In-liquid plasma: a novel tool in the fabrication of nanomaterials and in the treatment of wastewaters

Attempts to generate plasma in liquids have been successful and various devices have been proposed. Many reports have described the optimal conditions needed to generate plasma, and mechanisms have been inferred, together with the composition of the plasma. Elucidation of a stable method (and mechanism) to generate plasma in liquids has led to various active investigations into applications of this new energy source. This review article describes the generator and the generation mechanism of in-liquid plasma, and pays attention to the evolving technology. The characteristics of submerged plasma are summarized and examples of nanomaterials syntheses and wastewater treatment are given, both of which have attracted significant attention. Extreme reaction fields can be produced conveniently using electrical power even without the use of chemical substances and high-temperature high-pressure vessels. Chemical reactions can be carried out and environmental remediation processes achieved with high efficiency and operability with the use of in-liquid plasma. Suggestions for introducing in-liquid plasma to chemical processes are discussed.

[1]  J. Fukushima,et al.  Microwave Chemical and Materials Processing: A Tutorial , 2018 .

[2]  Erdal Yiğit,et al.  Introduction to Plasma , 2018 .

[3]  N. Saito,et al.  Facile preparation of defective black TiO2 through the solution plasma process: Effect of parametric changes for plasma discharge on its structural and optical properties , 2017 .

[4]  V. Colombo,et al.  Ultra-small CuO nanoparticles with tailored energy-band diagram synthesized by a hybrid plasma-liquid process , 2017 .

[5]  M. Aliofkhazraei,et al.  Synthesis mechanisms, optical and structural properties of η-Al2O3 based nanoparticles prepared by DC arc discharge in environmentally friendly liquids , 2017 .

[6]  R. López-Callejas,et al.  Growth of Ag particles from Ag-zeolite by pulsed discharges in water and their antibacterial activity , 2017 .

[7]  M. Cha,et al.  Synthesis of Carbon–Metal Multi-Strand Nanocomposites by Discharges in Heptane Between Two Metallic Electrodes , 2017, Plasma Chemistry and Plasma Processing.

[8]  D. Go,et al.  Perspectives on Plasmas in Contact with Liquids for Chemical Processing and Materials Synthesis , 2017, Topics in Catalysis.

[9]  Xiulan Hu,et al.  Plasma-induced synthesis of Pt nanoparticles supported on TiO2 nanotubes for enhanced methanol electro-oxidation , 2017 .

[10]  S. K. Gupta Contact Glow Discharge Electrolysis: A Novel Tool for Manifold Applications , 2017 .

[11]  Susanta K. Sen Gupta Contact Glow Discharge Electrolysis: A Novel Tool for Manifold Applications , 2017, Plasma Chemistry and Plasma Processing.

[12]  Hai Liu,et al.  Plasma electrochemical synthesis of cuprous oxide nanoparticles and their visible-light photocatalytic effect , 2016 .

[13]  N. Saito,et al.  Fastest Formation Routes of Nanocarbons in Solution Plasma Processes , 2016, Scientific Reports.

[14]  R. Rujiravanit,et al.  Fabrication of bacterial cellulose-ZnO composite via solution plasma process for antibacterial applications. , 2016, Carbohydrate polymers.

[15]  N. Saito,et al.  Electrocatalytic oxygen reduction on nitrogen-doped carbon nanoparticles derived from cyano-aromatic molecules via a solution plasma approach , 2016 .

[16]  Y. Choa,et al.  Plasma-assisted electrolytic synthesis of In(OH)3 nanocubes for thermal transformation into In2O3 nanocubes with a controllable Sn content , 2016 .

[17]  Sang‐Chul Jung,et al.  Facile synthesis of bimetallic Ni-Cu nanoparticles using liquid phase plasma method , 2016, Korean Journal of Chemical Engineering.

[18]  S. Nomura,et al.  Decomposition of methane hydrate for hydrogen production using microwave and radio frequency in-liquid plasma methods , 2015 .

[19]  S. Yatsu,et al.  Synthesis of stainless steel nanoballs via submerged glow-discharge plasma and its photocatalytic performance in methylene blue decomposition , 2015 .

[20]  T. Akiyama,et al.  Generation of solution plasma over a large electrode surface area , 2015 .

[21]  G. Saito,et al.  Solution plasma synthesis of Si nanoparticles , 2015, Nanotechnology.

[22]  Jue Zhang,et al.  Microplasma-Assisted Synthesis of Colloidal Gold Nanoparticles and Their Use in the Detection of Cardiac Troponin I (cTn-I) , 2015 .

[23]  Qiang Chen,et al.  A review of plasma–liquid interactions for nanomaterial synthesis , 2014, 1404.2515.

[24]  P. Pohl,et al.  Direct elemental analysis of honeys by atmospheric pressure glow discharge generated in contact with a flowing liquid cathode , 2015 .

[25]  T. Akiyama,et al.  Nanomaterial synthesis using plasma generation in liquid , 2015 .

