Strategies to enhance the carbon monoxide sensitivity of tin oxide thin films

Abstract In this work electrical response of SnO 2 thin film as a function of thickness was studied in order to determine the optimum of this parameter to detect carbon monoxide, finding out that thickness around 200 nm showed the highest response. Structural characteristics of tin oxide such as grain size and net distortions were also analysed. On the other hand, a study of two catalytic metals (Pt and Pd) and their influence on sensing parameters was also carried out. Tests under controlled atmospheres and XPS analyses showed that the doping technique that provided a suitable quantity and doping profile of metal for CO detection was the so called “buried layer” when Pt was used as catalyst. Therefore, a deeper study of the latter film was performed, in order to establish some of its electrical characteristics, moisture influence on response and long-term stability.

[1]  Giorgio Sberveglieri,et al.  Classical and novel techniques for the preparation of SnO2 thin-film gas sensors☆ , 1992 .

[2]  V. Brynzari,et al.  SnO2 films for thin film gas sensor design , 1999 .

[3]  Norio Miura,et al.  Gas sensing properties of tin oxide thin films fabricated from hydrothermally treated nanoparticles: Dependence of CO and H2 response on film thickness , 2001 .

[4]  L. D. Angelis,et al.  Selectivity and stability of a tin dioxide sensor for methane , 1995 .

[5]  Jürgen Wöllenstein,et al.  Material properties and the influence of metallic catalysts at the surface of highly dense SnO2 films , 2000 .

[6]  S. Olaizola,et al.  Comparative structural study between sputtered and liquid pyrolysis nanocrystaline SnO2 , 2000 .

[7]  Julian W. Gardner,et al.  Modelling of gas-sensitive conducting polymer devices , 1995 .

[8]  R. Ionescu,et al.  The mechanism of the interaction between CO and an SnO2 surface: the role of water vapour , 1993 .

[9]  F. J. Gracia,et al.  Built-in active filter for an improved response to carbon monoxide combining thin- and thick-film technologies , 2002 .

[10]  Giorgio Sberveglieri,et al.  Recent developments in semiconducting thin-film gas sensors , 1995 .

[11]  K. Sturm,et al.  PLD of Pb(Zr,Ti)O3 films: Phase formation on various substrates , 1998 .

[12]  N. Bârsan,et al.  Micromachined metal oxide gas sensors: opportunities to improve sensor performance , 2001 .

[13]  Pietro Siciliano,et al.  SnO2 thin films for gas sensor prepared by r.f. reactive sputtering , 1995 .