Controlling Inkjet Fluid Kinematics to Achieve SOFC Cathode Micropatterns

Drop-on-demand inkjet printing a mask-less, fine write, and high throughput technique is attractive for fabricating miniature ceramic devices. In this study, high quality, fine-featured solid oxide fuel cell (SOFC) cathode micropatterns were demonstrated using inkjet printing. The influence of the droplet kinematic properties on final drop deposition was studied by adjusting ink temperature and droplet velocity to obtain a wide range of Weber and Z values, i.e. 0 35 printing defects from splashes and satellites were present. At Weber < 35 the droplets coalesced into uniform, round circles without splashes or satellite defects. Defect-free printing was essential toward achieving uniform micropatterens such as micro dot arrays or micro lines which are on the scale of 100 microns or less. © The Author(s) 2015. Published by ECS. This is an open access article distributed under the terms of the Creative Commons Attribution Non-Commercial No Derivatives 4.0 License (CC BY-NC-ND, http://creativecommons.org/licenses/by-nc-nd/4.0/), which permits non-commercial reuse, distribution, and reproduction in any medium, provided the original work is not changed in any way and is properly cited. For permission for commercial reuse, please email: oa@electrochem.org. [DOI: 10.1149/2.0031504jss] All rights reserved.

[1]  F. Štěpánek,et al.  Fabrication of composite microcapsules by drop-on-demand inkjet: Effect of precursor composition on the process limits , 2011 .

[2]  R. Tomov,et al.  Direct ceramic inkjet printing of yttria-stabilized zirconia electrolyte layers for anode-supported solid oxide fuel cells , 2010 .

[3]  Brian Derby,et al.  Ink Jet Deposition of Ceramic Suspensions: Modeling and Experiments of Droplet Formation , 2000 .

[4]  Bartek A. Glowacki,et al.  Optimisation of CGO suspensions for inkjet-printed SOFC electrolytes , 2012 .

[5]  Thomas L. Reitz,et al.  Inkjet Printing of Anode Supported SOFC: Comparison of Slurry Pasted Cathode and Printed Cathode , 2009 .

[6]  K. Prakasan,et al.  Studies on rheology of ceramic inks and spread of ink droplets for direct ceramic ink jet printing , 2006 .

[7]  H. Wijshoff,et al.  The dynamics of the piezo inkjet printhead operation , 2010 .

[8]  Koichi Kikuta,et al.  Application of a thin intermediate cathode layer prepared by inkjet printing for SOFCs , 2010 .

[9]  Michael Rottmayer,et al.  Ink-jet printing of electrolyte and anode functional layer for solid oxide fuel cells , 2008 .

[10]  Huey-Jiuan Lin,et al.  Study of Micro-Droplet Behavior for a Piezoelectric Inkjet Printing Device Using a Single Pulse Voltage Pattern , 2004 .

[11]  Thierry Chartier,et al.  3D fine scale ceramic components formed by ink-jet prototyping process , 2005 .

[12]  Jooho Moon,et al.  Relationship between printability and rheological behavior of ink-jet conductive inks , 2013 .

[13]  Fritz B. Prinz,et al.  Atomic layer deposition of yttria-stabilized zirconia for solid oxide fuel cells , 2007 .

[14]  Brian Derby,et al.  Inkjet printing ceramics: from drops to solid , 2011 .

[15]  Chia-Yen Chan,et al.  Effects of actuating waveform, ink property, and nozzle size on piezoelectrically driven inkjet droplets , 2010 .

[16]  F. Prinz,et al.  Solid oxide fuel cell with corrugated thin film electrolyte. , 2008, Nano letters.

[17]  Patrick J. Smith,et al.  Direct ink-jet printing and low temperature conversion of conductive silver patterns , 2006 .

[18]  C. Herran,et al.  Drop-on-demand for aqueous solutions of sodium alginate , 2013 .

[19]  Fritz B. Prinz,et al.  High-Performance Ultrathin Solid Oxide Fuel Cells for Low-Temperature Operation , 2007 .

[20]  Jooho Moon,et al.  Influence of fluid physical properties on ink-jet printability. , 2009, Langmuir : the ACS journal of surfaces and colloids.

[21]  R. Telle,et al.  An experimental analysis of the influence of the ink properties on the drop formation for direct thermal inkjet printing of high solid content aqueous 3Y-TZP suspensions , 2010 .

[22]  J. E. Fromm,et al.  Numerical calculation of the fluid dynamics of drop-on-demand jets , 1984 .