[26]  N. Abdullah,et al.  Microwave-assisted synthesis of porous ZnO/SnS 2 heterojunction and its enhanced photoactivity for water purification , 2015 .

[27]  P. Gibbon,et al.  Introduction to Plasma Physics , 2017, 2007.04783.

[28]  C. Du,et al.  Cu2O nanoparticles synthesis by microplasma , 2014, Scientific Reports.

[29]  N. Matsuda,et al.  Synthesis of multiwall carbon nanotube-supported platinum catalysts by solution plasma processing for oxygen reduction in polymer electrolyte fuel cells , 2014 .

[30]  S. Katsuki,et al.  5. Use of Plasma in Liquid for Fishing Industry( Plasma Applications for Agriculture) , 2014 .

[31]  Tomoko Yoshida,et al.  In situ ultraviolet–visible absorbance measurement during and after solution plasma sputtering for preparation of colloidal gold nanoparticles , 2014 .

[32]  T. Akiyama,et al.  Excitation temperature of a solution plasma during nanoparticle synthesis , 2014 .

[33]  N. Saito,et al.  Synthesis of mono-dispersed nanofluids using solution plasma. , 2014, Journal of applied physics.

[34]  T. Akiyama,et al.  Optimization of electrolyte concentration and voltage for effective formation of Sn/SnO2 nanoparticles by electrolysis in liquid , 2014 .

[35]  Takashi Nakamura,et al.  Growth of carbon dendrites on cathode above liquid ethanol using surface plasma , 2014 .

[36]  T. Akiyama,et al.  Synthesis of nonstoichiometric titanium oxide nanoparticles using discharge in HCl solution , 2014 .

[37]  S. Uchida,et al.  Synthesis of metal nanoparticles by dual plasma electrolysis using atmospheric dc glow discharge in contact with liquid , 2014 .

[38]  T. Akiyama,et al.  Solution plasma synthesis of bimetallic nanoparticles , 2014, Nanotechnology.

[39]  Y. Mok,et al.  Synthesis of RuO2 nanomaterials under dielectric barrier discharge plasma at atmospheric pressure – Influence of substrates on the morphology and application , 2014 .

[40]  T. Akiyama,et al.  Surfactant-assisted synthesis of Sn nanoparticles via solution plasma technique , 2014 .

[41]  Hidenori Akiyama,et al.  A Method of Cyanobacteria Treatment Using Underwater Pulsed Streamer-Like Discharge , 2014, IEEE Transactions on Plasma Science.

[42]  Yi Lu,et al.  Microplasma-chemical synthesis and tunable real-time plasmonic responses of alloyed Au(x)Ag(1-x) nanoparticles. , 2014, Chemical communications.

[43]  T. Akiyama,et al.  High-speed camera observation of solution plasma during nanoparticles formation , 2014 .

[44]  T. Akiyama,et al.  Solution plasma synthesis of ZnO flowers and their photoluminescence properties , 2014 .

[45]  Yongfeng Li,et al.  Plasma synthesis of carbon nanotube-gold nanohybrids: efficient catalysts for green oxidation of silanes in water , 2014 .

[46]  N. Saito,et al.  A novel one-step synthesis of gold nanoparticles in an alginate gel matrix by solution plasma sputtering , 2014 .

[47]  S. Nomura,et al.  Synthesis of tungsten oxide, silver, and gold nanoparticles by radio frequency plasma in water , 2013 .

[48]  H. Ming,et al.  Liquid-phase plasma synthesis of silicon quantum dots embedded in carbon matrix for lithium battery anodes , 2013 .

[49]  S. Nomura,et al.  Electrical breakdown of microwave plasma in water , 2013 .

[50]  Guang-Zhou Qu,et al.  Simultaneous removal of cadmium ions and phenol from water solution by pulsed corona discharge plasma combined with activated carbon , 2013 .

[51]  P. Pohl,et al.  Comparison of the performance of direct current atmospheric pressure glow microdischarges operated between a small sized flowing liquid cathode and miniature argon or helium flow microjets , 2013 .

[52]  M. Tokushige,et al.  Formation of metallic Si and SiC nanoparticles from SiO2 particles by plasma-induced cathodic discharge electrolysis in chloride melt , 2013 .

[53]  Yongfeng Li,et al.  Plasma synthesis of Pd nanoparticles decorated-carbon nanotubes and its application in Suzuki reaction , 2013 .

[54]  O. Takai,et al.  One-step synthesis of gold bimetallic nanoparticles with various metal-compositions , 2013 .

[55]  Enric Bertran,et al.  In Situ Polymerization of Aqueous Solutions of NIPAAm Initiated by Atmospheric Plasma Treatment , 2013 .

[56]  S. Yatsu,et al.  Fabrication of Nanoparticles by Electric Discharge Plasma in Liquid , 2013 .

[57]  S. Nomura,et al.  Synthesis of tungsten trioxide nanoparticles by microwave plasma in liquid and analysis of physical properties , 2013 .

