Indoor application of emerging photovoltaics—progress, challenges and perspectives

The development of solution-processed photovoltaic (PV) devices for indoor applications has recently attracted widespread attention owing to their outstanding potential in harvesting energy efficiently for low-power-consumption electronic devices, such as wireless sensors and internet of things (IoT). In particular, organic PVs (OPVs), perovskite PVs (PPVs) and quantum dot PVs (QDPVs) are among the most promising emerging photovoltaic technologies that have already demonstrated strong commercialisation potential for this new market, owing to their excellent yet highly tuneable optoelectronic properties to meet the demands for specific applications. In this review, we summarise the recent progress in the development of OPVs, PPVs and QDPVs for indoor applications, showing the rapid advances in their device performance in conjunction with highly diverse materials and device designs, including semi-transparent, flexible and large-area devices. The remaining challenges of these emerging indoor PV technologies that need to be urgently addressed toward their commercialisation, including, in particular, their limited stability and high ecotoxicity, will be discussed in detail. Potential strategies to address these challenges will also be proposed.

[1]  J. Shim,et al.  Ternary Blend Strategy for Achieving High-Efficiency Organic Photovoltaic Devices for Indoor Applications. , 2019, Chemistry.

[2]  Jianqi Zhang,et al.  Single‐Junction Organic Photovoltaic Cells with Approaching 18% Efficiency , 2020, Advanced materials.

[3]  Harrison Ka Hin Lee,et al.  Is organic photovoltaics promising for indoor applications , 2016 .

[4]  Jing Li,et al.  Dynamic Antisolvent Engineering for Spin Coating of 10 × 10 cm 2 Perovskite Solar Module Approaching 18% , 2020, Solar RRL.

[5]  Zhe Li,et al.  From fullerene acceptors to non-fullerene acceptors: prospects and challenges in the stability of organic solar cells , 2019, Journal of Materials Chemistry A.

[6]  Masahiro Hosoya,et al.  Investigation of the organic solar cell characteristics for indoor LED light applications , 2015 .

[7]  P. Smowton,et al.  Colloidal quantum dot hybrids: an emerging class of materials for ambient lighting , 2020, Journal of Materials Chemistry C.

[8]  A. Djurišić,et al.  Tailoring Triple‐Anion Perovskite Material for Indoor Light Harvesting with Restrained Halide Segregation and Record High Efficiency Beyond 36% , 2019, Advanced Energy Materials.

[9]  Kai Zhu,et al.  Scalable fabrication of perovskite solar cells , 2018 .

[10]  Rajan Jose,et al.  Progress, challenges and perspectives in flexible perovskite solar cells , 2016 .

[11]  Thomas M. Brown,et al.  Efficient light harvesting from flexible perovskite solar cells under indoor white light-emitting diode illumination , 2017, Nano Research.

[12]  Jong Min Kim,et al.  Highly Monodispersed PbS Quantum Dots for Outstanding Cascaded-Junction Solar Cells , 2016, ACS energy letters.

[13]  Shuchi Gupta,et al.  Infrared Solution‐Processed Quantum Dot Solar Cells Reaching External Quantum Efficiency of 80% at 1.35 µm and Jsc in Excess of 34 mA cm−2 , 2018, Advanced materials.

[14]  A. Abate,et al.  Enhancement in lifespan of halide perovskite solar cells , 2019, Energy & Environmental Science.

[15]  Moonyong Kim,et al.  Device design rules and operation principles of high-power perovskite solar cells for indoor applications , 2020 .

[16]  Behrang H. Hamadani,et al.  Photovoltaic Characterization Under Artificial Low Irradiance Conditions Using Reference Solar Cells , 2020, IEEE Journal of Photovoltaics.

[17]  Zhe Li,et al.  The role of fullerenes in the environmental stability of polymer:fullerene solar cells , 2018 .

[18]  Zhe Li,et al.  Multiphoton Absorption Stimulated Metal Chalcogenide Quantum Dot Solar Cells under Ambient and Concentrated Irradiance , 2020, Advanced Functional Materials.

[19]  Francesca De Rossi,et al.  All Printable Perovskite Solar Modules with 198 cm2 Active Area and Over 6% Efficiency , 2018, Advanced Materials Technologies.

[20]  Moungi G. Bawendi,et al.  Improved performance and stability in quantum dot solar cells through band alignment engineering , 2014, Nature materials.

[21]  Hang Yin,et al.  Highly‐Transparent and True‐Colored Semitransparent Indoor Photovoltaic Cells , 2020 .

[22]  Zhe Li,et al.  Toward Improved Environmental Stability of Polymer:Fullerene and Polymer:Nonfullerene Organic Solar Cells: A Common Energetic Origin of Light- and Oxygen-Induced Degradation , 2019, ACS energy letters.

[23]  Philip Schulz,et al.  Defect Tolerance in Methylammonium Lead Triiodide Perovskite , 2016 .

[24]  S. Priya,et al.  Record Efficiency Stable Flexible Perovskite Solar Cell Using Effective Additive Assistant Strategy , 2018, Advanced materials.

