Engine Combustion, performance and emission characteristics of gas to liquid (GTL) fuels and its blends with diesel and bio-diesel

Crude oil price hikes, energy security concerns and environmental drivers have turned the focus to alternative fuels. Gas to liquid (GTL) diesel is regarded as a promising alternative diesel fuel, considering the adeptness to use directly as a diesel fuel or in blends with petroleum-derived diesel or bio-diesel. GTL fuel derived from Fischer–Tropsch synthesis is of distinctly different characteristics than fossil diesel fuel due to its paraffinic nature, virtually zero sulfur, low aromatic contents and very high cetane number. GTL fuel is referred to as a “clean fuel” for its inherent ability to reduce engine exhaust emission even with blends of diesel and bio-diesel.

[1]  R. Pettit,et al.  MECHANISM OF THE FISCHER-TROPSCH REACTION. THE CHAIN PROPAGATION STEP , 1981 .

[2]  José Rodríguez-Fernández,et al.  Combustion characteristics and emissions of FischerTropsch diesel fuels in IC engines , 2011 .

[3]  David B. Kittelson,et al.  On-line measurements of diesel nanoparticle composition and volatility , 2003 .

[4]  Jan Czerwinski,et al.  Injection, Combustion and (Nano) Particle Emissions of a Modern HD-Diesel Engine With GTL, RME & ROR , 2007 .

[5]  Pravat K. Swain,et al.  Biomass to liquid: A prospective challenge to research and development in 21st century , 2011 .

[6]  Axel Munack,et al.  Comparison of exhaust emissions and their mutagenicity from the combustion of biodiesel, vegetable oil, gas-to-liquid and petrodiesel fuels , 2009 .

[7]  José Luis Valverde,et al.  Design and development of catalysts for Biomass-To-Liquid-Fischer–Tropsch (BTL-FT) processes for biofuels production , 2012 .

[8]  Zhen Huang,et al.  Effect of Port Fuel Injection of Methanol on the Combustion Characteristics and Emissions of Gas-to-Liquid-Fueled Engines , 2009 .

[9]  Francisco Payri,et al.  Thermo- and fluid-dynamic processes in diesel engines 2 : selected papers from the THIESEL 2002 conference held in Valencia, Spain, September 11-13, 2002 , 2002 .

[10]  Hewu Wang,et al.  Energy consumption and GHG emissions of GTL fuel by LCA: Results from eight demonstration transit buses in Beijing , 2010 .

[11]  D. J. Wilhelm,et al.  Syngas production for gas-to-liquids applications: technologies, issues and outlook , 2001 .

[12]  S. Boucher,et al.  Conversion of syngas to diesel , 2008 .

[13]  Leslie Eudy,et al.  Final Operability and Chassis Emissions Results from a Fleet of Class 6 Trucks Operating on Gas-to-Liquid Fuel and Catalyzed Diesel Particle Filters , 2005 .

[14]  Haji Hassan Masjuki,et al.  A comprehensive review on biodiesel as an alternative energy resource and its characteristics , 2012 .

[15]  Dimitrios T. Hountalas,et al.  Operational and Environmental Evaluation of Diesel Engines Burning Oxygen-Enriched Intake Air or Oxygen-Enriched Fuels: A Review , 2004 .

[16]  Mitsuharu Oguma,et al.  Experimental Study of Direct Injection Diesel Engine Fueled with Two Types of Gas To Liquid (GTL) , 2002 .

[17]  Robert Lee,et al.  Fuel Quality Impact on Heavy Duty Diesel Emissions:- A Literature Review , 1998 .

[18]  Stella Bezergianni,et al.  Comparison between different types of renewable diesel , 2013 .

[19]  T. Mahlia,et al.  A review on energy scenario and sustainable energy in Malaysia , 2010 .

[20]  Seref Soylu,et al.  The speed of sound and isentropic bulk modulus of biodiesel at 21°C from atmospheric pressure to 35 MPa , 2000 .

[21]  Koji Kitano,et al.  Improvement of DI Diesel Engine System by Utilizing GTL Fuels Characteristics , 2009 .

[22]  Dragomir B. Bukur,et al.  Fischer-Tropsch synthesis on Co/ZnO catalyst - Effect of pretreatment procedure , 2011 .

[23]  José Rodríguez-Fernández,et al.  Performance, combustion and emissions of a diesel engine operated with reformed EGR. Comparison of diesel and GTL fuelling , 2009 .

