Synergistic Effect between Metal-Nitrogen-Carbon Sheets and NiO Nanoparticles for Enhanced Electrochemical Water-Oxidation Performance.

Identifying effective means to improve the electrochemical performance of oxygen-evolution catalysts represents a significant challenge in several emerging renewable energy technologies. Herein, we consider metal-nitrogen-carbon sheets which are commonly used for catalyzing the oxygen-reduction reaction (ORR), as the support to load NiO nanoparticles for the oxygen-evolution reaction (OER). FeNC sheets, as the advanced supports, synergistically promote the NiO nanocatalysts to exhibit superior performance in alkaline media, which is confirmed by experimental observations and density functional theory (DFT) calculations. Our findings show the advantages in considering the support effect for designing highly active, durable, and cost-effective OER electrocatalysts.

[1]  V. Stamenkovic,et al.  Enhancing Hydrogen Evolution Activity in Water Splitting by Tailoring Li+-Ni(OH)2-Pt Interfaces , 2011, Science.

[2]  Timothy R. Cook,et al.  Solar energy supply and storage for the legacy and nonlegacy worlds. , 2010, Chemical reviews.

[3]  Charles C. L. McCrory,et al.  Benchmarking heterogeneous electrocatalysts for the oxygen evolution reaction. , 2013, Journal of the American Chemical Society.

[4]  Gang Wu,et al.  High-Performance Electrocatalysts for Oxygen Reduction Derived from Polyaniline, Iron, and Cobalt , 2011, Science.

[5]  Tom Regier,et al.  Co₃O₄ nanocrystals on graphene as a synergistic catalyst for oxygen reduction reaction. , 2011, Nature materials.

[6]  M. Biesinger,et al.  X‐ray photoelectron spectroscopic chemical state quantification of mixed nickel metal, oxide and hydroxide systems , 2009 .

[7]  A. Hirata,et al.  Nanoporous Metal Enhanced Catalytic Activities of Amorphous Molybdenum Sulfide for High‐Efficiency Hydrogen Production , 2014, Advanced materials.

[8]  M. Grätzel.  Photoelectrochemical cells : Materials for clean energy , 2001 .

[9]  Shouheng Sun,et al.  Tuning nanoparticle catalysis for the oxygen reduction reaction. , 2013, Angewandte Chemie.

[10]  Shouheng Sun,et al.  Optimierte Nanopartikel‐Katalyse für die Sauerstoffreduktionsreaktion , 2013 .

[11]  Daniel G. Nocera,et al.  In Situ Formation of an Oxygen-Evolving Catalyst in Neutral Water Containing Phosphate and Co2+ , 2008, Science.

[12]  Allen J. Bard,et al.  Artificial Photosynthesis: Solar Splitting of Water to Hydrogen and Oxygen , 1995 .

[13]  S. Trasatti.  Electrocatalysis in the anodic evolution of oxygen and chlorine , 1984 .

[14]  Jyhfu Lee,et al.  Strong metal-support interactions between gold nanoparticles and ZnO nanorods in CO oxidation. , 2012, Journal of the American Chemical Society.

[15]  Maria Chan,et al.  Trends in activity for the water electrolyser reactions on 3d M(Ni,Co,Fe,Mn) hydr(oxy)oxide catalysts. , 2012, Nature materials.

[16]  Frédéric Jaouen,et al.  Iron-Based Catalysts with Improved Oxygen Reduction Activity in Polymer Electrolyte Fuel Cells , 2009, Science.

[17]  Piotr Zelenay,et al.  A class of non-precious metal composite catalysts for fuel cells , 2006, Nature.

[18]  Hailiang Wang,et al.  Strongly coupled inorganic/nanocarbon hybrid materials for advanced electrocatalysis. , 2013, Journal of the American Chemical Society.

[19]  Q. Wang,et al.  K7[CoIIICoII(H2O)W11O39]: a molecular mixed-valence Keggin polyoxometalate catalyst of high stability and efficiency for visible light-driven water oxidation , 2013 .

