Biomass and fossil fuel conversion by pressurised fluidised bed gasification using hot gas ceramic filters as gas cleaning

Abstract Gasification of biomass and fossil fuels, hot gas cleanup using a ceramic filter and combustion of LCV product gas in a combustor were performed using a 1.5 MWth test rig (pressurised bubbling fluidised bed gasifier) at Delft University and a 10– 50 kWth system at Stuttgart University (DWSA) in the framework of experimental research on efficient, environmentally acceptable large-scale power generators based on fluidised bed gasification. The influence of operating conditions (pressure, temperature, stoichiometric ratio) on gasification (gas composition, conversion grades) was studied. The gasifiers were operated in a pressure range of 0.15– 0.7 MPa and maximum temperatures of ca. 900°C. The Delft gasifier has a 2 m high bed zone (diameter: 0.4 m ) followed by a freeboard approximately 4 m high (diameter: 0.5 m ). The IVD gasifier has a diameter of 0.1 m and a reactor length of 4 m . Carbon conversions during wood, miscanthus and brown coal gasification experiments were well above 80%. Fuel-nitrogen conversion to ammonia was above ca. 50% and the highest values were observed for biomass. The results are in line with other investigations with biomass bottom feeding. Deviation occurs compared with top feeding. Measurements are compared with simulation results of a reaction-kinetics-based model, using ASPEN PLUS, related to emission of components like fuel-nitrogen-derived species. Data from literature regarding initial biomass flash pyrolysis in the gasification process are used in the gasifier model and will be compared with simulation results from the FG-DVC model. Measurements and model predictions were in reasonably good agreement with each other.

[1]  N. Padban PFB Air Gasification of Biomass, Investigation of Product Formation and Problematic Issues Related to Ammonia, Tar and Alkali , 2000 .

[2]  Jouni P. Hämäläinen,et al.  Conversion of fuel nitrogen through HCN and NH3 to nitrogen oxides at elevated pressure , 1996 .

[3]  H. Spliethoff,et al.  Tar quantification with a new online analyzing method , 2000 .

[4]  Esa Kurkela,et al.  Pressurized fluidized-bed gasification experiments with wood, peat and coal at VTT in 1991-1992: Part 1. Test facilities and gasification experiments with sawdust , 1993 .

[5]  Michael A. Serio,et al.  Modeling of biomass pyrolysis kinetics , 1998 .

[6]  Claes Brage,et al.  Use of amino phase adsorbent for biomass tar sampling and separation , 1997 .

[7]  Jukka Leppälahti,et al.  Nitrogen evolution from coal, peat and wood during gasification: Literature review , 1995 .

[8]  K. Sjöström,et al.  Provisional protocol for the sampling and anlaysis of tar and particulates in the gas from large-scale biomass gasifiers. Version 1998 ☆ , 2000 .

[9]  Krister Sjöström,et al.  Biomass gasification in a laboratory-scale AFBG: influence of the location of the feeding point on the fuel-N conversion , 2000 .

[10]  T. A. Milne,et al.  Biomass Gasifier "Tars": Their Nature, Formation, and Conversion , 1998 .

[11]  Jorma Nieminen,et al.  Kinetic Modeling Study on the Potential of Staged Combustion in Gas Turbines for the Reduction of Nitrogen Oxide Emissions from Biomass IGCC Plants , 2000 .

[12]  Peter Dirk Jilles Hoppesteyn Application of Low Calorific Value Gaseous Fuels in Gas Turbine Combustors , 1999 .

[13]  G. Simons,et al.  The Structure of Coal Char: Part I—Pore Branching , 1979 .

[14]  J. Mačák,et al.  Mathematical Model for the Gasification of Coal under Pressure , 1978 .

[15]  T. Shimizu,et al.  Hydrolysis and oxidation of hydrogen cyanide over limestone under fluidized bed combustion conditions , 1993 .

[16]  Anthony V. Bridgwater,et al.  Progress in Thermochemical Biomass Conversion , 2001 .