , 2012, Nature Communications.

[48]  T. Ding,et al.  Piezoresistivity of silicone-rubber/carbon black composites excited by Ac electrical field , 2009 .

[49]  John A Rogers,et al.  Controlled buckling of semiconductor nanoribbons for stretchable electronics , 2006, Nature nanotechnology.

[50]  X. Crispin,et al.  Towards polymer-based organic thermoelectric generators , 2012 .

[51]  T. Someya,et al.  A Rubberlike Stretchable Active Matrix Using Elastic Conductors , 2008, Science.

[52]  Sigurd Wagner,et al.  Mechanisms of reversible stretchability of thin metal films on elastomeric substrates , 2006 .

[53]  Yongtaek Hong,et al.  Silver nanowire-embedded PDMS with a multiscale structure for a highly sensitive and robust flexible pressure sensor. , 2015, Nanoscale.

[54]  R. Weiss,et al.  Conductive elastomeric foams prepared by in situ vapor phase polymerization of pyrrole and copolymerization of pyrrole and N-methylpyrrole , 1998 .

[55]  Dermot Diamond,et al.  Inherently conducting polymer modified polyurethane smart foam for pressure sensing , 2005 .

[56]  X. Liu,et al.  Preparation of rubber/graphene oxide composites with in-situ interfacial design , 2015 .

[57]  E. El-Mossalamy,et al.  New smart conducting elastomer blends of bi-based superconductor ceramics nartopartïcles reinforced natural rubber/low-densíty polyethylene for double thermistors, antistatic protectors, and electromagnetic interference shielding effectiweness application , 2009 .

[58]  Yongsung Ji,et al.  Flexible and twistable non-volatile memory cell array with all-organic one diode–one resistor architecture , 2013, Nature Communications.

[59]  J. Noh Cracked titanium film on an elastomeric substrate for highly flexible, transparent, and low-power strain sensors , 2013, Nanoscale Research Letters.

[60]  Goangseup Zi,et al.  Stretchable Active Matrix Temperature Sensor Array of Polyaniline Nanofibers for Electronic Skin , 2016, Advanced materials.

[61]  C. Brabec,et al.  2.5% efficient organic plastic solar cells , 2001 .

[62]  J. Vanfleteren,et al.  Design and Fabrication of Elastic Interconnections for Stretchable Electronic Circuits , 2007, IEEE Electron Device Letters.

[63]  Sangwoo Jin,et al.  Stretchable Array of Highly Sensitive Pressure Sensors Consisting of Polyaniline Nanofibers and Au-Coated Polydimethylsiloxane Micropillars. , 2015, ACS nano.

[64]  Byung Kyu Kim,et al.  Properties of Waterborne Polyurethane/ Functionalized Graphene Sheet Nanocomposites Prepared by an in situ Method , 2009 .

[65]  C. Park,et al.  Fabrication of well-controlled wavy metal interconnect structures on stress-free elastomeric substrates , 2014 .

[66]  J. Vanfleteren,et al.  Polyimide-Enhanced Stretchable Interconnects: Design, Fabrication, and Characterization , 2011, IEEE Transactions on Electron Devices.

[67]  Guangming Chen,et al.  Large-area, stretchable, super flexible and mechanically stable thermoelectric films of polymer/carbon nanotube composites , 2016 .

[68]  Jaeyoung Jang,et al.  Poly(3-hexylthiophene) wrapped carbon nanotube/poly(dimethylsiloxane) composites for use in finger-sensing piezoresistive pressure sensors , 2011 .

[69]  Jonathan N. Coleman,et al.  Development of stiff, strong, yet tough composites by the addition of solvent exfoliated graphene to polyurethane , 2010 .

[70]  K. West,et al.  Highly Stretchable and Conductive Polymer Material Made from Poly(3,4‐ethylenedioxythiophene) and Polyurethane Elastomers , 2007 .

[71]  Zhenan Bao,et al.  A chameleon-inspired stretchable electronic skin with interactive colour changing controlled by tactile sensing , 2015, Nature Communications.

[72]  Lesley Shannon,et al.  Characterization of Stretchable Interconnects Fabricated Using a Low Cost Metallization Transfer Process onto PDMS , 2015 .

[73]  Mohammad F. Islam,et al.  Single‐Walled Carbon Nanotube Aerogel‐Based Elastic Conductors , 2011, Advanced materials.

[74]  A. Bhowmick,et al.  Preparation and properties of nanocomposites based on acrylonitrile–butadiene rubber, styrene–butadiene rubber, and polybutadiene rubber , 2004 .

[75]  Chaoyi Yan,et al.  Stretchable graphene thermistor with tunable thermal index. , 2015, ACS nano.

[76]  W. Su,et al.  Stretchable organic memory: toward learnable and digitized stretchable electronic applications , 2014 .

[77]  Dajun Wu,et al.  Silicone rubber/graphite nanosheet electrically conducting nanocomposite with a low percolation threshold , 2007 .

[78]  N. Chauhan,et al.  A Review: Conducting Polymers and Their Applications. , 2014 .

[79]  M. Saboungi,et al.  Improving reinforcement of natural rubber by networking of activated carbon nanotubes , 2008 .

[80]  Robert Puers,et al.  Capacitive sensors: When and how to use them☆ , 1993 .