[24]  Iraj Isaac Rahmim,et al.  Stranded gas, diesel eds push GTL work , 2005 .

[25]  A. Megaritis,et al.  Effect of Gas-to-Liquid Diesel Fuels on Combustion Characteristics, Engine Emissions, and Exhaust Gas Fuel Reforming. Comparative Study , 2006 .

[26]  Patrik Soltic,et al.  Experimental investigation of mineral diesel fuel, GTL fuel, RME and neat soybean and rapeseed oil combustion in a heavy duty on-road engine with exhaust gas aftertreatment , 2009 .

[27]  Robert Güttel,et al.  Fischer–Tropsch synthesis in milli-structured fixed-bed reactors: Experimental study and scale-up considerations , 2010 .

[28]  James G. Speight,et al.  Hydrocarbons from synthesis gas , 2020, Handbook of Industrial Hydrocarbon Processes.

[29]  Rajamani Krishna,et al.  Design and scale up of a bubble column slurry reactor for Fischer–Tropsch synthesis , 2001 .

[30]  Octavio Armas,et al.  Effect of alternative fuels on exhaust emissions during diesel engine operation with matched combustion phasing , 2010 .

[31]  K. Kaygusuz Energy for sustainable development: A case of developing countries , 2012 .

[32]  Imad A. Khalek,et al.  Comparative emissions performance of sasol Fischer-Tropsch diesel fuel in current and older technology heavy-duty engines , 2000 .

[33]  Dushyant Shekhawat,et al.  catalytic partial oxidation , 2020, Catalysis from A to Z.

[34]  Matteo Lualdi,et al.  Fischer-Tropsch Synthesis over Cobalt-based Catalysts for BTL applications , 2012 .

[35]  Hans Schulz,et al.  Short history and present trends of Fischer–Tropsch synthesis , 1999 .

[36]  Mahmoud M. El-Halwagi,et al.  An Approach to the Design of Advanced Fischer-Tropsch Reactor for Operation in Near-Critical and Supercritical Phase Media , 2009 .

[37]  José Rodríguez-Fernández,et al.  Diesel Engine Performance and Emissions when First Generation Meets Next Generation Biodiesel , 2009 .

[38]  Mitsuharu Oguma,et al.  The Possibility of Gas to Liquid (GTL) as a Fuel of Direct Injection Diesel Engine , 2002 .

[39]  Arthur Bell,et al.  Comprehensive Applications Testing of Diesel from a Commercial Scale Gas-to-Liquids Plant , 2010 .

[40]  H. Sajjad,et al.  Fuel properties, engine performance and emission characteristic of common biodiesels as a renewable and sustainable source of fuel , 2013 .

[41]  Ulugbek Azimov,et al.  Visualization of Gas-to-Liquid (GTL) Fuel Liquid Length and Soot Formation in the Constant Volume Combustion Chamber , 2008 .

[42]  André L. Boehman,et al.  The Impact of the Bulk Modulus of Diesel Fuels on Fuel Injection Timing , 2004 .

[43]  Shinichi Goto,et al.  A Study of PM Emission Characteristics of Diesel Vehicle Fueled with GTL , 2007 .

[44]  Selçuk Bilgen,et al.  Renewable energy sources in Turkey for climate change mitigation and energy sustainability , 2012 .

[45]  Kebin He,et al.  Influence of fuel sulfur on the characterization of PM10 from a diesel engine , 2009 .

[46]  Wolfgang A. Herrmann,et al.  Organometallic Aspects of the Fischer‐Tropsch Synthesis , 1982 .

[47]  M. Rohde,et al.  Membrane application in Fischer–Tropsch synthesis reactors—Overview of concepts , 2005 .

[48]  Ezio Mancaruso,et al.  Premixed combustion of GTL and RME fuels in a single cylinder research engine , 2012 .

[49]  T. Mahlia,et al.  A review on energy scenario and sustainable energy in Indonesia , 2011 .

[50]  Thomas Panagopoulos,et al.  Green diesel from Fischer-Tropsch Synthesis: challenges and hurdles. , 2007 .

[51]  Richard Hugh Clark,et al.  Emissions Performance of Shell GTL Fuel in the Context of Future Fuel Specifications , 2006 .

[52]  Robert W. Dibble,et al.  Emissions Performance of Oxygenate-in-Diesel Blends and Fischer-Tropsch Diesel in a Compression Ignition Engine , 1999 .

