Durability assessment of alkali activated slag (AAS) concrete

The environmental impact from the production of cement has prompted research into the development of concretes using 100% replacement materials activated by alkali solutions. This paper reports research into the durability of AAS concrete. The durability properties of AAS have been studied for a range of sodium oxide dosages and activator modulus. Properties investigated have included measurements of workability, compressive strength, water sorptivity, depth of carbonation and rapid chloride permeability. Microstructure studies have been conducted using scanning electron microscopy and energy dispersive X-ray spectroscopy. It was concluded that an activator modulus of between 1.0 and 1.25 was identified as providing the optimum performance for a sodium oxide dosage of 5% and that AAS concretes can exhibit comparable strength to concrete currently produced using Portland cement (PC) and blended cements. However, with regards to the durability properties such as water sorptivity, chloride and carbonation resistance; the AAS concretes exhibited lower durability properties than PC and blended concretes. This, in part, can be attributed to surface microcracking in the AAS concretes.

[1]  J. Deventer,et al.  Direct measurement of the kinetics of geopolymerisation by in-situ energy dispersive X-ray diffractometry , 2007 .

[2]  Bernhard Elsener Corrosion of Steel in Concrete , 2013 .

[3]  V. Papadakis Effect of supplementary cementing materials on concrete resistance against carbonation and chloride ingress , 2000 .

[4]  Shi Caijun,et al.  Investigation on some factors affecting the characteristics of alkali-phosphorus slag cement , 1989 .

[5]  K. Tuutti Corrosion of steel in concrete , 1982 .

[6]  J. Sanjayan,et al.  Microcracking and strength development of alkali activated slag concrete , 2001 .

[7]  Jay G. Sanjayan,et al.  Early age strength and workability of slag pastes activated by NaOH and Na2CO3 , 1998 .

[8]  Yong-De Li,et al.  Preliminary study on combined-alkali–slag paste materials , 2000 .

[9]  C. Hall,et al.  Water sorptivity of mortars and concretes: a review , 1989 .

[10]  B. Talling,et al.  Present State and Future of Alkali-Activated Slag Concretes , 1989, "SP-114: Fly Ash, Silica Fume, Slag, and Natural Pozzolans in Concrete: Proceedings of the Third International Conference".

[11]  Jay G. Sanjayan,et al.  Cracking tendency of alkali-activated slag concrete subjected to restrained shrinkage , 2000 .

[12]  Tarja Häkkinen,et al.  THE INFLUENCE OF SLAG CONTENT ON THE MICROSTRUCTURE, PERMEABILITY AND MECHANICAL PROPERTIES OF CONCRETE. PART 1: MICROSTRUCTURAL STUDIES AND BASIC MECHANICAL PROPERTIES , 1993 .

[13]  Frank Collins,et al.  Effect of pore size distribution on drying shrinkage of alkali-activated slag concrete , 2000 .

[14]  Julia A. Stegemann,et al.  Effect of supplementary cementing materials on the specific conductivity of pore solution and its implications on the rapid chloride permeability test (AASHTO T277 and ASTM C1202) results , 1998 .

[15]  P. L. Pratt,et al.  Factors affecting the strength of alkali-activated slag , 1994 .

[16]  V. Lehtonen,et al.  Durability of Concrete Made With Alkali-Activated Slag , 1989, "SP-114: Fly Ash, Silica Fume, Slag, and Natural Pozzolans in Concrete: Proceedings of the Third International Conference".

[17]  Jiang‐Jhy Chang,et al.  A study on the setting characteristics of sodium silicate-activated slag pastes , 2003 .

[18]  F. Lea The chemistry of cement and concrete , 1970 .

[19]  A. Neville Properties of Concrete , 1968 .

[20]  S. Al-Otaibi,et al.  Durability of concrete incorporating GGBS activated by water-glass , 2008 .

[21]  Ravindra K. Dhir,et al.  Concrete containing ternary blended binders: Resistance to chloride ingress and carbonation , 1997 .

[22]  K. Scrivener,et al.  Hydration products of alkali activated slag cement , 1995 .

[23]  J. Sykes,et al.  Sodium silicate-based alkali-activated slag mortars: Part II. The retarding effect of additions of sodium chloride or malic acid , 2000 .

[24]  Harold E. McGannon The making, shaping and treating of steel , 1971 .

[25]  Darko Krizan,et al.  Effects of dosage and modulus of water glass on early hydration of alkali–slag cements , 2002 .

[26]  Jay G. Sanjayan,et al.  Resistance of alkali-activated slag concrete to carbonation , 2001 .

[27]  A. Atkinson,et al.  Sodium silicate-based, alkali-activated slag mortars: Part I. Strength, hydration and microstructure , 2002 .

[28]  J. I. Escalante-García,et al.  Coarse blast furnace slag as a cementitious material, comparative study as a partial replacement of Portland cement and as an alkali activated cement , 2009 .

[29]  Tarja Häkkinen,et al.  The influence of slag content on the microstructure, permeability and mechanical properties of concrete: Part 2 technical properties and theoretical examinations , 1993 .

[30]  H. Jennings,et al.  Hydration of alkali-activated ground granulated blast furnace slag , 2000 .

[31]  Francisca Puertas,et al.  Alkali-activated slag mortars: Mechanical strength behaviour , 1999 .

[32]  J. Mietz Corrosion Books: Corrosion of Steel in Concrete. By: Luca Bertolini, Bernhard Elsener, Pietro Pedeferri, Rob Polder , 2004 .

[33]  R E Franklin,et al.  Design of normal concrete mixes , 1975 .

[34]  R. H. Atkinson Recent advances in the applied chemistry of the rare metals. Jubilee memorial lecture , 1940 .

[35]  Zhihua Pan,et al.  Hydration products of alkali-activated slag–red mud cementitious material , 2002 .

[36]  N. Roussel,et al.  An environmental evaluation of geopolymer based concrete production: reviewing current research trends , 2011 .