The Spatial–Temporal Variation of Tropospheric NO2 over China during 2005 to 2018

In recent years, new and strict air quality regulations have been implemented in China. Therefore, it is of great significance to evaluate the current air pollution situation and effectiveness of actions. In this study, Ozone Monitoring Instrument (OMI) satellite data were used to detect the spatiotemporal characteristics of tropospheric NO2 columns over China from 2005 to 2018, including spatial distribution, seasonal cycles and long-term trends. The averaged NO2 pollution is higher in southeastern China and lower in the northwest, which are well delineated by the Heihe–Tengchong line. Furthermore, the NO2 loadings are highest in the North China Plain, with vertical column density (VCD) exceeding 13 × 1015 molec cm−2. Regarding the seasonal cycle, the NO2 loadings in eastern China is highest in winter and lowest in summer, while the western region shows the opposite feature. The amplitude of annual range increase gradually from the south to the north. If the entire period of 2005–2018 is taken into account, China has experienced little change in NO2. In fact, however, there appears to be significant trends of an increase followed by a downward tendency, with the turning point in the year 2012. In the former episode of 2005–2012, increasing trends overwhelm nearly the whole nation, especially in the Jing–Jin–Tang region, Shandong Province, and Northern Henan and Southern Hebei combined regions, where the rising rates were as high as 1.0–1.8 × 1015 molec cm−2 year−1. In contrast, the latter episode of 2013–2018 features remarkable declines in NO2 columns over China. Particularly, the regions where the decreased degree was remarkable in 2013–2018 were consistent with the regions where the upward trend was obvious in 2005–2012. Overall, this upward–downward pattern is true for most parts of China. However, some of the largest metropolises, such as Beijing, Shanghai and Guangzhou, witnessed a continuous decrease in the NO2 amounts, indicating earlier and more stringent measures adopted in these areas. Finally, it can be concluded that China’s recent efforts to cut NO2 pollution are successful, especially in mega cities.

[1]  Henk Eskes,et al.  Error analysis for tropospheric NO2 retrieval from space , 2004 .

[2]  Henk Eskes,et al.  Detection of the trend and seasonal variation in tropospheric NO2 over China , 2006 .

[3]  L. G. Tilstra,et al.  The Ozone Monitoring Instrument: overview of 14 years in space , 2017 .

[4]  K. Boersma,et al.  Trends, seasonal variability and dominant NOx source derived from a ten year record of NO2 measured from space , 2008 .

[5]  John P. Burrows,et al.  TROPOSPHERIC NO2 FROM GOME MEASUREMENTS , 2002 .

[6]  Yu-kuan Wang,et al.  Spatiotemporal Characteristics of Air Pollutants (PM10, PM2.5, SO2, NO2, O3, and CO) in the Inland Basin City of Chengdu, Southwest China , 2018 .

[7]  J. Veefkind,et al.  Validation of Ozone Monitoring Instrument nitrogen dioxide columns , 2008 .

[8]  F. Hendrick,et al.  Spatial and temporal changes in SO2 regimes over China in the recent decade and the driving mechanism , 2018, Atmospheric Chemistry and Physics.

[9]  Klaus Pfeilsticker,et al.  Global tropospheric NO2 column distributions' Comparing three-dimensional model calculations with GOME , 2001 .

[10]  James F. Gleason,et al.  A new stratospheric and tropospheric NO2 retrieval algorithm for nadir-viewing satellite instruments : applications to OMI , 2013 .

[11]  P. Kasibhatla,et al.  The relative impact of stratospheric photochemical production on tropospheric NO y levels: A model study , 1991 .

[12]  James F. Gleason,et al.  Validation of OMI tropospheric NO2 column densities using direct‐Sun mode Brewer measurements at NASA Goddard Space Flight Center , 2008 .

[13]  Henk Eskes,et al.  Evaluation of stratospheric NO2 retrieved from the Ozone Monitoring Instrument : intercomparison, diurnal cycle and trending , 2011 .

[14]  K. F. Boersma,et al.  Trends and trend reversal detection in 2 decades of tropospheric NO2 satellite observations , 2019, Atmospheric Chemistry and Physics.

[15]  F. Hendrick,et al.  The Spatial and Temporal Variability of Tropospheric NO2 during 2005–14 over China Observed by the OMI , 2015 .

[16]  R. Martin,et al.  Global deposition of total reactive nitrogen oxides from 1996 to 2014 constrained with satellite observations of NO 2 columns , 2017 .

[17]  G. Carmichael,et al.  MIX: a mosaic Asian anthropogenic emission inventory under the international collaboration framework of the MICS-Asia and HTAP , 2017 .

[18]  J. Veefkind,et al.  Comparison of tropospheric NO2 from in situ aircraft measurements with near-real-time and standard product data from OMI , 2008 .

