Methyl 3-(3-benzoylthioureido)propanoate

In the title compound, C12H14N2O3S, the propyl acetate group and the benzoyl group adopt a cis–trans conformation, respectively, with respect to the thiono S atom across the C—N bonds. The phenyl ring is twisted relative to the the thiourea mean plane, forming a dihedral angle of 24.16 (9)°. An intramolecular N—H⋯O hydrogen bond occurs. The crystal packing is stabilized by intermolecular N—H⋯O and C—H⋯O hydrogen bonds, forming a chain along the a axis.

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