Plasmonic energy collection through hot carrier extraction.

Conversion of light into direct current is important for applications ranging from energy conversion to photodetection, yet often challenging over broad photon frequencies. Here we show a new architecture based on surface plasmon excitation within a metal-insulator-metal device that produces power based on spatial confinement of electron excitation through plasmon absorption. Plasmons excited in the upper metal are absorbed, creating a high concentration of hot electrons which can inject above or tunnel through the thin insulating barrier, producing current. The theoretical power conversion efficiency enhancement achieved can be almost 40 times larger than that of direct illumination while utilizing a broad spectrum of IR to visible wavelengths. Here we present both theoretical estimates of the power conversion efficiency and experimental device measurements, which show clear rectification and power conversion behavior.

[1]  Mario Dagenais,et al.  Solar spectrum rectification using nano-antennas and tunneling diodes , 2010, OPTO.

[2]  B. Berland,et al.  Photovoltaic Technologies Beyond the Horizon: Optical Rectenna Solar Cell, Final Report, 1 August 2001-30 September 2002 , 2003 .

[3]  R. Franchy,et al.  Band gap of amorphous and well-ordered Al 2 O 3 on Ni 3 Al „ 100 ... , 2022 .

[4]  William C. Brown,et al.  The History of Power Transmission by Radio Waves , 1984 .

[5]  R. Franchy,et al.  Band gap of amorphous and well-ordered Al2O3 on Ni3Al(100) , 2001 .

[6]  Naomi J. Halas,et al.  Photodetection with Active Optical Antennas , 2011, Science.

[7]  A. Stesmans,et al.  Band alignments in metal–oxide–silicon structures with atomic-layer deposited Al2O3 and ZrO2 , 2002 .

[8]  J. R. Sambles,et al.  Optical excitation of surface plasmons: An introduction , 1991 .

[9]  Shanhui Fan,et al.  OVERVIEW OF SIMULATION TECHNIQUES FOR PLASMONIC DEVICES , 2007 .

[10]  H. Raether Surface Plasmons on Smooth and Rough Surfaces and on Gratings , 1988 .

[11]  Kevin Welford,et al.  Surface plasmon-polaritons and their uses , 1991 .

[12]  R. L. Bailey,et al.  A Proposed New Concept for a Solar-Energy Converter , 1972 .

[13]  Alexei A. Maradudin,et al.  Excitation of surface polaritons by end-fire coupling. , 1983, Optics letters.

[14]  Stephen V. Pepper,et al.  Optical analysis of photoemission , 1970 .

[15]  B. Ealet,et al.  Electronic and crystallographic structure of γ-alumina thin films , 1994 .

[16]  D. Diesing,et al.  Photo and particle induced transport of excited carriers in thin film tunnel junctions , 2007 .

[17]  Kai Chang,et al.  Theoretical and experimental development of 10 and 35 GHz rectennas , 1992 .

[18]  K. Gundlach Theory of metal‐insulator‐metal tunneling for a simple two‐band model , 1973 .

[19]  J. Kadlec,et al.  Interfacial barrier height measurement from voltage dependence of the photocurrent , 1975 .

[20]  Moskovits,et al.  Light-induced kinetic effects in solids. , 1996, Physical review. B, Condensed matter.

[21]  R. Powell Interface Barrier Energy Determination from Voltage Dependence of Photoinjected Currents , 1970 .

[22]  K. Malloy,et al.  Surface plasmon modes of finite, planar, metal-insulator-metal plasmonic waveguides. , 2008, Optics express.

[23]  W. Spicer,et al.  Photoemission studies of the noble metals. II - Gold , 1970 .

[24]  G. D. Scott,et al.  Optical excitation of surface plasma waves in layered media , 1977 .

[25]  Helmut Kanter,et al.  Slow-Electron Mean Free Paths in Aluminum, Silver, and Gold , 1970 .

[26]  Subramanian Krishnan,et al.  Design and development of batch fabricatable metal–insulator–metal diode and microstrip slot antenna as rectenna elements , 2008 .