[20]  Matthew W Kanan,et al.  Mechanistic studies of the oxygen evolution reaction by a cobalt-phosphate catalyst at neutral pH. , 2010, Journal of the American Chemical Society.

[21]  Zhe Wang,et al.  Biodegradable gold nanovesicles with an ultrastrong plasmonic coupling effect for photoacoustic imaging and photothermal therapy. , 2013, Angewandte Chemie.

[22]  T. Meyer,et al.  Proton-coupled electron transfer. , 2007, Chemical reviews.

[23]  Hua Zhang,et al.  The chemistry of two-dimensional layered transition metal dichalcogenide nanosheets. , 2013, Nature chemistry.

[24]  Tom Regier,et al.  An advanced Ni-Fe layered double hydroxide electrocatalyst for water oxidation. , 2013, Journal of the American Chemical Society.

[25]  Younan Xia,et al.  Formkontrolle bei der Synthese von Metallnanokristallen: einfache Chemie, komplexe Physik? , 2009 .

[26]  J. Barandiaran,et al.  Magnetite biomineralization in Magnetospirillum gryphiswaldense: time-resolved magnetic and structural studies. , 2013, ACS nano.

[27]  Shouheng Sun,et al.  Co/CoO nanoparticles assembled on graphene for electrochemical reduction of oxygen. , 2012, Angewandte Chemie.

[28]  F. Jiao,et al.  Nanostructured cobalt oxide clusters in mesoporous silica as efficient oxygen-evolving catalysts. , 2009, Angewandte Chemie.

[29]  Xiaofeng Yang,et al.  Single-atom catalysis of CO oxidation using Pt1/FeOx. , 2011, Nature chemistry.

[30]  P. Atanassov,et al.  Elucidating Oxygen Reduction Active Sites in Pyrolyzed Metal–Nitrogen Coordinated Non-Precious-Metal Electrocatalyst Systems , 2014, The journal of physical chemistry. C, Nanomaterials and interfaces.

[31]  M. Flytzani-Stephanopoulos,et al.  Alkali-metal-promoted Pt/TiO2 opens a more efficient pathway to formaldehyde oxidation at ambient temperatures. , 2012, Angewandte Chemie.

[32]  A. Bell,et al.  Enhanced activity of gold-supported cobalt oxide for the electrochemical evolution of oxygen. , 2011, Journal of the American Chemical Society.

[33]  D. Sokaras,et al.  Understanding Interactions between Manganese Oxide and Gold That Lead to Enhanced Activity for Electrocatalytic Water Oxidation , 2014, Journal of the American Chemical Society.

[34]  James R. McKone,et al.  Solar water splitting cells. , 2010, Chemical reviews.

[35]  S. Ardizzone,et al.  "Inner" and "outer" active surface of RuO2 electrodes , 1990 .

[36]  S. Boettcher,et al.  Solution-cast metal oxide thin film electrocatalysts for oxygen evolution. , 2012, Journal of the American Chemical Society.

[37]  Ralph E. White,et al.  Comprehensive Treatise of Electrochemistry , 1981 .

[38]  S. Mukerjee,et al.  Activity descriptor identification for oxygen reduction on nonprecious electrocatalysts: linking surface science to coordination chemistry. , 2013, Journal of the American Chemical Society.

[39]  Yang Shao-Horn,et al.  Double perovskites as a family of highly active catalysts for oxygen evolution in alkaline solution , 2013, Nature Communications.

[40]  Eduardo C. Escudero‐Adán,et al.  Fast and persistent electrocatalytic water oxidation by Co-Fe Prussian blue coordination polymers. , 2013, Journal of the American Chemical Society.

[41]  Mietek Jaroniec,et al.  Three-dimensional N-doped graphene hydrogel/NiCo double hydroxide electrocatalysts for highly efficient oxygen evolution. , 2013, Angewandte Chemie.