[58]  L. Němcová,et al.  Synthesis of surfactant-free electrostatically stabilized gold nanoparticles by plasma-induced liquid chemistry , 2013, Nanotechnology.

[59]  E. Gaigneaux,et al.  Plasma-Assisted Synthesis of TiO2 Nanorods by Gliding Arc Discharge Processing at Atmospheric Pressure for Photocatalytic Applications , 2013, Plasma Chemistry and Plasma Processing.

[60]  S. H. Park,et al.  Preparation of nonaggregated silver nanoparticles by the liquid phase plasma reduction method , 2013 .

[61]  Nick Serpone,et al.  Microwaves in nanoparticle synthesis : fundamentals and applications , 2013 .

[62]  R. Wüthrich,et al.  Synthesis of Ni and Pt nanomaterials by cathodic contact glow discharge electrolysis in acidic and alkaline media , 2013 .

[63]  Ruma,et al.  Effects of pulse frequency of input power on the physical and chemical properties of pulsed streamer discharge plasmas in water , 2013 .

[64]  M. Umeno,et al.  Formation of graphene nano-particle by means of pulsed discharge to ethanol , 2013 .

[65]  K. Ostrikov,et al.  Plasmonic Ag nanoparticles via environment-benign atmospheric microplasma electrochemistry , 2013, Nanotechnology.

[66]  O. Takai,et al.  Facile fabrication of PtAu alloy clusters using solution plasma sputtering and their electrocatalytic activity , 2013 .

[67]  O. Takai,et al.  Synthesis of gold nanoparticles by solution plasma sputtering in various solvents , 2013 .

[68]  A. Addou,et al.  DBDplate-TiO2 treatment of Yellow Tartrazine azo dye solution in falling film , 2013 .

[69]  S. Ogawa,et al.  Adsorption Reaction of L-Cysteine on Au Nanoparticle Prepared by Solution Plasma , 2013 .

[70]  N. Saito,et al.  Discharge time dependence of a solution plasma process for colloidal copper nanoparticle synthesis and particle characteristics , 2013, Nanotechnology.

[71]  S. Nomura,et al.  A practical electrode for microwave plasma processes , 2013 .

[72]  Wahyudiono,et al.  Decomposition of methyl orange using pulsed discharge plasma at atmospheric pressure: Effect of different electrodes , 2013 .

[73]  O. Takai,et al.  Simple Synthesis of Platinum Nanoparticles by Plasma Sputtering in Water , 2013 .

[74]  P. Pohl,et al.  Effect of the addition of non-ionic surfactants on the emission characteristic of direct current atmospheric pressure glow discharge generated in contact with a flowing liquid cathode , 2012 .

[75]  Davide Mariotti,et al.  Plasma–Liquid Interactions at Atmospheric Pressure for Nanomaterials Synthesis and Surface Engineering , 2012 .

[76]  P. Pohl,et al.  Development of direct-current, atmospheric-pressure, glow discharges generated in contact with flowing electrolyte solutions for elemental analysis by optical emission spectrometry , 2012 .

[77]  S. Nomura,et al.  Hydrogen production by radio frequency plasma stimulation in methane hydrate at atmospheric pressure , 2012 .

[78]  S. Takashima,et al.  Preparation of Aqueous Dispersion of Titanium Dioxide Nanoparticles using Plasma on Liquid Surface , 2012 .

[79]  O. Takai,et al.  Synthesis and characteristics of Ag/Pt bimetallic nanocomposites by arc-discharge solution plasma processing , 2012, Nanotechnology.

[80]  Y. Xing,et al.  Titanium oxide nanospheres: preparation, characterization, and wide‐spectral absorption , 2012 .

[81]  C. Subrahmanyam,et al.  Green Approach for Wastewater Treatment—Degradation and Mineralization of Aqueous Organic Pollutants by Discharge Plasma , 2012 .

[82]  Sang-Yul Lee,et al.  Rapid synthesis of Ag nanoparticles-embedded mesoporous silica via solution plasma and its catalysis for 4-nitrophenol reduction , 2012 .

[83]  T. Akiyama,et al.  Surface morphology of a glow discharge electrode in a solution , 2012 .

[84]  P. Pohl,et al.  An analytical performance of atmospheric pressure glow discharge generated in contact with flowing small size liquid cathode , 2012 .

[85]  Yongbing Xie,et al.  Morphologic evolution of Au nanocrystals grown in ionic liquid by plasma reduction. , 2012, Journal of colloid and interface science.

[86]  Giuseppe Faraci,et al.  Effect of the liquid environment on the formation of carbon nanotubes and graphene layers by arcing processes , 2012 .

[87]  T. Akiyama,et al.  Ripple formation on a nickel electrode during a glow discharge in a solution , 2012 .

[88]  T. Akiyama,et al.  Influence of Solution Temperature and Surfactants on Morphologies of Tin Oxide Produced Using a Solution Plasma Technique , 2012 .

[89]  Masaru Hori,et al.  Ultrahigh-Speed Synthesis of Nanographene Using Alcohol In-Liquid Plasma , 2012 .