[53]  K. Varatharajan,et al.  Influence of fuel properties and composition on NOx emissions from biodiesel powered diesel engines: A review , 2012 .

[54]  Eduardo Falabella Sousa-Aguiar,et al.  The main catalytic challenges in GTL (gas-to-liquids) processes , 2011 .

[55]  Arno de Klerk Fischer—Tropsch Refining: Technology Selection to Match Molecules , 2009 .

[56]  Eric D. Larson,et al.  High-Octane Gasoline Production by Upgrading Low-Temperature Fischer–Tropsch Syncrude , 2011 .

[57]  Nigel N. Clark,et al.  Heat Release and Emission Characteristics of B20 Biodiesel Fuels During Steady State and Transient Operation , 2008 .

[58]  Yong Wang,et al.  Preparation of a novel structured catalyst based on aligned carbon nanotube arrays for a microchannel Fischer-Tropsch synthesis reactor , 2005 .

[59]  Rahizar Ramli,et al.  Impact of various biodiesel fuels obtained from edible and non-edible oils on engine exhaust gas and noise emissions , 2013 .

[60]  Kadir Bilen,et al.  Energy production, consumption, and environmental pollution for sustainable development: A case study in Turkey , 2008 .

[61]  A. Sanjid,et al.  Impact of palm, mustard, waste cooking oil and Calophyllum inophyllum biofuels on performance and emission of CI engine , 2013 .

[62]  B. Jager Developments in Fischer-Tropsch technology , 1997 .

[63]  José M. Desantes,et al.  Effect of the Properties of Several Fuels on the Injection and Combustion Process in HSDI Diesel Engines , 2002 .

[64]  D. Leckel,et al.  Diesel Production from Fischer−Tropsch: The Past, the Present, and New Concepts , 2009 .

[65]  Zhen Huang,et al.  Emission characteristics of a turbocharged diesel engine fueled with gas-to-liquids , 2007 .

[66]  Y. Kidoguchi,et al.  Effects of Fuel Properties on Combustion and Emission Characteristics of a Direct-Injection Diesel Engine , 2000 .

[67]  Octavio Armas,et al.  Emissions from different alternative diesel fuels operating with single and split fuel injection , 2010 .

[68]  Francisco Payri,et al.  Characterisation of the Injection-Combustion Process in a Common Rail D.I. Diesel Engine Running with Sasol Fischer-Tropsch Fuel , 2000 .

[69]  Andy Yates,et al.  Investigation of the Combustion Characteristics of GTL Diesel Fuel in a Constant Volume Combustion Chamber , 2007 .

[70]  P. Schaberg,et al.  Comprehensive Evaluation of Exhaust Emissions with Diesel Fuel from a Commercial Scale Gas-to-Liquids Plant , 2010 .

[71]  David Balloy,et al.  Preparation of a multilayered composite catalyst for Fischer–Tropsch synthesis in a micro-chamber reactor , 2007 .

[72]  Koji Kitano,et al.  GTL Fuel Impact on DI Diesel Emissions , 2007 .

[73]  Mitsuharu Oguma,et al.  Fuel Characteristics Evaluation of GTL for DI Diesel Engine , 2004 .

[74]  C. Westbrook,et al.  Chemical kinetic modeling study of the effects of oxygenated hydrocarbons on soot emissions from diesel engines. , 2006, The journal of physical chemistry. A.

[75]  André L. Boehman,et al.  NOx emissions of alternative diesel fuels: A comparative analysis of biodiesel and FT diesel , 2005 .

[76]  Ivar Ivarsen Primdahl,et al.  Developments in Autothermal Reforming , 1998 .

[77]  Xiaoyu Yan,et al.  Life cycle analysis of energy use and greenhouse gas emissions for road transportation fuels in China , 2009 .

[78]  Noboru Miyamoto,et al.  Ultra Low Emission and High Performance Diesel Combustion with Highly Oxygenated Fuel , 2000 .

[79]  Greg Rideout,et al.  The Effect of Fuel Type and Aftertreatment Method on Ultrafine Particle Emissions from a Heavy-Duty Diesel Engine , 2007 .

[80]  Stefan de Goede,et al.  The Properties and Injector Nozzle Fouling Performance of Neat GTL and GTL/EN590 Diesel Blends in Various Diesel Engines , 2012 .