[19]  William Lahoz,et al.  Recent satellite-based trends of tropospheric nitrogen dioxide over large urban agglomerations worldwide , 2014 .

[20]  Wei Ge,et al.  Spatial–Temporal Variations in NO2 and PM2.5 over the Chengdu–Chongqing Economic Zone in China during 2005–2015 Based on Satellite Remote Sensing , 2018, Sensors.

[21]  P. Palmer,et al.  Asian emissions of CO and NOx : Constraints from aircraft and Chinese station data , 2004 .

[22]  S. Beirle,et al.  NOx emission trends over Chinese cities estimated from OMI observations during 2005 to 2015. , 2017, Atmospheric chemistry and physics.

[23]  Michael B. McElroy,et al.  Detection from space of a reduction in anthropogenic emissions of nitrogen oxides during the Chinese economic downturn , 2011 .

[24]  Heikki Saari,et al.  The ozone monitoring instrument , 2006, IEEE Transactions on Geoscience and Remote Sensing.

[25]  Yang Liu,et al.  Effects of air pollution control policies on PM2.5 pollution improvement in China from 2005 to 2017: a satellite-based perspective , 2019, Atmospheric Chemistry and Physics.

[26]  Philipp Schneider,et al.  A global single‐sensor analysis of 2002–2011 tropospheric nitrogen dioxide trends observed from space , 2012 .

[27]  James F. Gleason,et al.  Evaluation of OMI operational standard NO 2 column retrievals using in situ and surface-based NO 2 observations , 2014 .

[28]  Lei Ding,et al.  The Spatial-Temporal Characteristics and Influential Factors of NOx Emissions in China: A Spatial Econometric Analysis , 2018, International journal of environmental research and public health.

[29]  Yang Li,et al.  Population distribution and urbanization on both sides of the Hu Huanyong Line: Answering the Premier’s question , 2016, Journal of Geographical Sciences.

[30]  G. Carmichael,et al.  Biomass burning in Asia: Annual and seasonal estimates and atmospheric emissions , 2003 .

[31]  John P. Burrows,et al.  Validation of SCIAMACHY tropospheric NO2-columns with AMAXDOAS measurements , 2004 .

[32]  Henk Eskes,et al.  Validation of urban NO 2 concentrations and their diurnal and seasonal variations observed from the SCIAMACHY and OMI sensors using in situ surface measurements in Israeli cities , 2009 .

[33]  Shixin Wang,et al.  Analysis of the tropospheric column nitrogen dioxide over China based on satellite observations during 2008–2017 , 2019, Atmospheric Pollution Research.

[34]  Henk Eskes,et al.  Intercomparison of SCIAMACHY nitrogen dioxide observations, in situ measurements and air quality modeling results over Western Europe , 2007 .

[35]  N. Krotkov,et al.  Characterization of OMI tropospheric NO 2 over the Baltic Sea region , 2014 .

[36]  K. F. Boersma,et al.  Comparison of OMI NO 2 observations and their seasonal and weekly cycles with ground-based measurements in Helsinki , 2016 .

[37]  H. Levy,et al.  Empirical model of global soil‐biogenic NOχ emissions , 1995 .

[38]  K. Gui,et al.  The spatial temporal variation and factor analysis of the tropospheric NO2 columns in the Sichuan Basin from 2005 to 2016 , 2018, Atmospheric Pollution Research.

[39]  David G. Streets,et al.  Aura OMI observations of regional SO2 and NO2 pollution changes from 2005 to 2015 , 2015 .

[40]  王 普才,et al.  奥运期间北京地区卫星监测NO 2 柱浓度的变化 , 2009 .

[41]  Y. Wang,et al.  Assessing Spatial and Temporal Patterns of Observed Ground-level Ozone in China , 2017, Scientific Reports.

[42]  Y. Yun,et al.  Declining hailstorm frequency in China during 1961–2015 and its potential influential factors , 2018 .

[43]  James F. Gleason,et al.  Algorithm for NO/sub 2/ vertical column retrieval from the ozone monitoring instrument , 2006, IEEE Transactions on Geoscience and Remote Sensing.

[44]  Mengistu Wolde,et al.  High‐Resolution Mapping of Nitrogen Dioxide With TROPOMI: First Results and Validation Over the Canadian Oil Sands , 2019, Geophysical research letters.

[45]  Who Europe Air Quality Guidelines Global Update 2005: Particulate Matter, ozone, nitrogen dioxide and sulfur dioxide , 2006 .

[46]  Nicolas Theys,et al.  Cleaning up the air: effectiveness of air quality policy for SO 2 and NO x emissions in China , 2016 .

[47]  Nicolas Theys,et al.  Evaluation of tropospheric SO 2 retrieved from MAX-DOAS measurements in Xianghe, China , 2014 .

[48]  K. F. Boersma,et al.  Near-real time retrieval of tropospheric NO 2 from OMI , 2006 .