Electrochemical carboxylation with carbon dioxide

Abstract Studies carried out in the past two years on electrochemical fixation of carbon dioxide with carbon-carbon bond formation, so-called electrochemical carboxylation or electrocarboxylation, are reviewed. Among about twenty papers on electrochemical carboxylation published from 2014 to the present, recent advances in electrochemical carboxylation regarding asymmetric carboxylation, sacrificial anode-free carboxylation, and carboxylation following aryl radical cyclization are focused on and discussed.

[1]  Tetsuaki Fujihara,et al.  Carbon dioxide as a carbon source in organic transformation: carbon-carbon bond forming reactions by transition-metal catalysts. , 2012, Chemical communications.

[2]  K. Yoneda,et al.  Electrochemical direct carboxylation of benzyl alcohols having an electron-withdrawing group on the phenyl ring: one-step formation of phenylacetic acids from benzyl alcohols under mild conditions , 2015 .

[3]  D. Velayutham,et al.  Ionic liquids as an electrolyte for the electro synthesis of organic compounds. , 2015, Chemical communications.

[4]  V. Suryanarayanan,et al.  Efficient electrocarboxylation of benzophenone on silver nanoparticles deposited boron doped diamond electrode , 2015 .

[5]  H. Senboku.  Electrochemical Fixation of Carbon Dioxide , 2014 .

[6]  Jia‐Xing Lu,et al.  Electrocarboxylation of haloacetophenones at silver electrode , 2014 .

[7]  S. Hara,et al.  Aryl radical cyclization with alkyne followed by tandem carboxylation in methyl 4-tert-butylbenzoate-mediated electrochemical reduction of 2-(2-propynyloxy)bromobenzenes in the presence of carbon dioxide , 2016 .

[8]  Jan Fransaer,et al.  Electrocarboxylation: towards sustainable and efficient synthesis of valuable carboxylic acids , 2014, Beilstein journal of organic chemistry.

[9]  M. Atobe,et al.  Electrochemical fixation of CO2 to organohalides in room-temperature ionic liquids under supercritical CO2 , 2015 .

[10]  E. Steckhan,et al.  Electrochemical oxidation of chiral 5-substituted 2-oxazolidinones: A key building block for dichiral β-amino alcohols , 1996 .

[11]  Xiao-hua Cai,et al.  Direct Carboxylative Reactions for the Transformation of Carbon Dioxide into Carboxylic Acids and Derivatives , 2013 .

[12]  Jia‐Xing Lu,et al.  CO2 as a C1-organic building block: Enantioselective electrocarboxylation of aromatic ketones with CO2catalyzed by cinchona alkaloids under mild conditions , 2014 .

[13]  F. Beck,et al.  Anodic oxidation of -cyanoethyl ethers , 1985 .

[14]  Tsuyoshi Fukuhara,et al.  Three-component coupling reaction of benzylic halides, carbon dioxide, and N,N-dimethylformamide by using paired electrolysis: sacrificial anode-free efficient electrochemical carboxylation of benzylic halides , 2015 .

[15]  Jia‐Xing Lu,et al.  Asymmetric electrocarboxylation of 1-phenylethyl chloride catalyzed by electrogenerated chiral [CoI(salen)]− complex , 2014 .

[16]  S. Gambino,et al.  Sacrificial Anodes in the Electrocarboxylation of Organic Chlorides , 1984 .

[17]  J. Périchon,et al.  Electrosynthesis of carboxylic acids from organic halides and carbon dioxide , 1985 .

[18]  Jan Fransaer,et al.  Paired Electrosynthesis of Diacid and Diol Precursors Using Dienes and CO2 as the Carbon Source , 2015 .

[19]  Alan M. Bond,et al.  Electrocarboxylation of acetophenone in ionic liquids: the influence of proton availability on product distribution , 2014 .

[20]  Svante Wold,et al.  Use of Sacrificial Anodes in Synthetic Electrochemistry. Processes Involving Carbon Dioxide , 1992 .

[21]  Hiroyuki Tateno,et al.  Development of a novel electrochemical carboxylation system using a microreactor , 2015 .

[22]  Jia‐Xing Lu,et al.  Selective electrocarboxylation of bromostyrene at silver cathode in DMF , 2016 .

[23]  J. Périchon,et al.  Use of Sacrificial Anodes in Electrochemical Functionalization of Organic Halides , 1990 .