[90]  W. Chu,et al.  Honeycomb-like Co–B amorphous alloy catalysts assembled by a solution plasma process show enhanced catalytic hydrolysis activity for hydrogen generation , 2012 .

[91]  S. Nomura,et al.  Improvement in preventing metal contamination from an electrode used for generating microwave plasma in liquid , 2012 .

[92]  Rikizo Hatakeyama,et al.  Rapid synthesis of water-soluble gold nanoparticles with control of size and assembly using gas–liquid interfacial discharge plasma , 2012 .

[93]  O. Takai,et al.  Rapid Synthesis and Structural Characterization of Well-Defined Gold Clusters by Solution Plasma Sputtering , 2012 .

[94]  T. Kareem,et al.  Glow discharge plasma electrolysis for nanoparticles synthesis , 2012, Ionics.

[95]  S. Nomura,et al.  Continuous synthesis of magnesium-hydroxide, zinc-oxide, and silver nanoparticles by microwave plasma in water , 2011 .

[96]  Susumu Sato,et al.  Synthesis of nanoparticles of silver and platinum by microwave-induced plasma in liquid , 2011 .

[97]  O. Takai,et al.  Microstructural characterization of gold nanoparticles synthesized by solution plasma processing , 2011, Nanotechnology.

[98]  T. Akiyama,et al.  Synthesis of ZnO nanoflowers by solution plasma , 2011 .

[99]  Qiang Chen,et al.  Characterization of pulse-driven gas-liquid interfacial discharge plasmas and application to synthesis of gold nanoparticle-DNA encapsulated carbon nanotubes , 2011 .

[100]  Susumu Sato,et al.  A novel liquid plasma AOP device integrating microwaves and ultrasounds and its evaluation in defluorinating perfluorooctanoic acid in aqueous media. , 2011, Ultrasonics sonochemistry.

[101]  M. Kostić,et al.  Decolorization of reactive textile dyes using water falling film dielectric barrier discharge. , 2011, Journal of hazardous materials.

[102]  T. Akiyama,et al.  Nickel Nanoparticles Formation from Solution Plasma Using Edge-Shielded Electrode , 2011 .

[103]  S. Nomura,et al.  A consideration of ternary C–H–O diagram for diamond deposition using microwave in-liquid and gas phase plasma , 2011 .

[104]  F. Endres,et al.  Plasma electrochemistry in ionic liquids: an alternative route to generate nanoparticles. , 2011, Physical chemistry chemical physics : PCCP.

[105]  T. Akiyama,et al.  Synthesis of copper/copper oxide nanoparticles by solution plasma , 2011 .

[106]  H. Sakai,et al.  Microwave discharge electrodeless lamps (MDELs). VI. Performance evaluation of a novel microwave discharge granulated electrodeless lamp (MDGEL)—Photoassisted defluorination of perfluoroalkoxy acids in aqueous media , 2011 .

[107]  Sang-Yul Lee,et al.  Effects of the gap distance on the characteristics of gold nanoparticles in nanofluids synthesized using solution plasma processing , 2011 .

[108]  M. Brown,et al.  Plasma Physics: An Introduction to Laboratory, Space, and Fusion Plasmas , 2011 .

[109]  S. Nomura,et al.  Influence of conductivity on the generation of a radio frequency plasma surrounded by bubbles in water , 2011 .

[110]  William G. Graham,et al.  Vapour layer formation by electrical discharges through electrically conducting liquids—modelling and experiment , 2011 .

[111]  R. Hatakeyama,et al.  Structural and reactive kinetics in gas–liquid interfacial plasmas , 2011 .

[112]  S. Nomura,et al.  Characteristics of in-liquid plasma in water under higher pressure than atmospheric pressure , 2011 .

[113]  William G. Graham,et al.  Plasma production in electrically conducting liquids , 2011 .

[114]  N. Takeuchi,et al.  Experimental and theoretical study of acetic-acid decomposition by a pulsed dielectric-barrier plasma in a gas–liquid two-phase flow , 2011 .

[115]  S. Nomura,et al.  Internal conditions of a bubble containing radio-frequency plasma in water , 2011 .

[116]  S. Nomura,et al.  Plasma Decomposition of Clathrate Hydrates by 2.45 GHz Microwave Irradiation at Atmospheric Pressure , 2011 .

[117]  O. Takai,et al.  Ag nanoparticle incorporation in mesoporous silica synthesized by solution plasma and their catalysis for oleic acid hydrogenation , 2011 .

[118]  M. Tokushige,et al.  Formation of Co–Pt Intermetallic Compound Nanoparticles by Plasma-Induced Cathodic Discharge Electrolysis in a Chloride Melt , 2011 .

[119]  S. Nomura,et al.  Synthesis of zinc and zinc oxide nanoparticles from zinc electrode using plasma in liquid , 2011 .

[120]  Zhehao Wei,et al.  Synthesis of monodisperse gold nanoparticles in ionic liquid by applying room temperature plasma , 2011 .