[81]  Zhen Huang,et al.  Particle size distribution from a GTL engine. , 2007, The Science of the total environment.

[82]  M. Dry High quality diesel via the Fischer–Tropsch process – a review , 2002 .

[83]  I. Wender Reactions of synthesis gas , 1996 .

[84]  Arno de Klerk,et al.  Can Fischer−Tropsch Syncrude Be Refined to On-Specification Diesel Fuel? , 2009 .

[85]  Leslie Eudy,et al.  Fuel Property, Emission Test, and Operability Results from a Fleet of Class 6 Vehicles Operating on Gas-To-Liquid Fuel and Catalyzed Diesel Particle Filters , 2004 .

[86]  Morteza Sohrabi,et al.  A comparison between two kinds of hydrodynamic models in bubble column slurry reactor during Fischer–Tropsch synthesis: Single-bubble class and two-bubble class , 2009 .

[87]  P. Samuel,et al.  GTL Technology - Challenges and Opportunities in Catalysis , 2003 .

[88]  Xunmin Ou,et al.  Alternative fuel buses currently in use in China: Life-cycle fossil energy use, GHG emissions and policy recommendations , 2010 .

[89]  Lawrence L. Tavlarides,et al.  Carbon deactivation of Fischer−Tropsch ruthenium catalyst , 1986 .

[90]  Robert L. McCormick,et al.  Fischer-Tropsch Diesel Fuels - Properties and Exhaust Emissions: A Literature Review , 2003 .

[91]  Liu Shenghua,et al.  Study on the Performance and Emissions of a Compression Ignition Engine Fuelled with Fischer-Tropsch Diesel Fuel , 2006 .

[92]  Richard Barney Carlson,et al.  Comparing the Performance of GTL/ULSD Blends in Older and Newer Diesel Passenger Cars , 2008 .

[93]  Richard Hugh Clark,et al.  Engine performance and emissions from the combustion of low-temperature Fischer-Tropsch synthetic diesel fuel and biodiesel rapeseed methyl ester blends , 2009 .

[94]  Huang Zhen,et al.  Emission reduction potential of using gas-to-liquid and dimethyl ether fuels on a turbocharged diesel engine. , 2009, The Science of the total environment.

[95]  Rudolf Maly,et al.  Emissions Performance of GTL Diesel Fuel and Blends with Optimized Engine Calibrations , 2005 .

[96]  A. Sanjid,et al.  Energy balance of internal combustion engines using alternative fuels , 2013 .

[97]  Yonggyu Lee,et al.  Emission characteristics of diesel, gas to liquid, and biodiesel-blended fuels in a diesel engine for passenger cars , 2010 .

[98]  James J. Eberhardt,et al.  On-Road Use of Fischer-Tropsch Diesel Blends , 1999 .

[99]  B. Buchholz,et al.  A Numerical Investigation into the Anomalous Slight NOx Increase when Burning Biodiesel: A New (Old) Theory , 2007 .

[100]  Hisashi Yokota,et al.  The Emission Performance of a GTL Diesel Fuel - a Japanese Market Study , 2003 .

[101]  Noboru Miyamoto,et al.  Smokeless, Low NOx, High Thermal Efficiency, and Low Noise Diesel Combustion with Oxygenated Agents as Main Fuel , 1998 .

[102]  John B. Heywood,et al.  Internal combustion engine fundamentals , 1988 .

[103]  Albert Renken,et al.  Gas–liquid and liquid–liquid mass transfer in microstructured reactors , 2011 .

[104]  Haji Hassan Masjuki,et al.  A review on emissions and mitigation strategies for road transport in Malaysia , 2011 .

[105]  Kamil Kaygusuz,et al.  Energy and environmental issues relating to greenhouse gas emissions for sustainable development in Turkey , 2009 .

[106]  Vilmar Æsøy,et al.  Emission characteristics of GTL fuel as an alternative to conventional marine gas oil , 2013 .

[107]  Hiroshi Yoshida,et al.  Diesel Engine Emissions and Performance Optimization for Neat GTL Fuel , 2008 .

[108]  Horst Harndorf,et al.  Motorisches Potenzial von synthetischen Dieselkraftstoffen , 2006 .

[109]  Johan E. Hustad,et al.  Experimental and thermodynamic studies of the catalytic partial oxidation of model biogas using a plasma-assisted gliding arc reactor , 2011 .

[110]  J. Rostrup-Nielsen New aspects of syngas production and use , 2000 .

