Synthesis, structure and formation pathways of new Fe-S complexes containing [Fe2S2]-units in different valences, [Fe2S2(CO)4(PPh3)2], [Fe3S2(CO)6(PPh3)3] and [Fe4S2(CO)10]2- and the origin of the [Fe2S2]-unit in metal-[Fe2S2(CO)6] complexes

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