[121]  J. Janek,et al.  Plasma Electrochemistry in 1‐Butyl‐3‐methylimidazolium dicyanamide: Copper Nanoparticles from CuCl and CuCl2 , 2011 .

[122]  H. Hongo,et al.  Formation of Sm-Co Intermetallic Compound Nanoparticles Based on Plasma-Induced Cathodic Discharge Electrolysis in Chloride Melt , 2011 .

[123]  Y. Fukunaka,et al.  Formation of FePt intermetallic compound nanoparticles by plasma-induced cathodic discharge electrolysis , 2010 .

[124]  A. Ashkarran A novel method for synthesis of colloidal silver nanoparticles by arc discharge in liquid , 2010 .

[125]  Michio Kondo,et al.  Microplasma-induced surface engineering of silicon nanocrystals in colloidal dispersion , 2010 .

[126]  M. Tokushige,et al.  Formation of Fine Ni Nanoparticle by Plasma-Induced Cathodic Discharge Electrolysis Using Rotating Disk Anode , 2010 .

[127]  T. Akiyama,et al.  Size-controlled Ni nanoparticles formation by solution glow discharge , 2010 .

[128]  S. Nomura,et al.  Growth of bubbles containing plasma in water by high-frequency irradiation , 2010 .

[129]  M. Tokushige,et al.  Plasma-induced cathodic discharge electrolysis to form various metal/alloy nanoparticles , 2010 .

[130]  S. Saviz,et al.  On the Formation of TiO2 Nanoparticles Via Submerged Arc Discharge Technique: Synthesis, Characterization and Photocatalytic Properties , 2010 .

[131]  Susumu Sato,et al.  Preparation of Zinc Oxide Nanoparticles by Using Microwave-induced Plasma in Liquid , 2010 .

[132]  R. M. Sankaran,et al.  Microplasma-assisted growth of colloidal Ag nanoparticles for point-of-use surface-enhanced Raman scattering applications , 2010 .

[133]  R. M. Sankaran,et al.  Continuous-flow, atmospheric-pressure microplasmas: a versatile source for metal nanoparticle synthesis in the gas or liquid phase , 2010 .

[134]  U. Panne,et al.  Radiative models of laser-induced plasma and pump-probe diagnostics relevant to laser-induced breakdown spectroscopy , 2010 .

[135]  P. Bruggeman,et al.  Optical emission spectroscopy as a diagnostic for plasmas in liquids: opportunities and pitfalls , 2010 .

[136]  S. Nomura,et al.  Optimization and analysis of shape of coaxial electrode for microwave plasma in water , 2010 .

[137]  S. Nomura,et al.  Degradation of methylene blue by radio frequency plasmas in water under ultraviolet irradiation. , 2010, Journal of hazardous materials.

[138]  J. Janek,et al.  Plasma electrochemistry in ionic liquids: deposition of copper nanoparticles. , 2010, Physical chemistry chemical physics : PCCP.

[139]  T. Kaneko,et al.  Synthesis of monodispersed nanoparticles functionalized carbon nanotubes in plasma-ionic liquid interfacial fields. , 2010, Chemical communications.

[140]  I. Alexandrou,et al.  γ-Al2O3 nanoparticle production by arc-discharge in water: in situ discharge characterization and nanoparticle investigation , 2009 .

[141]  N. Lu,et al.  Simulataneous pentachlorophenol decomposition and granular activated carbon regeneration assisted by dielectric barrier discharge plasma. , 2009, Journal of hazardous materials.

[142]  S. Nomura,et al.  Temperature distributions of radio-frequency plasma in water by spectroscopic analysis , 2009 .

[143]  O. Takai,et al.  Synthesis process of gold nanoparticles in solution plasma , 2009 .

[144]  Lei Wang Aqueous organic dye discoloration induced by contact glow discharge electrolysis. , 2009, Journal of hazardous materials.

[145]  B. Locke,et al.  Effects of Electrode Protrusion Length, Pre‐Existing Bubbles, Solution Conductivity and Temperature, on Liquid Phase Pulsed Electrical Discharge , 2009 .

[146]  T. Kaneko,et al.  Novel Gas-Liquid Interfacial Plasmas for Synthesis of Metal Nanoparticles , 2009 .

[147]  Jiangang Han,et al.  Analysis of TiO2 photocatalysis in a pulsed discharge system for phenol degradation , 2009 .

[148]  Chang‐jun Liu Size-Controlled Synthesis of Colloidal Gold Nanoparticles at Room Temperature Under the Influence of Glow Discharge , 2009, Nanoscale research letters.

[149]  A. I. Zad,et al.  STABILITY, SIZE AND OPTICAL PROPERTIES OF COLLOIDAL SILVER NANOPARTICLES PREPARED BY ELECTRICAL ARC DISCHARGE IN WATER , 2009 .

[150]  M. Tsuji,et al.  Laser-induced silver nanocrystal formation in polyvinylpyrrolidone solutions , 2009 .

