BIOLOGICAL REMOVAL OF NOx FROM SIMULATED FLUE GAS IN AEROBIC BIOFILTER

A bench-scale biofiltration system was developed to evaluate the NOx removal efficiency under high oxygen concentration. The system had been running for 120 days and kept on a steady NOx removal rate above 80%. A stable NOx removal with an efficiency of more than 80% from the gas phase can be obtained by the bioreactor concept, when flue gas containing NO (400-600 ppmv) and a certain O2 concentration (0-20%). In the blank experiment, less than 35% NO was removed as oxygen increased. The tendency of the three curves about NO removal rate with various O2 concentrations was mainly similar but some differences in the highest and lowest removal rate happened in the definite O2 concentration range. Oxygen was shown to have a significant effect on NOx removal at the first two or three days when oxygen concentration increased sharply. The higher concentration NO influent gas contained, the longer time the microflora need to regain activities. Compared with humidifier, microbial regenerator which was incorporated in biofilter can improve aerobic denitrifying bacteria activity by applying alternating oxic–anoxic conditions in the presence of nitrate and nitrite. Oxidation-Reduction Potential (ORP) and Dissolved Oxygen (DO) were used to control the dose of carbon source.

[1]  Donald S. Mavinic,et al.  Controlling factors for simultaneous nitrification and denitrification in a two-stage intermittent aeration process treating domestic sewage , 1999 .

[2]  S. Chang,et al.  Removal of NO from flue gases by absorption to an iron(ii) thiochelate complex and subsequent reduction to ammonia , 1994, Nature.

[3]  M. Wood,et al.  Heterotrophic nitrification in an acid forest soil : isolation and characterisation of a nitrifying bacterium , 2001 .

[4]  M. Fuerhacker,et al.  Relationship between release of nitric oxide and CO2 and their dependence on oxidation reduction potential in wastewater treatment. , 2001, Chemosphere.

[5]  J. M. Morgan-Sagastume,et al.  Hydrogen sulfide removal by compost biofiltration: effect of mixing the filter media on operational factors. , 2006, Bioresource technology.

[6]  R. Moletta,et al.  Aerobic Denitrifiers Isolated from Diverse Natural and Managed Ecosystems , 2000, Microbial Ecology.

[7]  Wang Zhi-xuan Discussion on the environment protection and resources saving in power industry during the 11th Five-year Plan , 2006 .

[8]  Dominique Patureau,et al.  Combined nitrification and denitrification in a single aerated reactor using the aerobic denitrifier Commonas sp. strain SGLY2 , 1997 .

[9]  J. Silverstein,et al.  Acetate Limitation and Nitrite Accumulation during Denitrification , 1999 .

[10]  Etienne Paul,et al.  Process state evaluation of alternating oxic-anoxic activated sludge using ORP, pH and DO , 1998 .

[11]  S. Revah,et al.  Biofiltration of volatile ethanol using sugar cane bagasse inoculated with Candida utilis. , 2002, Journal of hazardous materials.

[12]  S. Gupta,et al.  Biological oxidation of high strength nitrogenous wastewater , 1996 .

[13]  Auria,et al.  Microbiological and kinetic aspects of a biofilter for the removal of toluene from waste gases , 1999, Biotechnology and bioengineering.

[14]  W. A. Smith,et al.  Oxygen effects on thermophilic microbial populations in biofilters treating nitric oxide containing off-gas streams , 2001 .