论文信息 - Epoxidation of Polyolefin by Peroxy Acid Generated in situ

Epoxidation of Polyolefin by Peroxy Acid Generated in situ

The epoxidation of a new type polyolefin copolymer, poly(ethylene-co-1,9-decadiene) (PED) was carried out with performic acid produced in situ from formic acid and 35% hydrogen peroxide. The reaction was performed at room temperature or at 50 °C with conversion of vinyl group in the polymer chain and high selectivity to epoxide.

[1] A. S. Hay,et al. Catalytic epoxidation of styrene–butadiene triblock copolymer with hydrogen peroxide , 1991 .

[2] A. S. Hay,et al. Catalytic epoxidation of polyisobutylene-co-isoprene with hydrogen peroxide , 1991 .

[3] K. Udipi. Epoxidation of styrene–butadiene block polymers. II , 1979 .

[4] R. Hanzlik,et al. Transition state structure for peracid epoxidation. Secondary deuterium isotope effects , 1975 .

[5] M. Senō,et al. Solvent Effects on Epoxidation Reaction of Butadiene by Perbenzoic Acid , 1970 .