[81]  R. Service,et al.  Solar energy. Outlook brightens for plastic solar cells. , 2011, Science.

[82]  Zhen Zheng,et al.  The thermal and mechanical properties of a polyurethane/multi-walled carbon nanotube composite , 2006 .

[83]  S. Cartmell,et al.  Conductive polymers: towards a smart biomaterial for tissue engineering. , 2014, Acta biomaterialia.

[84]  N. S. Sariciftci,et al.  Efficiency of bulk-heterojunction organic solar cells , 2013, Progress in polymer science.

[85]  A. M. Mathew,et al.  Styrene butadiene copolymer-based transparent conducting thin films , 2014 .

[86]  Meifang Zhu,et al.  The use of a carbon nanotube layer on a polyurethane multifilament substrate for monitoring strains as large as 400 , 2012 .

[87]  S. Ko,et al.  Highly Stretchable and Highly Conductive Metal Electrode by Very Long Metal Nanowire Percolation Network , 2012, Advanced materials.

[88]  Jong-Hyun Ahn,et al.  Stretchable electronics: materials, architectures and integrations , 2012 .

[89]  Yonggang Huang,et al.  Materials and Mechanics for Stretchable Electronics , 2010, Science.

[90]  M. Kaltenbrunner,et al.  Ultrathin and lightweight organic solar cells with high flexibility , 2012, Nature Communications.

[91]  D. Nezich,et al.  A novel class of strain gauges based on layered percolative films of 2D materials. , 2012, Nano letters.

[92]  N. Kotov,et al.  Stretchable nanoparticle conductors with self-organized conductive pathways , 2013, Nature.

[93]  Bong Hoon Kim,et al.  Stretchable, transparent graphene interconnects for arrays of microscale inorganic light emitting diodes on rubber substrates. , 2011, Nano letters.

[94]  Ok Chan Jeong,et al.  Measurement of nonlinear mechanical properties of PDMS elastomer , 2011 .

[95]  M. Paoli,et al.  A conductive elastomer based on EPDM and polyaniline: II. Effect of the crosslinking method , 2002 .

[96]  Sigurd Wagner,et al.  Stretchable Interconnects for Elastic Electronic Surfaces , 2005, Proceedings of the IEEE.

[97]  J. Rogers,et al.  Stretchable Electronics: Materials Strategies and Devices , 2008 .

[98]  Liliane Bokobza,et al.  MULTIWALL CARBON NANOTUBE ELASTOMERIC COMPOSITES: A REVIEW , 2007 .

[99]  R. Ruoff,et al.  Stretchable and highly sensitive graphene-on-polymer strain sensors , 2012, Scientific Reports.

[100]  U. Chung,et al.  Highly Stretchable Resistive Pressure Sensors Using a Conductive Elastomeric Composite on a Micropyramid Array , 2014, Advanced materials.

[101]  Seung Hwan Ko,et al.  A Hyper‐Stretchable Elastic‐Composite Energy Harvester , 2015, Advanced materials.

[102]  Benjamin C. K. Tee,et al.  Stretchable Organic Solar Cells , 2011, Advanced materials.

[103]  Yonggang Huang,et al.  A curvy, stretchy future for electronics , 2009, Proceedings of the National Academy of Sciences.

[104]  G. S. Holister,et al.  Strain gauge technology , 1982 .

[105]  Jacky W Y Lam,et al.  Functional polyacetylenes. , 2005, Accounts of chemical research.

[106]  S. Pandey,et al.  Nanocomposite based flexible ultrasensitive resistive gas sensor for chemical reactions studies , 2013, Scientific Reports.

[107]  B. Cho,et al.  A wearable thermoelectric generator fabricated on a glass fabric , 2014 .

[108]  Yonggang Huang,et al.  Stretchable GaAs Photovoltaics with Designs That Enable High Areal Coverage , 2011, Advanced materials.

[109]  Xiaoming Tao,et al.  High stretchable MWNTs/polyurethane conductive nanocomposites , 2011 .

[110]  Yuliang Yang,et al.  Preparation, properties and applications of polypyrroles , 2001 .

[111]  Yonggang Huang,et al.  Stretchable and Foldable Silicon Integrated Circuits , 2008, Science.

[112]  정운룡,et al.  Highly Stretchable Polymer Transistors Consisting Entirely of Stretchable Device Components , 2014 .

[113]  Krishnan Balasubramaniam,et al.  Functionalized graphene reinforced thermoplastic nanocomposites as strain sensors in structural health monitoring , 2011 .

[114]  Q. Pei,et al.  Silver nanowire percolation network soldered with graphene oxide at room temperature and its application for fully stretchable polymer light-emitting diodes. , 2014, ACS nano.

[115]  M. Nogi,et al.  Printable and Stretchable Conductive Wirings Comprising Silver Flakes and Elastomers , 2011, IEEE Electron Device Letters.

[116]  K. Kojio,et al.  Control of Mechanical Properties of Thermoplastic Polyurethane Elastomers by Restriction of Crystallization of Soft Segment , 2010, Materials.

[117]  T. Tamai Electrical Properties of Conductive Elastomer as Electrical Contact Material , 1982 .

[118]  Ji-Beom Yoo,et al.  Highly Stretchable Piezoelectric‐Pyroelectric Hybrid Nanogenerator , 2014, Advanced materials.