[151]  M. Tokushige,et al.  Synthesis of Magnetic Nanoparticles (Fe and FePt) by Plasma-Induced Cathodic Discharge Electrolysis , 2009, IEEE Transactions on Plasma Science.

[152]  M. Belhadj,et al.  Enhancement of the bleaching and degradation of textile wastewaters by Gliding arc discharge plasma in the presence of TiO2 catalyst. , 2009, Journal of hazardous materials.

[153]  T. Kaneko,et al.  Static gas-liquid interfacial direct current discharge plasmas using ionic liquid cathode , 2009 .

[154]  S. Mahdavi,et al.  Rapid and efficient synthesis of colloidal gold nanoparticles by arc discharge method , 2009 .

[155]  Yunfei Liu,et al.  Controllable morphology evolution of electrodeposited ZnO nano/micro-scale structures in aqueous solution , 2009 .

[156]  Manuel Á. González,et al.  Characterization of a direct dc-excited discharge in water by optical emission spectroscopy , 2009 .

[157]  K. Tseng,et al.  Identification and quantification of ionic silver from colloidal silver prepared by electric spark discharge system and its antimicrobial potency study , 2009 .

[158]  S. Nomura,et al.  Spectroscopic measurements of high frequency plasma in supercritical carbon dioxide , 2009 .

[159]  N. Shirai,et al.  Atmospheric DC Glow Microplasmas Using Miniature Gas Flow and Electrolyte Cathode , 2009 .

[160]  M. Tokushige,et al.  Synthesis of Ni nanoparticles by plasma-induced cathodic discharge electrolysis , 2009 .

[161]  T. Kaneko,et al.  Efficient Synthesis of Gold Nanoparticles Using Ion Irradiation in Gas–Liquid Interfacial Plasmas , 2009 .

[162]  Guoliang Zhang,et al.  Size control of carbon black-supported platinum nanoparticles via novel plasma reduction , 2009 .

[163]  Xingwang Zhang,et al.  Degradation characteristics of toxic contaminant with modified activated carbons in aqueous pulsed discharge plasma process , 2009 .

[164]  J. Bell,et al.  Plasma Electrolytic Deposition of Titanium Dioxide Nanorods and Nano-particles , 2008 .

[165]  Sang-Yul Lee,et al.  Effects of PVP and KCl concentrations on the synthesis of gold nanoparticles using a solution plasma processing , 2008 .

[166]  S. Nomura,et al.  Submerged synthesis of diamond in liquid alcohol plasma , 2008 .

[167]  R. M. Sankaran,et al.  Plasma-liquid electrochemistry: Rapid synthesis of colloidal metal nanoparticles by microplasma reduction of aqueous cations , 2008 .

[168]  正明 細見,et al.  メカノケミカル法によるペルフルオロオクタンスルホン酸(PFOS)およびペルフルオロオクタン酸(PFOA)の分解 , 2008 .

[169]  Yujing Wang,et al.  Synthesis and characterization of superabsorbent composite by using glow discharge electrolysis plasma , 2008 .

[170]  O. Takai,et al.  Size-regulated gold nanoparticles fabricated by a discharge in reverse micelle solutions , 2008 .

[171]  J. Vierendeels,et al.  Plasma characteristics and electrical breakdown between metal and water electrodes , 2008 .

[172]  Seungho Cho,et al.  Morphology-Controlled Growth of ZnO Nanostructures Using Microwave Irradiation: from Basic to Complex Structures , 2008 .

[173]  W. Cai,et al.  Enhanced degradation of aqueous methyl orange by contact glow discharge electrolysis using Fe2+ as catalyst , 2008 .

[174]  S. Nomura,et al.  Degradation of Methylene Blue by RF Plasma in Water , 2008 .

[175]  O. Takai,et al.  Exotic shapes of gold nanoparticles synthesized using plasma in aqueous solution , 2008 .

[176]  V. Burakov,et al.  Synthesis of nanoparticles using a pulsed electrical discharge in a liquid , 2008 .

[177]  Ravindra P. Joshi,et al.  Electrical breakdown of water in microgaps , 2008 .

[178]  Qiang Chen,et al.  Microplasma discharge in ethanol solution: Characterization and its application to the synthesis of carbon microstructures , 2008 .

[179]  Yongbing Xie,et al.  Stability of Ionic Liquids under the Influence of Glow Discharge Plasmas , 2008 .

[180]  S. Nomura,et al.  Discharge Characteristics of Microwave and High-Frequency In-Liquid Plasma in Water , 2008 .

[181]  H. Bleuler,et al.  Fabrication of metallic nanoparticles by electrochemical discharges , 2008 .

[182]  Ming-hua Zhou,et al.  Effect of various gases and chemical catalysts on phenol degradation pathways by pulsed electrical discharges. , 2008, Journal of hazardous materials.

[183]  X. Jiang,et al.  Plasma-induced Degradation of Chlorobenzene in Aqueous Solution , 2008 .

