Secondary reactions during acrylate radical polymerization: Determining their rate coefficients
暂无分享,去创建一个
[1] Dagmar R. D’hooge,et al. Cost‐efficient modeling of distributed molar mass and topological variations in graft copolymer synthesis by upgrading the method of moments , 2021, AIChE Journal.
[2] Dagmar R. D’hooge,et al. Bridging principal component analysis and method of moments based parameter estimation for grafting of polybutadiene with styrene , 2021 .
[3] Dagmar R. D’hooge,et al. Translating Simulated Chain Length and Molar Mass Distributions in Chain‐Growth Polymerization for Experimental Comparison and Mechanistic Insight , 2021, Macromolecular Theory and Simulations.
[4] W. Kaminsky. polyacrylates , 2020, Catalysis from A to Z.
[5] M. Soroush,et al. Experimental and Mechanistic Modeling Study of Self-Initiated High-Temperature Polymerization of Ethyl Acrylate , 2020 .
[6] F. Ruipérez. Application of quantum chemical methods in polymer chemistry , 2019, International Reviews in Physical Chemistry.
[7] Anil B. Vir,et al. From n-butyl acrylate Arrhenius parameters for backbiting and tertiary propagation to β-scission via stepwise pulsed laser polymerization , 2019, Polymer Chemistry.
[8] Anil B. Vir,et al. Access to the β-scission rate coefficient in acrylate radical polymerization by careful scanning of pulse laser frequencies at elevated temperature , 2018 .
[9] J. Asua,et al. Mid-Chain Radical Migration in the Radical Polymerization of n-Butyl Acrylate , 2018, Polymers.
[10] Gregory T. Russell,et al. Effects of Chain Transfer Agent and Temperature on Branching and β-Scission in Radical Polymerization of 2-Ethylhexyl Acrylate , 2018 .
[11] M. Buback,et al. Termination, Propagation, and Transfer Kinetics of Midchain Radicals in Methyl Acrylate and Dodecyl Acrylate Homopolymerization , 2018 .
[12] J. Asua,et al. Radical polymerization of acrylic monomers: An overview , 2017 .
[13] Dagmar R. D’hooge,et al. Kinetic Monte Carlo Generation of Complete Electron Spray Ionization Mass Spectra for Acrylate Macromonomer Synthesis , 2017 .
[14] Dagmar R. D’hooge,et al. Kinetic Monte Carlo Modeling Extracts Information on Chain Initiation and Termination from Complete PLP-SEC Traces , 2017 .
[15] Dagmar R. D’hooge,et al. An alternative method to estimate the bulk backbiting rate coefficient in acrylate radical polymerization , 2016 .
[16] J. Asua,et al. Intermolecular Transfer to Polymer in the Radical Polymerization of n-Butyl Acrylate , 2016 .
[17] M. Buback,et al. Propagation and Chain-Length-Dependent Termination Rate Coefficients Deduced from a Single SP–PLP–EPR Experiment , 2016 .
[18] Benjamin Wenn,et al. Kilohertz Pulsed-Laser-Polymerization: Simultaneous Determination of Backbiting, Secondary, and Tertiary Radical Propagation Rate Coefficients for tert-Butyl Acrylate. , 2016, Macromolecular rapid communications.
[19] J. Leiza,et al. Analyzing the discrepancies in the activation energies of the backbiting and β-scission reactions in the radical polymerization of n-butyl acrylate , 2016 .
[20] D. Moscatelli,et al. On the Use of Quantum Chemistry for the Determination of Propagation, Copolymerization, and Secondary Reaction Kinetics in Free Radical Polymerization , 2015 .
[21] A. Kajiwara. A combination of Electron Spin Resonance spectroscopy/atom transfer radical polymerization (ESR/ATRP) techniques for fundamental investigation of radical polymerizations of (meth)acrylates , 2015 .
[22] M. Buback,et al. Novel Access to Propagation Rate Coefficients of Radical Polymerization by the SP–PLP–EPR Method , 2015 .