[42]  H. Dai,et al.  High-Performance Silicon Photoanodes Passivated with Ultrathin Nickel Films for Water Oxidation , 2013, Science.

[43]  Vittal K. Yachandra,et al.  Structure-activity correlations in a nickel-borate oxygen evolution catalyst. , 2012, Journal of the American Chemical Society.

[44]  S. Hammes-Schiffer,et al.  Theory of proton-coupled electron transfer in energy conversion processes. , 2009, Accounts of chemical research.

[45]  T. Moore,et al.  Photochemical synthesis of a water oxidation catalyst based on cobalt nanostructures. , 2011, Journal of the American Chemical Society.

[46]  T. Jaramillo,et al.  A bifunctional nonprecious metal catalyst for oxygen reduction and water oxidation. , 2010, Journal of the American Chemical Society.

[47]  Jun Jiang,et al.  Water oxidation electrocatalyzed by an efficient Mn3O4/CoSe2 nanocomposite. , 2012, Journal of the American Chemical Society.

[48]  Ang Li,et al.  Mesoporous anatase TiO2 nanocups with plasmonic metal decoration for highly active visible-light photocatalysis. , 2013, Chemical communications.

[49]  Younan Xia,et al.  Shape-controlled synthesis of metal nanocrystals: simple chemistry meets complex physics? , 2009, Angewandte Chemie.

[50]  M. Langell,et al.  Comparison of Nanoscaled and Bulk NiO Structural and Environmental Characteristics by XRD, XAFS, and XPS , 2012 .

[51]  Zhipan Zhang,et al.  Photochemical Route for Accessing Amorphous Metal Oxide Materials for Water Oxidation Catalysis , 2013, Science.

[52]  Daniel G Nocera,et al.  The artificial leaf. , 2012, Accounts of chemical research.

[53]  Yong Zhao,et al.  Nitrogen-doped carbon nanomaterials as non-metal electrocatalysts for water oxidation , 2013, Nature Communications.

[54]  Tewodros Asefa,et al.  Efficient noble metal-free (electro)catalysis of water and alcohol oxidations by zinc-cobalt layered double hydroxide. , 2013, Journal of the American Chemical Society.

[55]  Raymond J. Kopp,et al.  Energy Resources and Global Development , 2003, Science.

[56]  Haeshin Lee,et al.  Mussel-Inspired Surface Chemistry for Multifunctional Coatings , 2007, Science.

[57]  M. Fontecave,et al.  A Janus cobalt-based catalytic material for electro-splitting of water. , 2012, Nature materials.

[58]  Lehui Lu,et al.  Polydopamine and its derivative materials: synthesis and promising applications in energy, environmental, and biomedical fields. , 2014, Chemical reviews.

[59]  J. Goodenough,et al.  A Perovskite Oxide Optimized for Oxygen Evolution Catalysis from Molecular Orbital Principles , 2011, Science.

[60]  N. Lewis,et al.  Powering the planet: Chemical challenges in solar energy utilization , 2006, Proceedings of the National Academy of Sciences.

[61]  Qiushi Yin,et al.  A Fast Soluble Carbon-Free Molecular Water Oxidation Catalyst Based on Abundant Metals , 2010, Science.

[62]  A. Bell,et al.  In Situ Raman Study of Nickel Oxide and Gold-Supported Nickel Oxide Catalysts for the Electrochemical Evolution of Oxygen , 2012 .

[63]  Qiang Xu,et al.  Iron-nanoparticle-catalyzed hydrolytic dehydrogenation of ammonia borane for chemical hydrogen storage. , 2008, Angewandte Chemie.

[64]  B. Wiley,et al.  Optically transparent water oxidation catalysts based on copper nanowires. , 2013, Angewandte Chemie.

[65]  R. Li,et al.  A highly durable platinum nanocatalyst for proton exchange membrane fuel cells: multiarmed starlike nanowire single crystal. , 2011, Angewandte Chemie.