1,4‐Bis(trimethylsilyl)buta‐1,3‐diyne

1,4-Bis(trimethylsilyl)buta-1,3-diyne solvent: petroleum ether (bp 30–40°C, 3 × 150 mL) product: bis(trimethylsilyl)butadiyne (BTMSBD) Keywords: oxidation,  CC; copper(I) chloride, tetramethylethylenediamine complex; acetylenic compounds, potential explosives; stirrers, vibromixer; vibromixer

[1]  E. Stracker,et al.  Novel syntheses of 1-(trialkylsilyl)-1,3-diynes and 1,4-bis-silyl-1,3-butadiynes from (Z)-1-methoxy-1-buten-3-yne , 1990 .

[2]  S. Rajagopalan,et al.  (Z)-1-Methoxybut-1-en-3-yne. A versatile synthon for 1,4-bis(trimethylsilyl)-1,3-butadiyne as well as for nucleophilic aldehyde and butadiyne equivalents , 1985 .

[3]  A. Holmes,et al.  Total synthesis of (±)-trans-maneonene-B , 1984 .

[4]  D. Liotta,et al.  A simple, efficient synthesis of 3-substituted furans , 1983 .

[5]  A. Holmes,et al.  Total synthesis of cis-maneonenes-a and -b , 1983 .

[6]  A. Holmes,et al.  Acylation reactions of silylated butadiynes: synthesis of some naturally occuring diacetylenic ketones , 1982 .

[7]  L. Birkofer,et al.  Silyl‐Derivate von Pyridazin , 1981 .

[8]  A. Holmes,et al.  Synthesis of 4-alkyl-1-trimethylsilylbuta-1,3-diynes , 1980 .

[9]  L. Birkofer,et al.  Silyl‐Derivate von Pyrazol, Isoxazol und 1,2,3‐Triazol , 1979 .

[10]  D. Walton,et al.  Selective desilylation of bis(trimethylsilyl)acetylenes , 1980 .

[11]  K. Praefcke,et al.  Organische Tellurverbindungen, IV: Eine verbesserte Synthese von Tellurophen , 1978 .

[12]  P. Jacobs,et al.  A semi‐micro synthesis of selenophene , 1977 .

[13]  A. Holmes,et al.  Model studies in the histrionicotoxin series: a highly stereoselective synthesis of terminal enyne units. , 1976 .

[14]  D. Walton,et al.  Friedel-crafts reactions of bis(trimethylsilyl)polyynes with acyl chlorides; a useful route to terminal-alkynyl ketones , 1972 .

[15]  H. Gilman,et al.  Hexakis(trimethylsilyl)-2-butyne by trimethylsilylation of hexachloro-1,3-butadiene , 1968 .

[16]  A. S. Hay Oxidative Coupling of Acetylenes. II1 , 1962 .

[17]  E. Jones,et al.  9. Researches on acetylenic compounds. Part XXVIII. A new route to diacetylene and its symmetrical derivatives , 1951 .