Modelling negative bias temperature instabilities in advanced p-MOSFETs

Abstract The decrease of the threshold voltage V th of p-channel metal-oxide semiconductor field effect transistors (p-MOSFET) with ultrathin gate dielectric layers under negative bias temperature stress is studied. A degradation model is developed, that accounts for the generation of Si 3 Si (P b0 ) centers and bulk oxide defects, induced by the tunnelling of electrons or holes through the gate dielectric layer during the electrical stress. The model predicts that V th shifts are mainly due to the tunnelling of holes at low gate bias | V G |, typically below 1.5 V , while electrons are mainly responsible for these shifts at higher | V G |. Consequently, device lifetime at operating voltage, based on V th shifts, should not be extrapolated from measurements performed at high gate bias. The impact of nitrogen incorporated at the Si/dielectric interface on V th shifts is next investigated. The acceleration of device degradation when the amount of nitrogen increases is attributed to the increase in local interfacial strain, induced by the increase in bonding constraints, as well as to the increase in the density of SiNSi strained bonds, that act as trapping centers of hydrogen species released during the electrical stress. Finally, V th shifts in p-MOSFET with Hf y SiO x gate layers and SiO 2 /Hf y SiO x gate stacks are simulated, taking into account the generation of P b0 centers induced by the injection of electrons through the structure. It is found that the transistor lifetime, based on threshold voltage shifts, is improved in SiO 2 /Hf y SiO x gate stacks as compared to single Hf y SiO x layers. This finding is attributed to the beneficial presence of the SiO 2 interfacial layer, which allows the relaxation of strain at the Si/dielectric interface.

[1]  L. Pantisano,et al.  Origin of the threshold voltage instability in SiO2/HfO2 dual layer gate dielectrics , 2003, IEEE Electron Device Letters.

[2]  E. H. Nicollian,et al.  Mechanism of negative‐bias‐temperature instability , 1991 .

[3]  Andre Stesmans,et al.  Influence of interface relaxation on passivation kinetics in H2 of coordination Pb defects at the (111)Si/SiO2 interface revealed by electron spin resonance , 2002 .

[4]  Eiichi Murakami,et al.  Effect of nitrogen at SiO2/Si interface on reliability issues—negative-bias-temperature instability and Fowler–Nordheim-stress degradation , 2002 .

[5]  D. Adler,et al.  Quantum Mechanics For Applied Physics And Engineering , 1981 .

[6]  R. Wallace,et al.  High-κ gate dielectrics: Current status and materials properties considerations , 2001 .

[7]  T. Mogami,et al.  Bias temperature instability in scaled p/sup +/ polysilicon gate p-MOSFET's , 1999 .

[8]  Masanobu Miyao,et al.  Incorporation of N into Si/SiO2 interfaces: Molecular orbital calculations to evaluate interface strain and heat of reaction , 1999 .

[9]  R. Wallace,et al.  Hafnium and zirconium silicates for advanced gate dielectrics , 2000 .

[10]  M. Houssa,et al.  Impact of Nitrogen on Negative Bias Temperature Instability in p-Channel MOSFETs , 2003 .

[11]  Andre Stesmans,et al.  Polarity dependence of defect generation in ultrathin SiO2/ZrO2 gate dielectric stacks , 2001 .

[12]  Luigi Colombo,et al.  Application of HfSiON as a gate dielectric material , 2002 .

[13]  James H. Stathis,et al.  Anode hole injection, defect generation, and breakdown in ultrathin silicon dioxide films , 2001 .

[14]  Andre Stesmans,et al.  Model for defect generation at the (1 0 0)Si/SiO2 interface during electron injection in MOS structures , 2003 .

[15]  Veena Misra,et al.  Bonding constraints and defect formation at interfaces between crystalline silicon and advanced single layer and composite gate dielectrics , 1999 .

[16]  Ogawa,et al.  Generalized diffusion-reaction model for the low-field charge-buildup instability at the Si-SiO2 interface. , 1995, Physical review. B, Condensed matter.

[17]  C. R. Helms,et al.  The silicon-silicon dioxide system: Its microstructure and imperfections , 1994 .

[18]  Andre Stesmans,et al.  Model for interface defect and positive charge generation in ultrathin SiO2/ZrO2 gate dielectric stacks , 2002 .

[19]  A. Stesmans Dissociation kinetics of hydrogen-passivated Pb defects at the (111)Si/SiO2 interface , 2000 .

[20]  Arnold,et al.  Theory of high-field electron transport and impact ionization in silicon dioxide. , 1994, Physical review. B, Condensed matter.

[21]  T. P. Chen,et al.  Nitrogen-enhanced negative bias temperature instability: An insight by experiment and first-principle calculations , 2003 .

[22]  J. F. Conley,et al.  What can electron paramagnetic resonance tell us about the Si/SiO2 system? , 1998 .

[23]  Byung Jin Cho,et al.  Origin of temperature-sensitive hole current at low gate voltage regime in ultrathin gate oxide , 2000 .

[24]  J. Robertson Band offsets of wide-band-gap oxides and implications for future electronic devices , 2000 .

[25]  Richard Carter,et al.  Constant voltage stress induced degradation in HfO2/SiO2 gate dielectric stacks , 2002 .

[26]  Alfredo Pasquarello,et al.  Dielectric constants of Zr silicates: a first-principles study. , 2002, Physical review letters.

[27]  Stathis,et al.  Atomic hydrogen reactions with Pb centers at the (100) Si/SiO2 interface. , 1994, Physical review letters.

[28]  Dennis B. Brown,et al.  Time dependence of radiation‐induced interface trap formation in metal‐oxide‐semiconductor devices as a function of oxide thickness and applied field , 1991 .