Thermal Chemical Vapor Deposition of Diamond from Methane-Hydrogen Gas System Pyrolized at Low Temperature (1450°C)
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Thermal chemical vapor deposition (CVD) of diamond using a nozzle or a plate heated at much lower temperature than a conventional hot filament CVD was reported. The lowest temperature achieved for the pyrolysis of the material gas was 1450°C for the methane-hydrogen mixture system. The gas-phase chemistry was then discussed in relation to both the experimentation and the corresponding numerical simulation.
[1] Yoichiro Sato,et al. Vapor Deposition of Diamond Particles from Methane , 1982 .