[184]  A. Addou,et al.  TiO2-assisted degradation of a perfluorinated surfactant in aqueous solutions treated by gliding arc discharge. , 2008, Chemosphere.

[185]  O. Takai Solution plasma processing (SPP) , 2008 .

[186]  Xiaoyan He,et al.  Decoloration of alizarin red S in aqueous solution by glow discharge electrolysis , 2008 .

[187]  Honggang Chen,et al.  Effect of granular activated carbon on degradation of methyl orange when applied in combination with high-voltage pulse discharge. , 2007, Journal of colloid and interface science.

[188]  C. Cho,et al.  Effects of the medium on synthesis of nanopowders by wire explosion process , 2007 .

[189]  Masanori Sato,et al.  Multibubble plasma production and solvent decomposition in water by slot-excited microwave discharge , 2007 .

[190]  S. Nomura,et al.  Observation of Microwave In-Liquid Plasma using High-Speed Camera , 2007 .

[191]  K. Furuya,et al.  Protective agent-free preparation of gold nanoplates and nanorods in aqueous HAuCl4 solutions using gas - Liquid interface discharge , 2007 .

[192]  J. Bell,et al.  Development of a Novel Cathodic Plasma/Electrolytic Deposition Technique Part 2: Physico-chemical Analysis of the Plasma Discharge , 2007 .

[193]  C. Du,et al.  Degradation of 4-Chlorophenol using a Gas–Liquid Gliding Arc Discharge Plasma Reactor , 2007 .

[194]  S. Yatsu,et al.  Controlled formation of metallic nanoballs during plasma electrolysis , 2007 .

[195]  Hong‐Ming Lin Preparation of Gold Nanoparticles by Arc Discharge in Water. , 2007 .

[196]  T. Sakugawa,et al.  Electron Temperature and Electron Density of Underwater Pulsed Discharge Plasma Produced by Solid-State Pulsed-Power Generator , 2007, IEEE Transactions on Plasma Science.

[197]  Hong-Ming Lin,et al.  Preparation of gold nanoparticles by arc discharge in water , 2007 .

[198]  Hong-Ming Lin,et al.  Preparation of silver nanofluid by the submerged arc nanoparticle synthesis system (SANSS) , 2007 .

[199]  S. Nomura,et al.  27.12 MHz plasma generation in supercritical carbon dioxide , 2007 .

[200]  Ming-hua Zhou,et al.  Non-thermal plasma-induced photocatalytic degradation of 4-chlorophenol in water. , 2007, Journal of hazardous materials.

[201]  Ho-Suk Choi,et al.  Comparative Actions of NiO and TiO2 Catalysts on the Destruction of Phenol and its Derivatives in a Dielectric Barrier Discharge , 2007 .

[202]  J. Janek,et al.  Employing plasmas as gaseous electrodes at the free surface of ionic liquids: deposition of nanocrystalline silver particles. , 2007, Chemphyschem : a European journal of chemical physics and physical chemistry.

[203]  S. Uchida,et al.  Glow Discharge Formation over Water Surface at Saturated Water Vapor Pressure and Its Application to Wastewater Treatment , 2006 .

[204]  S. Nomura,et al.  Radio Frequency Plasma in Water , 2006 .

[205]  Satoshi Hamaguchi,et al.  Radio-Frequency-Driven Atmospheric-Pressure Plasmas in Contact with Liquid Water , 2006 .

[206]  B. Locke,et al.  Degradation of chemical warfare agent simulants using gas-liquid pulsed streamer discharges. , 2006, Journal of hazardous materials.

[207]  X. Jiang,et al.  Phenol degradation by a nonpulsed diaphragm glow discharge in an aqueous solution. , 2005, Environmental science & technology.

[208]  Myoungseok Lee,et al.  Platinum nanoparticles prepared by a plasma-chemical reduction method , 2005 .

[209]  H. Schröder,et al.  Stability of fluorinated surfactants in advanced oxidation processes--A follow up of degradation products using flow injection-mass spectrometry, liquid chromatography-mass spectrometry and liquid chromatography-multiple stage mass spectrometry. , 2005, Journal of chromatography. A.

[210]  Qing-Song Wu,et al.  Formation of uniform CuO nanorods by spontaneous aggregation: Selective synthesis of CuO, Cu2O, and Cu nanoparticles by a solid-liquid phase arc discharge process. , 2005, The journal of physical chemistry. B.

[211]  Y. Maeda,et al.  Sonochemical decomposition of perfluorooctane sulfonate and perfluorooctanoic acid. , 2005, Environmental science & technology.

[212]  R. Arakawa,et al.  Efficient decomposition of environmentally persistent perfluorocarboxylic acids by use of persulfate as a photochemical oxidant. , 2005, Environmental science & technology.

[213]  Y. Aoki,et al.  Hydrogen Evolution by Plasma Electrolysis in Aqueous Solution , 2005 .

[214]  M. Seo,et al.  Formation of Microparticles from Titanium and Silicon Electrodes Using High-Voltage Discharge in Electrolyte Solution , 2005 .

