Improved methanol tolerance using Pt/C in cathode of direct methanol fuel cell

Membrane-electrode assemblies (MEAs) were prepared using PtRu black and 60 wt% carbon-supported platinum (Pt/C) as their anode and cathode catalysts, respectively. The cathode catalyst layers were fabricated using various amounts of Pt (0.5, 1.0, 2.0 and 3.0 mg/cm 2 ). To study the effect of carbon support on performance, an MEA in which Pt black was used as the cathode catalyst was fabricated. In addition, the effect of methanol crossover on the Pt/C on the cathode side of a direct methanol fuel cell (DMFC) was investigated. The performance of the single cell that used Pt/C as the cathode catalyst was higher than that of the single cell that used Pt black, and this result was pronounced when highly concentrated methanol (above 2.0M) was used as the fuel.

[1]  Biswa R. Padhy,et al.  Performance of DMFC with SS 316 bipolar/end plates , 2006 .

[2]  C. Bernard,et al.  Etude de la reduction de l'oxygene sur les phtalocyanines monomeres et polymeres—II: Polyphtalocyanines de fer impregnees sur noir d'acetylene Y , 1974 .

[3]  K. Eguchi,et al.  Selective removal of NO by absorption in mixed oxide catalysts , 1996 .

[4]  K. Okajima,et al.  Structural control and impedance analysis of cathode for direct methanol fuel cell , 2005 .

[5]  S. Srinivasan,et al.  International activities in DMFC R&D: status of technologies and potential applications , 2004 .

[6]  E. Gonzalez,et al.  Structure and Activity of Carbon-Supported Pt−Co Electrocatalysts for Oxygen Reduction , 2004 .

[7]  Antonino S. Aricò,et al.  Performance of DMFC anodes with ultra-low Pt loading , 2004 .

[8]  J. Kerres Development of ionomer membranes for fuel cells , 2001 .

[9]  Y. Sung,et al.  Pd-based PdPt(19:1)/C electrocatalyst as an electrode in PEM fuel cell , 2007 .

[10]  J. Zagal,et al.  Linear versus volcano correlations between electrocatalytic activity and redox and electronic properties of metallophthalocyanines , 1998 .

[11]  K. Kreuer,et al.  On the development of proton conducting materials for technological applications , 1997 .

[12]  Taeghwan Hyeon,et al.  High-performance direct methanol fuel cell electrodes using solid-phase-synthesized carbon nanocoils. , 2003, Angewandte Chemie.

[13]  Tatyana V. Reshetenko,et al.  Performance of a direct methanol fuel cell (DMFC) at low temperature: Cathode optimization , 2006 .

[14]  Yuhao Lu,et al.  The electrochemical behavior of cobalt phthalocyanine/platinum as methanol-resistant oxygen-reduction electrocatalysts for DMFC , 2007 .

[15]  M. Mulder,et al.  Characterization of polymer blends of polyethersulfone/sulfonated polysulfone and polyethersulfone/sulfonated polyetheretherketone for direct methanol fuel cell applications , 2002 .

[16]  Jong-Ho Choi,et al.  Electro-oxidation of methanol and formic acid on PtRu and PtAu for direct liquid fuel cells , 2006 .

[17]  H. Gasteiger,et al.  Oxygen Reduction on Ru1.92Mo0.08SeO4, Ru/Carbon, and Pt/Carbon in Pure and Methanol‐Containing Electrolytes , 2000 .

[18]  H. Gasteiger,et al.  Activity benchmarks and requirements for Pt, Pt-alloy, and non-Pt oxygen reduction catalysts for PEMFCs , 2005 .

[19]  Y. Sung,et al.  PtRh alloy nanoparticle electrocatalysts for oxygen reduction for use in direct methanol fuel cells , 2006 .

[20]  S. Kaliaguine,et al.  Sulfonated polyether ether ketone based composite polymer electrolyte membranes , 2001 .

[21]  Weijiang Zhou,et al.  Pt-based anode catalysts for direct ethanol fuel cells , 2004 .

[22]  C. Pu,et al.  Carbon supported and unsupported Pt–Ru anodes for liquid feed direct methanol fuel cells , 1998 .

[23]  Shimshon Gottesfeld,et al.  High performance direct methanol polymer electrolyte fuel cells , 1996 .

[24]  Y. Sung,et al.  A Pd-impregnated nanocomposite Nafion membrane for use in high-concentration methanol fuel in DMFC , 2003 .

[25]  M. Othman,et al.  Proton conducting composite membrane from sulfonated poly(ether ether ketone) and boron orthophosphate for direct methanol fuel cell application , 2007 .