Gas sensors based on deposited single-walled carbon nanotube networks for DMMP detection

Sensors based on single-walled carbon nanotube (SWNT) networks were fabricated and their sensitive properties for the nerve agent stimulant dimethyl methylphosphonate (DMMP) vapor were investigated at room temperature. The SWNT networks were deposited on oxidized silicon surface functionalized with 3-aminopropyltrimethysilane (APS). Combining with a traditional silicon process, SWNT-based gas sensors were made at a wafer scale. The effects of the density of deposited SWNTs on the sensor response were studied. The excellent response is obtained under a density of 30-40 tubes microm(-2). The sensors exhibit high resistance response, fast response time, rapid recovery and good reproducibility for DMMP vapor. The deposited SWNT sensors will be potentially extended to large-scale fabrication.

[1]  Jing Sun,et al.  Production of aqueous colloidal dispersions of carbon nanotubes. , 2003, Journal of colloid and interface science.

[2]  Guodong Liu,et al.  Electrochemical sensor for organophosphate pesticides and nerve agents using zirconia nanoparticles as selective sorbents. , 2005, Analytical chemistry.

[3]  Alexander Star,et al.  Gas sensor array based on metal-decorated carbon nanotubes. , 2006, The journal of physical chemistry. B.

[4]  C. Tripp,et al.  Dual WO(3) based sensors to selectively detect DMMP in the presence of alcohols. , 2007, Talanta.

[5]  Seung-Chul Ha,et al.  Gas sensor measurement system capable of sampling volatile organic compounds (VOCs) in wide concentration range , 2007 .

[6]  Douglas R. Kauffman,et al.  Carbon nanotube gas and vapor sensors. , 2008, Angewandte Chemie.

[7]  G. Martin Milner Detection/classification/quantification of chemical agents using an array of surface acoustic wave (SAW) devices , 2005, SPIE Defense + Commercial Sensing.

[8]  E. S. Snow,et al.  Chemical Detection with a Single-Walled Carbon Nanotube Capacitor , 2005, Science.

[9]  R. A. McGill,et al.  The “NRL-SAWRHINO”: a nose for toxic gases , 2000 .

[10]  Duk-Dong Lee,et al.  Classification of chemical warfare agents using thick film gas sensor array , 2005 .

[11]  Jae Do Lee,et al.  Adsorption of NH3 and NO2 molecules on carbon nanotubes , 2001 .

[12]  Mikhail Kozlov,et al.  Flexible carbon nanotube sensors for nerve agent simulants , 2006, Nanotechnology.

[13]  R. A. McGill,et al.  Nerve agent detection using networks of single-walled carbon nanotubes , 2003 .

[14]  G. Fedder,et al.  Electrostatically actuated resonant microcantilever beam in CMOS technology for the detection of chemical weapons , 2005, IEEE Sensors Journal.

[15]  Gregory P. Harmer,et al.  Detection of chemical warfare agents using nanostructured metal oxide sensors , 2005 .

[16]  Junya Suehiro,et al.  Controlled fabrication of carbon nanotube NO2 gas sensor using dielectrophoretic impedance measurement , 2005 .

[17]  W. D. de Heer,et al.  Carbon Nanotubes--the Route Toward Applications , 2002, Science.

[18]  Byeong Kwon Ju,et al.  Multiwall carbon nanotube gas sensor fabricated using thermomechanical structure , 2005 .

[19]  Kong,et al.  Nanotube molecular wires as chemical sensors , 2000, Science.

[20]  B. Kowalski,et al.  Chemical piezoelectric sensor and sensor array characterization , 1986 .

[21]  D. H. Moore Long term health effects of low dose exposure to nerve agent , 1998, Journal of Physiology-Paris.

[22]  E. Snow,et al.  Capacitance and conductance of single-walled carbon nanotubes in the presence of chemical vapors. , 2005, Nano letters.

[23]  N. Myung,et al.  Recent progress in carbon nanotube-based gas sensors , 2008, Nanotechnology.

[24]  Taehyung Kim,et al.  Sensors and sensor arrays based on conjugated polymers and carbon nanotubes , 2002 .

[25]  Franz Kreupl,et al.  Carbon nanotubes in interconnect applications , 2002 .

[26]  Hai-Feng Ji,et al.  Organophosphorus hydrolase multilayer modified microcantilevers for organophosphorus detection. , 2007, Biosensors & bioelectronics.

[27]  Nathan S. Lewis,et al.  Detection and classification characteristics of arrays of carbon black/organic polymer composite chemiresistive vapor detectors for the nerve agent simulants Dimethylmethylphosphonate and Diisopropy , 2002, SPIE Defense + Commercial Sensing.

[28]  C. Dejous,et al.  Detection of GB and DMMP vapors by Love wave acoustic sensors using strong acidic fluoride polymers , 2004, IEEE Sensors Journal.

[29]  Jijun Zhao,et al.  Gas molecule adsorption in carbon nanotubes and nanotube bundles , 2002 .

[30]  Jose Maria Kenny,et al.  Carbon nanotubes as new materials for gas sensing applications , 2004 .

[31]  Todd E. Mlsna,et al.  Chemicapacitive Microsensors for Chemical Warfare Agent and Toxic Industrial Chemical Detection , 2006 .

[32]  Jay W. Grate,et al.  Hybrid Organic/Inorganic Copolymers with Strongly Hydrogen-Bond Acidic Properties for Acoustic Wave and Optical Sensors , 1997 .

[33]  Qiang Zhao,et al.  Electrochemical sensors based on carbon nanotubes , 2002 .

[34]  F. Worek,et al.  Diagnostic aspects of organophosphate poisoning. , 2005, Toxicology.

[35]  Russell Chung,et al.  Evaluation of SAW chemical sensors for air filter lifetime and performance monitoring , 1998 .

[36]  L Szinicz,et al.  History of chemical and biological warfare agents. , 2005, Toxicology.

[37]  J. M. Ballingall,et al.  The operation of metalorganic bubblers at reduced pressure , 1990 .

[38]  Antonio J. Ricco,et al.  Chemically Sensitive Surface Acoustic Wave Devices Employing a Self-Assembled Composite Monolayer Film: Molecular Specificity and Effects Due to Self-Assembled Monolayer Adsorption Time and Gold Surface Morphology , 1996 .

[39]  S. Milinkovic,et al.  Evaluation of coating materials used on piezoelectric sensors for the detection of organophosphorus compounds in the vapour phase , 1992 .

[40]  J. White,et al.  Surface chemistry of dimethyl methylphosphonate on rhodium(100) , 1985 .

[41]  Michael S Strano,et al.  Charge transfer from metallic single-walled carbon nanotube sensor arrays. , 2006, The journal of physical chemistry. B.

[42]  M. W. Ellzy,et al.  Chemical warfare agent detection using MEMS-compatible microsensor arrays , 2005, IEEE Sensors Journal.

[43]  Junsheng Yu,et al.  PVDF coated quartz crystal microbalance sensor for DMMP vapor detection , 2007 .

[44]  Alan Gelperin,et al.  DNA-decorated carbon nanotubes for chemical sensing. , 2005 .