[23] N. Papayannakos,et al. Group Additive Kinetics for Hydrogen Transfer Between Oxygenates. , 2015, The journal of physical chemistry. A.
[24] M. Soroush,et al. Theoretical Study of Intermolecular Chain Transfer to Polymer Reactions of Alkyl Acrylates , 2015 .
[25] M. Buback,et al. Chain-Length-Dependent Termination of Styrene Bulk Homopolymerization Studied by SP−PLP−EPR , 2015 .
[26] M. Soroush,et al. Backbiting and β‐scission reactions in free‐radical polymerization of methyl acrylate , 2014 .
[27] D. Moscatelli,et al. Quantum mechanical investigation on bimolecular hydrogen abstractions in butyl acrylate-based free radical polymerization processes. , 2014, The journal of physical chemistry. A.
[28] Gregory T. Russell,et al. Critically evaluated rate coefficients in radical polymerization – 7. Secondary-radical propagation rate coefficients for methyl acrylate in the bulk , 2014 .
[29] M. Buback,et al. Detailed Investigations into Radical Polymerization Kinetics by Highly Time‐Resolved SP–PLP–EPR , 2013 .
[30] M. Coote,et al. First principles modelling of free-radical polymerisation kinetics , 2013 .
[31] D. Moscatelli,et al. Quantum chemistry investigation of secondary reaction kinetics in acrylate-based copolymers. , 2013, The journal of physical chemistry. A.
[32] J. Vandenbergh,et al. Synthesis of macromonomers from high-temperature activation of nitroxide mediated polymerization (NMP)-made polyacrylates , 2013 .
[33] M. Soroush,et al. Computational study of chain transfer to monomer reactions in high-temperature polymerization of alkyl acrylates. , 2013, The journal of physical chemistry. A.
[34] D. Moscatelli,et al. A Density Functional Theory Study of Secondary Reactions in n‐Butyl Acrylate Free Radical Polymerization , 2013 .
[35] J. Vandenbergh,et al. Macromonomers from AGET Activation of Poly(n-butyl acrylate) Precursors: Radical Transfer Pathways and Midchain Radical Migration , 2012 .
[36] A. Laschewsky,et al. Influencing the phase transition temperature of poly(methoxy diethylene glycol acrylate) by molar mass, end groups, and polymer architecture , 2012 .
[37] L. Broadbelt,et al. Kinetic Study of 1,5‐Hydrogen Transfer Reactions of Methyl Acrylate and Butyl Acrylate Using Quantum Chemistry , 2012 .
[38] K. Matyjaszewski,et al. SP-PLP-EPR Measurement of ATRP Deactivation Rate , 2012 .
[39] J. Barth,et al. SP-PLP-EPR Study into Termination and Transfer Kinetics of Non-Ionized Acrylic Acid Polymerized in Aqueous Solution , 2012 .
[40] Gregory T. Russell,et al. Chain‐Length‐Dependent Termination in Radical Polymerization of Acrylates , 2011 .
[41] J. Barth,et al. SP-PLP-EPR Study into the Termination Kinetics of Methacrylic Acid Radical Polymerization in Aqueous Solution , 2011 .
[42] C. Schütte,et al. A Hybrid Galerkin-Monte-Carlo Approach to Higher-Dimensional Population Balances in Polymerization Kinetics , 2010 .
[43] A. N. Nikitin,et al. Effect of Intramolecular Transfer to Polymer on Stationary Free-Radical Polymerization of Alkyl Acrylates, 5 – Consideration of Solution Polymerization up to High Temperatures† , 2010 .
[44] J. Barth,et al. SP‐PLP‐EPR—A Novel Method for Detailed Studies into the Termination Kinetics of Radical Polymerization , 2010 .
[45] J. Barth,et al. Termination and Transfer Kinetics of Butyl Acrylate Radical Polymerization Studied via SP-PLP-EPR , 2010 .
[46] A. N. Nikitin,et al. Consideration of Macromonomer Reactions in n-Butyl Acrylate Free Radical Polymerization. , 2009, Macromolecular rapid communications.