[25]  L. Cinà,et al.  Efficient fully laser-patterned flexible perovskite modules and solar cells based on low-temperature solution-processed SnO2/mesoporous-TiO2 electron transport layers , 2018, Nano Research.

[26]  Michael Woodhouse,et al.  Economic competitiveness of III–V on silicon tandem one‐sun photovoltaic solar modules in favorable future scenarios , 2017 .

[27]  Ganesh D. Sharma,et al.  Toward High‐Performance Polymer Photovoltaic Devices for Low‐Power Indoor Applications , 2017 .

[28]  S. Manzhos,et al.  All‐Rounder Low‐Cost Dopant‐Free D‐A‐D Hole‐Transporting Materials for Efficient Indoor and Outdoor Performance of Perovskite Solar Cells , 2020, Advanced Electronic Materials.

[29]  Zhe Li,et al.  Impact of Aggregation on the Photochemistry of Fullerene Films: Correlating Stability to Triplet Exciton Kinetics. , 2017, ACS applied materials & interfaces.

[30]  Valentin D. Mihailetchi,et al.  Light intensity dependence of open-circuit voltage of polymer: fullerene solar cells , 2005 .

[31]  Mario Leclerc,et al.  Recent Progress on Indoor Organic Photovoltaics: From Molecular Design to Production Scale , 2020, ACS Energy Letters.

[32]  Changduk Yang,et al.  Guest-oriented non-fullerene acceptors for ternary organic solar cells with over 16.0% and 22.7% efficiencies under one-sun and indoor light , 2020 .

[33]  O. Voznyy,et al.  Gradient-Doped Colloidal Quantum Dot Solids Enable Thermophotovoltaic Harvesting of Waste Heat , 2016 .

[34]  Ken-Tsung Wong,et al.  Device characteristics and material developments of indoor photovoltaic devices , 2020 .

[35]  Takuma Yasuda,et al.  Organic energy-harvesting devices achieving power conversion efficiencies over 20% under ambient indoor lighting , 2019, Journal of Materials Chemistry A.

[36]  Chien-Yu Chen,et al.  Perovskite Photovoltaics for Dim‐Light Applications , 2015 .

[37]  G. Konstantatos,et al.  Solution-processed solar cells based on environmentally friendly AgBiS2 nanocrystals , 2016, Nature Photonics.

[38]  Hyun Hwi Lee,et al.  All‐Day Operating Quaternary Blend Organic Photovoltaics , 2019, Advanced Functional Materials.

[39]  R. Signerski,et al.  Effect of band gap on power conversion efficiency of single-junction semiconductor photovoltaic cells under white light phosphor-based LED illumination , 2020 .

[40]  Yun‐Hi Kim,et al.  Understanding Performance of Organic Photovoltaics under Indoor and Outdoor Conditions: Effects of Chlorination of Donor Polymers. , 2020, ACS applied materials & interfaces.

[41]  Hang Yin,et al.  Designing a ternary photovoltaic cell for indoor light harvesting with a power conversion efficiency exceeding 20 , 2018 .

[42]  Peter Veelaert,et al.  A Proposal for Typical Artificial Light Sources for the Characterization of Indoor Photovoltaic Applications , 2014 .

[43]  T. Miyasaka,et al.  Stabilizing the Efficiency Beyond 20% with a Mixed Cation Perovskite Solar Cell Fabricated in Ambient Air under Controlled Humidity , 2018 .

[44]  Hang Yin,et al.  From 33% to 57% – an elevated potential of efficiency limit for indoor photovoltaics , 2020 .

[45]  A. Donald,et al.  Dependence on material choice of degradation of organic solar cells following exposure to humid air , 2015, Journal of polymer science. Part B, Polymer physics.

[46]  Zhike Liu,et al.  Europium and Acetate Co-doping Strategy for Developing Stable and Efficient CsPbI2 Br Perovskite Solar Cells. , 2019, Small.

[47]  Markus Hösel,et al.  Solar cells with one-day energy payback for the factories of the future , 2012 .

[48]  N. Park,et al.  Scalable fabrication and coating methods for perovskite solar cells and solar modules , 2020, Nature Reviews Materials.

[49]  P. Lin,et al.  Lead‐Free Double Perovskites for Perovskite Solar Cells , 2020, Solar RRL.

[50]  Yiying Wu,et al.  Monoammonium Porphyrin for Blade-Coating Stable Large-Area Perovskite Solar Cells with >18% Efficiency. , 2019, Journal of the American Chemical Society.

[51]  L. Reindl,et al.  Maximum efficiencies of indoor photovoltaic devices , 2013, IEEE Journal of Photovoltaics.

[52]  Adolf Acquaye,et al.  Perovskite solar cells: An integrated hybrid lifecycle assessment and review in comparison with other photovoltaic technologies , 2017 .

[53]  A. Arias,et al.  Evaluation of indoor photovoltaic power production under directional and diffuse lighting conditions , 2019, Solar Energy Materials and Solar Cells.

