TITANIUM(IV) COMPLEXES OF CHELATING 2-(SALICYLIDENEAMINO) BENZENETHIOL

Abstract This paper describes the synthesis and structural features of titanium(IV) complexes of biologically active Z-(salicylideneamino) benzenethiol. The complexes have been synthesized by the reaction of Ticl4 with the sodium salt of the ligand (prepared in situ) in different Stoichiometric ratios and are characterized by elemental analyses, molecular weights, and spectral (IR, 1H and 13C NMR) studies.

[1]  S. Khan,et al.  SYNTHESIS AND CHARACTERISATION OF TITANIUM(IV) COMPLEXES OF BENZILMONOTHIOSEMICARBAZONE , 1997 .

[2]  R. Mülhaupt,et al.  NINE-MEMBERED TITANACYCLIC COMPLEXES BASED ON AN ETHYLENE-BRIDGED BIS(PHENOLATO) LIGAND : SYNTHESIS, STRUCTURE, AND OLEFIN POLYMERIZATION ACTIVITY , 1997 .

[3]  E. Negishi,et al.  Titanium-catalyzed cascade carboalumination of 2-alkyl-substituted dienes and related trienes , 1996 .

[4]  Xiaoxiang Liu,et al.  EFFICIENT CHIRAL POISONING OF RACEMIC TITANIUM CATALYSTS FOR THE ASYMMETRIC CHLORAL-ENE REACTION , 1996 .

[5]  R. T. Yang,et al.  New Adsorbents Based on Principles of Chemical Complexation: Monolayer-Dispersed Nickel(II) for Acetylene Separation by π-Complexation , 1996 .

[6]  R. Sustmann,et al.  Reaction of 1,2-diketones with N,N-dimethylcyanamide in the presence of titanium(IV) chloride , 1996 .

[7]  W. M. Davis,et al.  Synthesis of Titanium Complexes That Contain Triamido−Amine Ligands , 1996 .

[8]  M. Sasidharan,et al.  Titanium silicate molecular sieve, TS-1, catalysed C–C bond formation in Mukaiyama type aldol reactions , 1996 .

[9]  S. Kaliaguine,et al.  Synthesis and characterization of a novel titanium aluminophosphate molecular sieve with ATS structure: TAPO-36 , 1996 .

[10]  K. Hadjiivanov,et al.  Surface chemistry of titania (anatase) and titania-supported catalysts , 1996 .

[11]  C. Detellier,et al.  [{Ti(μ‐CH3)5(μ‐CH2)}{(tmeda)Li}3] · THF: An Unusual and Highly Fluxional Titanium Organometallic Compound , 1995 .

[12]  R. C. Fay,et al.  STEREOCHEMICALLY RIGID SEVEN-COORDINATE COMPLEXES. SYNTHESIS, STRUCTURE, AND DYNAMIC STEREOCHEMISTRY OF CHLOROTRIS(N,N-DIALKYLMONOTHIOCARBAMATO)TITANIUM(IV) COMPLEXES , 1979 .

[13]  M. Campbell Transition metal complexes of thiosemicarbazide and thiosemicarbazones , 1975 .

[14]  S. Livingstone,et al.  Metal complexes of sulphur-nitrogen chelating agents , 1974 .

[15]  A. El-Toukhy,et al.  Coordination compounds of hydrazine derivatives with transition metals. V. Square planar nickel(II) complexes with hydrazine-S-methyl dithiocarboxylate schiff bases☆ , 1972 .

[16]  K. Ison,et al.  Magnetic behaviour of bivalent copper complexes of some tridentate Schiff bases , 1970 .

[17]  C. J. Jones,et al.  Complexes of transition metals with Schiff bases and the factors influencing their redox properties. Part I. Nickel and copper complexes of some diketone bisthiosemicarbazones , 1970 .

[18]  R. Feld,et al.  The organic chemistry of titanium , 1965 .

[19]  C. H. Bayley,et al.  Antifungal Activity of Some Thiosemicarbazones and Their Copper Complexes. , 1960, Applied microbiology.

[20]  F. Pansy,et al.  THE CHEMOTHERAPY OF EXPERIMENTAL TUBERCULOSIS I , 1950, Journal of bacteriology.

[21]  J. W. COOK,et al.  A Text-Book of Practical Organic Chemistry , 1948, Nature.

[22]  C. Lenoir,et al.  Bull. Soc. Chim. France , 1915 .