[47] J. Barth,et al. SP-PLP-EPR Investigations into the Chain-Length-Dependent Termination of Methyl Methacrylate Bulk Polymerization. , 2009, Macromolecular rapid communications.
[48] C. Barner‐Kowollik,et al. Optimum Reaction Conditions for the Synthesis of Macromonomers Via the High‐Temperature Polymerization of Acrylates , 2009 .
[49] K. Matyjaszewski. Controlled/Living Radical Polymerization: Progress in ATRP , 2009 .
[50] A. N. Nikitin,et al. The Effect of Intramolecular Transfer to Polymer on Stationary Free-Radical Polymerization of Alkyl Acrylates, 3 – Consideration of Solution Polymerization up to High Conversions† , 2009 .
[51] M. Wilhelm,et al. Detection and quantification of branching in polyacrylates by size-exclusion chromatography (SEC) and melt-state 13C NMR spectroscopy , 2009 .
[52] Dagmar R. D’hooge,et al. Methodology for Kinetic Modeling of Atom Transfer Radical Polymerization , 2009 .
[53] K. Dam-Johansen,et al. Anticorrosive coatings: a review , 2009 .
[54] Michael Wulkow,et al. Computer Aided Modeling of Polymer Reaction Engineering—The Status of Predici, I‐Simulation , 2008 .
[55] C. Barner‐Kowollik,et al. Self-directed formation of uniform unsaturated macromolecules from acrylate monomers at high temperatures , 2008 .
[56] A. N. Nikitin,et al. Determination of Intramolecular Chain Transfer and Midchain Radical Propagation Rate Coefficients for Butyl Acrylate by Pulsed Laser Polymerization , 2007 .
[57] J. D. L. Fuente,et al. Glass transition temperature of allyl methacrylate‐n‐butyl acrylate gradient copolymers in dependence on chemical composition and molecular weight , 2007 .
[58] Philipp Vana,et al. Z-RAFT star polymerizations of acrylates : Star coupling via intermolecular chain transfer to polymer , 2007 .
[59] A. Kajiwara. Studying the Fundamentals of Radical Polymerization Using ESR in Combination with Controlled Radical Polymerization Methods , 2007 .
[60] I. Lacík,et al. Critically evaluated rate coefficients for free-radical polymerization Part 6: Propagation rate coefficient of methacrylic acid in aqueous solution (IUPAC Technical Report) , 2007 .
[61] A. N. Nikitin,et al. Effect of Intramolecular Transfer to Polymer on Stationary Free Radical Polymerization of Alkyl Acrylates, 2 , 2006 .
[62] David C. Rohlfing,et al. SEC-MALS method for the determination of long-chain branching and long-chain branching distribution in polyethylene , 2005 .
[63] A. N. Nikitin,et al. The effect of intramolecular transfer to polymer on stationary free radical polymerization of alkyl acrylates , 2005 .
[64] M. Dubé,et al. Emulsion‐Based Pressure‐Sensitive Adhesives: A Review , 2004 .
[65] José M. Asua,et al. Critically Evaluated Rate Coefficients for Free‐Radical Polymerization, 5, , 2004 .
[66] R. Hutchinson,et al. Secondary Reactions in the High-Temperature Free Radical Polymerization of Butyl Acrylate , 2004 .
[67] M. Buback,et al. Free-Radical Termination Kinetics Studied Using a Novel SP-PLP-ESR Technique , 2004 .
[68] G. Marin,et al. Ab Initio Calculations for Hydrocarbons: Enthalpy of Formation, Transition State Geometry, and Activation Energy for Radical Reactions , 2003 .
[69] Thomas P. Davis,et al. Critically Evaluated Rate Coefficients for Free-Radical Polymerization, 4†‡ , 2003 .
[70] G. Arzamendi,et al. Effect of the intramolecular chain transfer to polymer on PLP/SEC experiments of alkyl acrylates , 2003 .
