Effect of nanoscale precipitation on strengthening of ferritic ODS Fe–Cr–Al alloy

Abstract The kinetics of Fe rich α and Cr rich α′ phase separation during aging of Fe–Cr–Al oxide dispersion strengthened alloys have been analysed with a combination of atom probe tomography and thermoelectric power measurements. The slight lattice parameter decrease measured by X-ray diffraction after thermal aging was associated with a lattice misfit between the emerging α and α′ domains. The elastic strain associated with this misfit and the different elastic moduli for the α and α′ phases would produce an increase in internal stresses that would retard the motion of dislocations and thus would be the main cause for the strengthening.

[1]  H. Bhadeshia,et al.  Strain heterogeneity and the production of coarse grains in mechanically alloyed iron-based PM2000 alloy , 2001 .

[2]  C. Capdevila,et al.  Manufacturing and Microstructural Evolution of Mechanuically Alloyed Oxide Dispersion Strengthened Superalloys , 2001 .

[3]  J. Cahn,et al.  Divergent pearlite in a manganese eutectoid steel , 1963 .

[4]  C. Capdevila,et al.  Influence of recrystallization on phase separation kinetics of oxide dispersion strengthened Fe–Cr–Al alloy , 2012 .

[5]  Manuel Roussel,et al.  Kinetic study of phase transformation in a highly concentrated Fe–Cr alloy: Monte Carlo simulation versus experiments , 2011 .

[6]  Michael K Miller,et al.  Phase separation kinetics in a Fe–Cr–Al alloy , 2012 .

[7]  C. Capdevila,et al.  Heterogeneous deformation and recrystallisation of iron base oxide dispersion strengthened PM2000 alloy , 2001 .

[8]  Andrew G. Glen,et al.  APPL , 2001 .

[9]  J. Pelletier,et al.  Temperature and concentration dependences of thermoelectric power at high temperatures in some aluminium alloys , 1982 .

[10]  Dieter Isheim,et al.  Analysis of Three-dimensional Atom-probe Data by the Proximity Histogram , 2000, Microscopy and Microanalysis.

[11]  Giovanni Bonny,et al.  New Contribution to the Thermodynamics of Fe-Cr Alloys as Base for Ferritic Steels , 2010 .

[12]  C. Capdevila,et al.  Influence of the α-α' phase separation on the tensile properties of Fe-base ODS PM 2000 alloy , 2010 .

[13]  G. G. Stokes "J." , 1890, The New Yale Book of Quotations.

[14]  Roger E. Stoller,et al.  Stability of nanometer-sized oxide clusters in mechanically-alloyed steel under ion-induced displacement cascade damage conditions , 2007 .

[15]  Michael K Miller,et al.  Embrittlement of RPV steels: An atom probe tomography perspective , 2007 .

[16]  J. G. Sevillano Comment on “Lattice constant dependence of elastic modulus for ultrafine grained mild steel” , 2003 .

[17]  C. Capdevila Oxide coarsening and its influence on recrystallization in a mechanically alloyed Fe-base oxide-dispersion-strengthened alloy , 2005 .

[18]  Influence of Deformation on Recrystallization of an Yttrium Oxide Dispersion‐Strengthened Iron Alloy (PM2000) , 2003 .

[19]  Olena KALOKHTINA,et al.  Atom Probe Tomography , 2012 .

[20]  Margaret Nichols Trans , 2015, De-centering queer theory.

[21]  Francisca García Caballero,et al.  Thermoelectric power studies on a martensitic stainless steel , 2004 .

[22]  M. Harada,et al.  Alloying design of oxide dispersion strengthened ferritic steel for long life FBRs core materials , 1993 .

[23]  A. Cerezo,et al.  Comparison of low temperature decomposition in FeCr and duplex stainless steels , 1995 .

[24]  J. Christian,et al.  The theory of transformations in metals and alloys , 2003 .

[25]  R. Lagneborg Deformation in an iron-30% chromium alloy aged at 475°c , 1967 .

[26]  C. M. Elliott,et al.  Spinodal decomposition in Fe-Cr alloys: Experimental study at the atomic level and comparison with computer models—I. Introduction and methodology , 1995 .

[27]  C. Pareige,et al.  Atomic scale analysis and phase separation understanding in a thermally aged Fe–20 at.%Cr alloy , 2009 .

[28]  W. Marsden I and J , 2012 .

[29]  J. Jiménez,et al.  Assessment of factors influencing surface recrystallisation during high temperature exposure of fine-grained PM 2000 alloy , 2007 .

[30]  R. Borrelly,et al.  Study of aluminium nitride precipitation in pure FeAlN alloy by thermoelectric power measurements , 1997 .