Blue-, green-, and red-light emission from Si+-implanted thermal SiO2 films on crystalline silicon

Abstract Three primary color emission bands, 467 nm (~ 2.7 eV), 540 nm (~ 2.3 eV), and 680 nm (~ 1.8 eV), were observed from Si+-implanted thermal SiO2 films on crystalline Si under ultraviolet excitation at room temperature. The blue emission is caused by oxygen vacancies in the films, and the green emission may also be caused by oxygen vacancies. The red emission, observed in 1100 °C annealed samples, is due to nanocrystalline Si precipitation.

[1]  Tsutomu Shimizu-Iwayama,et al.  Visible photoluminescence in Si+‐implanted thermal oxide films on crystalline Si , 1994 .

[2]  N. Haegel,et al.  Interpretation of photoluminescence excitation spectroscopy of porous Si layers , 1993 .

[3]  H. Ogawa,et al.  Quantum size effects on photoluminescence in ultrafine Si particles , 1990 .

[4]  John F. Conley,et al.  Observation and electronic characterization of ‘‘new’’ E′ center defects in technologically relevant thermal SiO2 on Si: An additional complexity in oxide charge trapping , 1994 .

[5]  G. Ghislotti,et al.  Room‐temperature visible luminescence from silicon nanocrystals in silicon implanted SiO2 layers , 1995 .

[6]  M. Martini,et al.  A 1.9 eV photoluminescence induced by 4 eV photons in high‐purity wet synthetic silica , 1993 .

[7]  L. Canham Silicon quantum wire array fabrication by electrochemical and chemical dissolution of wafers , 1990 .

[8]  Hideki Hashimoto,et al.  Strong blue light emission from an oxygen‐containing Si fine structure , 1993 .

[9]  Nakamura,et al.  Photoluminescence from defect centers in high-purity silica glasses observed under 7.9-eV excitation. , 1992, Physical review. B, Condensed matter.

[10]  Kastner,et al.  Time-resolved photoluminescence in amorphous silicon dioxide. , 1987, Physical review. B, Condensed matter.

[11]  Yoshimichi Ohki,et al.  Radiation Effects on Pure Silica Core Optical Fibers by γ-Rays: Relation between 2 eV Band and Non-Bridging Oxygen Hole Centers , 1986 .

[12]  X. Bao,et al.  Study of photoluminescence in nanocrystalline silicon/amorphous silicon multilayers , 1995 .

[13]  Rolf E. Hummel,et al.  Novel technique for preparing porous silicon , 1992 .

[14]  Semi-Insulating Polycrystalline-Silicon (SIPOS) Passivation Technology , 1976 .

[15]  Y. Mochizuki,et al.  Effects of thermal annealing on porous silicon photoluminescence dynamics , 1992 .

[16]  A. A. Seraphin,et al.  SYNTHESIS AND PROCESSING OF SILICON NANOCRYSTALLITES USING A PULSED LASER ABLATION SUPERSONIC EXPANSION METHOD , 1994 .

[17]  Y. Hama,et al.  2.7-eV luminescence in as-manufactured high-purity silica glass. , 1989, Physical review letters.