Diiron σ-π alkenyl complexes: crystal structures of cis-[Fe2(CO)4(μ-RCCH2)(μ-PPh2)(μ-dppm)], (R Ph, CH2OH), trans-[Fe2(CO)4(μ-HCCHPh)(μ-PPh2)(μ-dppm)] and the α,β-unsaturated acyl complex trans-[Fe2(CO)4{μ-OCC(Ph)CH2}(μ-PCy2)(μ-dppm)]

[1]  G. Hogarth,et al.  Diiron-Hydride Complexes: Synthesis, Structure, and Reactivity of trans-[Fe2(CO)4(.mu.-H)(.mu.-CO)(.mu.-PCy2)(.mu.-Ph2PCH2PPh2)] , 1995 .

[2]  J. Dewan,et al.  Novel Products from Reactions of Li[(.mu.-CO)(.mu.-RS)Fe2(CO)6] Salts with Ethoxyacetylene , 1994 .

[3]  Y. Chi,et al.  Fluxional behavior of the .sigma.,.pi.-vinyl complexes Os2[.mu.-CH:C(H)Ph](.mu.-Br)(CO)6-n(PPh3)n (n = 1, 2): use of 13C[1H] NOE and 187Os-13C couplings in assignment of carbonyls , 1993 .

[4]  G. Hogarth,et al.  The reactivity of bridging hydride ligands at the di-iron centre. Synthesis and reactivity towards alkynes of [Fe2(CO)6(μ-H)(μ-CO)(μ-dppm)][BF4]. X-ray crystal structure of [Fe2(CO)6(μ-PhCCH2)(μ-dppm)][BF4] , 1992 .

[5]  R. W. Hilts,et al.  Reactions of triethylammonium salts of the [(.mu.-CO)(.mu.-RS)Fe2(CO)6]- anion with alkyl-, aryl-, and vinylmercuric halides. Formal C-alkylation of the bridging CO ligand , 1991 .

[6]  J. Zubieta,et al.  Binuclear iron-manganese acetyl and hydride complexes from the reactions of Cp(CO)2FePPh2 with MeMn(CO)5 and HMn(CO)5 , 1984 .

[7]  J. Gallucci,et al.  Novel mode of reduction of phosphido-bridged, metal-metal-bonded binuclear complexes. Synthesis and reactivity of an unsymmetrical anion from bis(.mu.-diphenylphosphido)hexacarbonyldiiron [Fe2(CO)6(.mu.-PPh2)2] , 1983 .

[8]  N. Taylor,et al.  Carbonylation and amination of .mu.-.eta.2-acetylides in M2(CO)6(.mu.-.eta.2-C.tplbond.CPh)(PPh2): synthesis of .mu.-O:CCHC(Ph)NR2 complexes and the x-ray structure of Ru2(CO)6[.mu.-O:CCHC(Ph)NEt2](PPh2) , 1983 .