A mathematical model of sulphite chemical aggression of limestones with high permeability. Part I. Modeling and qualitative analysis

We introduce a degenerate nonlinear parabolic–elliptic system, which describes the chemical aggression of limestones under the attack of SO2, in high permeability regime. By means of a dimensional scaling, the qualitative behavior of the solutions in the fast reaction limit is investigated. Explicit asymptotic conditions for the front formation are derived.

[1]  Th. Skoulikidis,et al.  Mechanism of Sulphation by Atmospheric SO2 of the Limestones and Marbles of the Ancient Monuments and Statues: I. Observations in situ (Acropolis) and laboratory measurements , 1981 .

[2]  Milton Abramowitz,et al.  Handbook of Mathematical Functions with Formulas, Graphs, and Mathematical Tables , 1964 .

[3]  S. Hassanizadeh,et al.  A non-linear theory of high-concentration-gradient dispersion in porous media , 1995 .

[4]  Jerrold Bebernes,et al.  Mathematical Problems from Combustion Theory , 1989 .

[5]  Gas-solid reaction with porosity change. , 2000 .

[6]  P. Adler,et al.  Deposition in porous media and clogging on the field scale. , 2005, Physical review. E, Statistical, nonlinear, and soft matter physics.

[7]  Roberto Natalini,et al.  A Mathematical Model for the Sulphur Dioxide Aggression to Calcium Carbonate Stones: Numerical Approximation and Asymptotic Analysis , 2004, SIAM J. Appl. Math..

[8]  G. I. Barenblatt,et al.  Theory of Fluid Flows Through Natural Rocks , 1990 .

[9]  P. Ortoleva,et al.  A weakly nonlinear stability analysis of the reactive infiltration interface , 1988 .

[10]  Akira Rinoshika,et al.  Effects of initial conditions on a wavelet-decomposed turbulent near-wake. , 2005, Physical review. E, Statistical, nonlinear, and soft matter physics.

[11]  A. Bejan,et al.  Convection in Porous Media , 1992 .

[12]  Fred H. Haynie Deterioration of marble , 1983 .

[13]  Th. Skoulikidis,et al.  Mechanism of Sulphation by Atmospheric SO2 of the Limestones and Marbles of the Ancient Monuments and Statues: II. Hypothesis concerning the rate determining step in the process of sulphation, and its experimental confirmation , 1981 .

[14]  Frederick W. Lipfert,et al.  Atmospheric damage to calcareous stones: Comparison and reconciliation of recent experimental findings , 1989 .

[15]  Li Ying,et al.  A geochemical reaction-transport simulator for matrix acidizing analysis and design , 1997 .

[16]  Global existence of solutions to a nonlinear model of sulphation phenomena in calcium carbonate stones , 2005 .

[17]  D. Turcotte,et al.  Weathering and damage , 2002 .

[18]  Danielle Hilhorst,et al.  The Fast Reaction Limit for a Reaction-Diffusion System , 1996 .

[19]  A mathematical model of sulphite chemical aggression of limestones with high permeability. Part II: Numerical approximation , 2007 .

[20]  A. M. Meirmanov,et al.  The Stefan Problem , 1992 .

[21]  John Crank,et al.  The Mathematics Of Diffusion , 1956 .

[22]  Giovanni G. Amoroso,et al.  Stone Decay and Conservation: Atmospheric Pollution, Cleaning, Consolidation and Protection , 1983 .

[23]  A. Peirce,et al.  Stability of reactive flows in porous media: coupled porosity and viscosity changes , 1991 .

[24]  D. Hoff,et al.  Reactive Infiltration Instabilities , 1986 .