[111]  Zoran Filipi,et al.  Simulation Study of a Series Hydraulic Hybrid Propulsion System for a Light Truck , 2007 .

[112]  M. Dry,et al.  Practical and theoretical aspects of the catalytic Fischer-Tropsch process , 1996 .

[113]  Bp Upstream 2002—Emergence of the Gas-to-Liquids Industry: a Review of Global GTL Developments , 2002 .

[114]  Hewu Wang,et al.  Performance of Euro III common rail heavy duty diesel engine fueled with Gas to Liquid , 2009 .

[115]  Stefan Pischinger,et al.  Potential of Synthetic Fuels in Future Combustion Systems for HSDI Diesel Engines , 2006 .

[116]  Octavio Armas,et al.  Effect of biodiesel fuels on diesel engine emissions , 2008 .

[117]  Xunmin Ou,et al.  Energy consumption and GHG emissions of six biofuel pathways by LCA in (the) People's Republic of China , 2009 .

[118]  Z. İlsen Önsan,et al.  Reactor Design for Fuel Processing , 2011 .

[119]  Octavio Armas,et al.  Potential for reducing emissions in a diesel engine by fuelling with conventional biodiesel and Fischer–Tropsch diesel , 2010 .

[120]  M. Dry,et al.  The Fischer–Tropsch process: 1950–2000 , 2002 .

[121]  José Rodríguez-Fernández,et al.  Combining GTL fuel, reformed EGR and HC-SCR aftertreatment system to reduce diesel NOx emissions. A statistical approach , 2009 .

[122]  Axel Munack,et al.  Fuel economy and emission characteristics of Gas-to-Liquid (GTL) and Rapeseed Methyl Ester (RME) as alternative fuels for diesel engines , 2012 .

[123]  J. W. Mitchell,et al.  Slurry-phase Fischer-Tropsch synthesis and kinetic studies over supported cobalt carbonyl derived catalysts , 1990 .

[124]  Ichiro Sakata,et al.  Effects of GTL fuel properties on DI diesel combustion , 2005 .

[125]  Huang Zhen,et al.  Emission characteristics of a turbocharged diesel engine fueled with gas-to-liquids , 2006 .

[126]  M. Dry,et al.  Fischer–Tropsch reactions and the environment , 1999 .

[127]  Mehmet Erturk,et al.  Economic analysis of unconventional liquid fuel sources , 2011 .

[128]  Chikezie Nwaoha,et al.  Gas-to-liquids (GTL): A review of an industry offering several routes for monetizing natural gas , 2012 .

[129]  H. Zhen,et al.  Effect of cetane number improver on heat release rate and emissions of high speed diesel engine fueled with ethanol–diesel blend fuel , 2004 .

[130]  Jim S. Cowart,et al.  Performance, Efficiency and Emissions Comparison of Diesel Fuel and a Fischer-Tropsch Synthetic Fuel in a CFR Single Cylinder Diesel Engine during High Load Operation , 2008 .

[131]  Johan E. Hustad,et al.  Experimental Investigation of Diesel Combustion and Exhaust Emissions Fuelled with Fischer-Tropsch-biodiesel Blends: Part-I , 2009 .

[132]  Nigel N. Clark,et al.  In-Cylinder Combustion Pressure Characteristics of Fischer-Tropsch and Conventional Diesel Fuels in a Heavy Duty CI Engine , 1999 .

[133]  Juhun Song,et al.  Examination of the oxidation behavior of biodiesel soot , 2006 .

[134]  Gisela Henrici-Olivé,et al.  The Fischer‐Tropsch Synthesis: Molecular Weight Distribution of Primary Products and Reaction Mechanism , 1976 .

[135]  Matthias Lamping,et al.  Dedicated GTL Vehicle: A Calibration Optimization Study , 2010 .

[136]  Thomas W. Ryan,et al.  The Effects of Fuel Properties on Emissions from a 2.5gm NOx Heavy-Duty Diesel Engine , 1998 .

[137]  Zhen Huang,et al.  Physical and Chemical Properties of GTL−Diesel Fuel Blends and Their Effects on Performance and Emissions of a Multicylinder DI Compression Ignition Engine , 2007 .

[138]  Anders Holmen,et al.  A review of catalytic partial oxidation of methane to synthesis gas with emphasis on reaction mechanisms over transition metal catalysts , 2008 .