论文信息 - Mild, Efficient and Selective Opening of Epoxides with Alcohols Catalyzed by Ceric(IV) Ammonium Nitrate

Mild, Efficient and Selective Opening of Epoxides with Alcohols Catalyzed by Ceric(IV) Ammonium Nitrate

Abstract Commercially available Ceric(IV) Ammonium Nitrate (CAN) catalyzes nucleophilic ring opening of epoxides in primary, secondary and tertiary alcohols under mild conditions. The corresponding β-alkoxy-alcohols were obtained with high regio and stereoselectivity in high yields.

N. Iranpoor | I. M. Baltork | N. Iranpoor*

[1] S. Roberts,et al. Conversion of Some Cephalosporins Into the 2-Alkoxy Derivatives Using Alkanolic Ceric (IV) Ammonium Nitrate , 1985 .

[2] J. Otera,et al. Highly regioselective ring opening of epoxides with alcohols catalyzed by organotin phosphate condensates , 1985 .

[3] J. Smith. Synthetically Useful Reactions of Epoxides , 1984 .

[4] N. Iranpoor,et al. Ceric Trihydroxy Hydroperoxide Ce(OH)3O2H, A Regenerable, Mild, and A Versatile Reagent for the Oxidation of Organic Compounds , 1984 .

[5] H. Firouzabadi,et al. Ceric Triethylammonium Nitrate [Ce(Et3NH)2l(NO3)6; An Efficient Oxidant for the Oxidation of Benzylic Alcohols and α-Hydroxy Ketones to Their Corresponding Carbonyl Compounds Under Mild Conditions , 1983 .

[6] G. Olah,et al. Synthetic Methods and Reactions; 681. Nafion-H-Catalyzed Hydration and Methanolysis of Epoxides , 1981 .

[7] D. Z. Rogers,et al. Organic reactions at alumina surfaces. Displacement reactions effected by alcohols, thiols, and acetic acid on dehydrated alumina. , 1975 .

[8] W. S. Trahanovsky,et al. Oxidation of organic compounds with cerium(IV). V. The substituent effect on the rate of the one-electron oxidative cleavage of 2-aryl-1-phenylethanols , 1968 .

[9] W. Kumler,et al. The Relation between Chemical Structure and Bacteriostatic Activity of Sulfanilamide Type Compounds , 1943 .