[215]  Takashi Ibusuki,et al.  Decomposition of environmentally persistent perfluorooctanoic acid in water by photochemical approaches. , 2004, Environmental science & technology.

[216]  Lan-sun Zheng,et al.  Preparation and self-assembly of copper nanoparticles via discharge of copper rod electrodes in a surfactant solution: a combination of physical and chemical processes , 2004 .

[217]  Jie Yu,et al.  Oxidative degradation of phenol in aqueous electrolyte induced by plasma from a direct glow discharge , 2003 .

[218]  G. Amaratunga,et al.  Pressure effects on nanotubes formation using the submerged arc in water method , 2003 .

[219]  I. Alexandrou,et al.  Fabrication of inorganic molybdenum disulfide fullerenes by arc in water , 2003 .

[220]  M. V. Antisari,et al.  Synthesis of multiwall carbon nanotubes by electric arc discharge in liquid environments , 2003 .

[221]  Xiaoquan Lu,et al.  Plasma degradation of dyes in water with contact glow discharge electrolysis. , 2003, Water research.

[222]  Hongwei Zhu,et al.  Formation of carbon nanotubes in water by the electric-arc technique , 2002 .

[223]  T. Ohshima,et al.  Effect of culture temperature on high-voltage pulse sterilization of Escherichia coli , 2002 .

[224]  Xiaoquan Lu,et al.  Oxidative degradation of acridine orange induced by plasma with contact glow discharge electrolysis , 2001 .

[225]  Fu-Rong Chen,et al.  Production and in‐situ Metal Filling of Carbon Nanotubes in Water , 2001 .

[226]  Abdul Ghaffar,et al.  Water purification by electrical discharges , 2001 .

[227]  A D Yoffe,et al.  Semiconductor quantum dots and related systems: Electronic, optical, luminescence and related properties of low dimensional systems , 2001 .

[228]  H. Akiyama Streamer discharges in liquids and their applications , 2000 .

[229]  Kenkichiro Kobayashi,et al.  Electrochemical Generation of Hot Plasma by Pulsed Discharge in an Electrolyte , 2000 .

[230]  K. Azumi,et al.  Light Emission from Pt during High‐Voltage Cathodic Polarization , 1999 .

[231]  W. C. Finney,et al.  Aqueous phase pulsed streamer corona reactor using suspended activated carbon particles for phenol oxidation : Model-data comparison , 1999 .

[232]  Shuhong Yu,et al.  Formation of silver nanowires by a novel solid-liquid phase arc discharge method , 1999 .

[233]  K. Moritani,et al.  Discharge electrolysis in molten chloride: formation of fine silver particles , 1998 .

[234]  S. Sengupta,et al.  A Study on the Origin of Nonfaradaic Behavior of Anodic Contact Glow Discharge Electrolysis The Relationship Between Power Dissipated in Glow Discharges and Nonfaradaic Yields , 1998 .

[235]  J. Heath,et al.  Nanocrystal superlattices. , 1998, Annual review of physical chemistry.

[236]  Bing Sun,et al.  Optical study of active species produced by a pulsed streamer corona discharge in water , 1997 .

[237]  Mounir Laroussi,et al.  Sterilization of contaminated matter with an atmospheric pressure plasma , 1996 .

[238]  J. Sid Clements,et al.  Formation of chemical species and their effects on microorganisms using a pulsed high voltage discharge in water , 1994, Proceedings of 1994 IEEE Industry Applications Society Annual Meeting.

[239]  M. Beck,et al.  Formation of C60 and polycyclic aromatic hydrocarbons upon electric discharges in liquid toluene , 1993 .

[240]  S. Campbell,et al.  Cathodic contact glow discharge electrolysis under reduced pressure , 1992 .

[241]  J. S. Clements,et al.  Preliminary Investigation of Prebreakdown Phenomena and Chemical Reactions Using a Pulsed High-Voltage Discharge in Water , 1987, IEEE Transactions on Industry Applications.

[242]  A. Ekimov,et al.  Quantum Size Effect in Three-Dimensional Microscopic Semiconductor Crystals , 1981, JETP Letters.

[243]  J. C. Devins,et al.  Breakdown and prebreakdown phenomena in liquids , 1981 .

[244]  E. Board,et al.  CATHODE RAYS , 1966 .

[245]  M. Ingram,et al.  Glow-discharge electrolysis , 1964 .

[246]  M. Ingram,et al.  Contact glow-discharge electrolysis , 1964 .

[247]  I Langmuir,et al.  Oscillations in Ionized Gases. , 1928, Proceedings of the National Academy of Sciences of the United States of America.

[248]  J. J. Thomson,et al.  XL. Cathode Rays , 1897 .

[249]  E. Archibald A Fourth State of Matter , 1880, Nature.

[250]  W. Crookes I. On a fourth state of matter, in a letter to the Secretary. By W. Crookes, F. R. S , 1880, Proceedings of the Royal Society of London.