Modelling the pyrolysis of wet wood – I. Three-dimensional formulation and analysis

A three-dimensional mathematical model for the pyrolysis of wet wood is developed with detailed consideration of moisture evaporation, anisotropic and variable properties, and pressure driven internal convection of gases. Multiple competing reactions are formulated; a single first-order Arrhenius reaction is however applied herein. Transient pyrolysis of a beech wood cube with different initial moisture contents is investigated under various furnace temperatures. Influences of anisotropic properties due to the grain structure on heat and mass transfers are discussed. This model serves as a precursor for Part II: Simulation of piloted ignition of wood in a cone calorimeter of this two-part study.

[1]  C. Diblasi On The Influence Of Physical Processes On The Transient Pyrolysis Of Cellulosic Samples , 1994 .

[2]  D. H. Malan,et al.  The combustion of wood. Part I , 1946, Mathematical Proceedings of the Cambridge Philosophical Society.

[3]  A. F. Roberts A review of kinetics data for the pyrolysis of wood and related substances , 1970 .

[4]  Colomba Di Blasi,et al.  Modeling intra- and extra-particle processes of wood fast pyrolysis , 2002 .

[5]  C. Blasi,et al.  Oxidative degradation and ignition of loose-packed straw beds , 1999 .

[6]  C. Blasi,et al.  Kinetics of the isothermal degradation of wood in the temperature range 528–708 K , 2003 .

[7]  Bertil Fredlund,et al.  A model for heat and mass transfer in timber structures during fire: a theoretical, numerical and experimental study , 1988 .

[8]  Bertil Fredlund,et al.  Modelling of heat and mass transfer in wood structures during fire , 1993 .

[9]  E. Roy Tinney,et al.  The combustion of wooden dowels in heated air , 1965 .

[10]  Colomba Di Blasi,et al.  Modelling the fast pyrolysis of cellulosic particles in fluid-bed reactors , 2000 .

[11]  C. Blasi,et al.  Thermogravimetric Analysis and Devolatilization Kinetics of Wood , 2002 .

[12]  Hsiang-Cheng Kung,et al.  A mathematical model of wood pyrolysis , 1972 .

[13]  Hsiang-Cheng Kung,et al.  On the heat of reaction in wood pyrolysis , 1973 .

[14]  Colomba Di Blasi,et al.  Physico-chemical processes occurring inside a degrading two-dimensional anisotropic porous medium , 1998 .

[15]  A. Murty Kanury,et al.  Some Considerations Pertaining to the Problem of Wood-Burning , 1970 .

[16]  A. Broido,et al.  Char yield on pyrolysis of cellulose , 1975 .

[17]  Fred Shafizadeh,et al.  A kinetic model for pyrolysis of cellulose. , 1979 .

[18]  Edwin R. Galea,et al.  The numerical simulation of the noncharring pyrolysis process and fire development within a compartment , 1999 .

[19]  Colomba Di Blasi,et al.  Comparison of semi-global mechanisms for primary pyrolysis of lignocellulosic fuels , 1998 .

[20]  H. L. Stone ITERATIVE SOLUTION OF IMPLICIT APPROXIMATIONS OF MULTIDIMENSIONAL PARTIAL DIFFERENTIAL EQUATIONS , 1968 .

[21]  P. Gilot,et al.  A three-dimensional model for the determination of kinetic data from the pyrolysis of beech wood , 1993 .

[22]  A. Murty Kanury,et al.  Thermal decomposition kinetics of wood pyrolysis , 1972 .

[23]  Guan Heng Yeoh,et al.  THE INFLUENCE OF MOISTURE ON THE COMBUSTION OF WOOD , 2000 .

[24]  José L. Figueiredo,et al.  A model for pyrolysis of wet wood , 1989 .

[25]  C. Branca,et al.  Kinetics of primary product formation from wood pyrolysis , 2001 .

[26]  Colomba Di Blasi,et al.  Pyrolytic behavior and products of some wood varieties , 2001 .