[71] G. Arzamendi,et al. Evidence of Branching in Poly(butyl acrylate) Produced in Pulsed‐Laser Polymerization Experiments , 2003 .
[72] Sabine Beuermann,et al. Rate coefficients of free-radical polymerization deduced from pulsed laser experiments , 2002 .
[73] P. Castignolles,et al. Pulsed-laser radical polymerization and propagation kinetic parameters of some alkyl acrylates , 2001 .
[74] José M. Asua,et al. Modeling of Seeded Semibatch Emulsion Polymerization of n-BA , 2001 .
[75] A. Herk. Pulsed initiation polymerization applied to acrylate monomers: Sources of experimental failure , 2001 .
[76] G. Arzamendi,et al. A Decrease in Effective Acrylate Propagation Rate Constants Caused by Intramolecular Chain Transfer , 2000 .
[77] Thomas P. Davis,et al. Critically evaluated rate coefficients for free‐radical polymerization, 2.. Propagation rate coefficients for methyl methacrylate , 2000 .
[78] R. Gilbert,et al. Measurement of transfer constant for butyl acrylate free-radical polymerization , 1998 .
[79] P. Lovell,et al. Chain transfer to polymer in free-radical solution polymerization of 2-ethylhexyl acrylate studied by NMR spectroscopy , 1998 .
[80] D. Paquet,et al. Determination of Free-Radical Propagation Rate Coefficients of Butyl, 2-Ethylhexyl, and Dodecyl Acrylates by Pulsed-Laser Polymerization , 1996 .
[81] M. Wulkow,et al. The simulation of molecular weight distributions in polyreaction kinetics by discrete Galerkin methods , 1996 .
[82] R. Gilbert,et al. Pulsed-Laser Polymerization Measurements of the Propagation Rate Coefficient for Butyl Acrylate , 1996 .
[83] K. O'driscoll,et al. Monte Carlo simulation of pulsed laser polymerization , 1994 .
[84] A. Mau,et al. Evaluation of the kinetic-parameters for styrene polymerization and their chain-length dependence by kinetic simulation and pulsed-laser photolysis , 1993 .
[85] Gregory T. Russell,et al. Consistent values of rate parameters in free radical polymerization systems. II. Outstanding dilemmas and recommendations , 1992 .
[86] M. Winnik,et al. Determination of propagation rate constants using a pulsed laser technique , 1989 .
[87] O. F. Olaj,et al. The laser flash-initiated polymerization as a tool of evaluating (individual) kinetic constants of free radical polymerization, 3. Information from degrees of polymerization† , 1987 .
[88] F. Tüdös,et al. Kinetics of Free Radical Polymerization. XXXVIII. Solvent Effect on the Degree of Polymerization of Poly(ethyl Acrylates) and Poly(methyl Acrylates) , 1982 .
[89] V. V. Sokolov,et al. Kinetics of laser-initiated polymerization and molecular-weight distribution of the resultant polymer , 1977 .
[90] S. Patra,et al. Kinetics of polymerization of benzyl acrylate in bulk , 1968 .
[91] M. Gopalan,et al. Methyl ethyl ketone peroxide as an initiator in the polymerization of vinyl monomers , 1957 .
[92] C. Eckart. The Penetration of a Potential Barrier by Electrons , 1930 .
[93] Tanja Junkers,et al. Pulsed Laser Polymerization – Size Exclusion Chromatography Investigations into Backbiting in Ethylhexyl Acrylate Polymerization , 2022, Polymer Chemistry.
[94] Dagmar R. D’hooge,et al. Impact of side reactions on molar mass distribution, unsaturation level and branching density in solution free radical polymerization of n-butyl acrylate under well-defined lab-scale reactor conditions , 2021 .
[95] I. Lacík,et al. A comparison of the solution radical propagation kinetics of partially water-miscible non-functional acrylates to acrylic acid , 2020 .
[96] V. Mahadevan,et al. Rates of initiation and chain transfer constants in the polymerization of methyl acrylate , 1955 .