[54]  Z. Hassan,et al.  Enhancement of optical transmittance and electrical resistivity of post-annealed ITO thin films RF sputtered on Si , 2018, Applied Surface Science.

[55]  Christoph J. Brabec,et al.  Organic photovoltaics for low light applications , 2011 .

[56]  Young-Jun You,et al.  Highly Efficient Indoor Organic Photovoltaics with Spectrally Matched Fluorinated Phenylene‐Alkoxybenzothiadiazole‐Based Wide Bandgap Polymers , 2019, Advanced Functional Materials.

[57]  A. Nozik Spectroscopy and hot electron relaxation dynamics in semiconductor quantum wells and quantum dots. , 2001, Annual review of physical chemistry.

[58]  J. Luther,et al.  Third generation photovoltaics based on multiple exciton generation in quantum confined semiconductors. , 2013, Accounts of chemical research.

[59]  Bo Hou Colloidal Quantum Dots: The Artificial Building Blocks for New‐Generation Photo‐Electronics and Photochemistry , 2019, Israel Journal of Chemistry.

[60]  Ian Marius Peters,et al.  Technology and Market Perspective for Indoor Photovoltaic Cells , 2019, Joule.

[61]  Tae Geun Kim,et al.  Highly efficient flexible organic photovoltaics using quasi-amorphous ZnO/Ag/ZnO transparent electrodes for indoor applications , 2019, Journal of Power Sources.

[62]  Erin Baker,et al.  Estimating the manufacturing cost of purely organic solar cells , 2009 .

[63]  Jong Min Kim,et al.  Red green blue emissive lead sulfide quantum dots: heterogeneous synthesis and applications. , 2017, Journal of materials chemistry. C.

[64]  T. Brown,et al.  Perovskite Photovoltaics on Roll-To-Roll Coated Ultra-thin Glass as Flexible High-Efficiency Indoor Power Generators , 2020 .

[65]  K. Wong,et al.  High-Efficiency Indoor Organic Photovoltaics with a Band-Aligned Interlayer , 2020, Joule.

[66]  J. Jung,et al.  Reduced energy loss in SnO2/ZnO bilayer electron transport layer-based perovskite solar cells for achieving high efficiencies in outdoor/indoor environments , 2020 .

[67]  Takuma Yasuda,et al.  High-Performance Organic Energy-Harvesting Devices and Modules for Self-Sustainable Power Generation under Ambient Indoor Lighting Environments. , 2019, ACS Applied Materials and Interfaces.

[68]  Yong Cui,et al.  1 cm2 Organic Photovoltaic Cells for Indoor Application with over 20% Efficiency , 2019, Advanced materials.

[69]  T. Xu,et al.  On-device lead sequestration for perovskite solar cells , 2020, Nature.

[70]  I. Samuel,et al.  Efficient indoor p-i-n hybrid perovskite solar cells using low temperature solution processed NiO as hole extraction layers , 2019, Solar Energy Materials and Solar Cells.

[71]  G. Kang,et al.  High-Power and Flexible Indoor Solar Cells via Controlled Growth of Perovskite Using a Greener Antisolvent , 2020, ACS Applied Energy Materials.

[72]  Alan J. Heeger,et al.  Recombination in polymer-fullerene bulk heterojunction solar cells , 2010 .

[73]  T. Miyasaka,et al.  Perovskite Solar Cells: Can We Go Organic‐Free, Lead‐Free, and Dopant‐Free? , 2019, Advanced Energy Materials.

[74]  Hang Yin,et al.  Porphyrin-based thick-film bulk-heterojunction solar cells for indoor light harvesting , 2018 .

[75]  Matthew J. Carnie,et al.  Outstanding Indoor Performance of Perovskite Photovoltaic Cells - Effect of Device Architectures and Interlayers , 2018, Solar RRL.

[76]  M. Roeffaers,et al.  It's a trap! On the nature of localised states and charge trapping in lead halide perovskites , 2020, Materials Horizons.

[77]  Juan‐Pablo Correa‐Baena,et al.  The role of carbon-based materials in enhancing the stability of perovskite solar cells , 2020 .

[78]  Ning Li,et al.  Stability of Nonfullerene Organic Solar Cells: from Built‐in Potential and Interfacial Passivation Perspectives , 2019, Advanced Energy Materials.

[79]  F. Cacialli,et al.  Highly efficient perovskite solar cells for light harvesting under indoor illumination via solution processed SnO2/MgO composite electron transport layers , 2018, Nano Energy.

[80]  O. Inganäs,et al.  Wide-gap non-fullerene acceptor enabling high-performance organic photovoltaic cells for indoor applications , 2019, Nature Energy.

[81]  Yiwang Chen,et al.  Recent Progress on the Long‐Term Stability of Perovskite Solar Cells , 2018, Advanced science.

[82]  T. López-luke,et al.  Improving the stability of perovskite solar cells under harsh environmental conditions , 2020 .

[83]  A. Nozik,et al.  Multiexciton generation by a single photon in nanocrystals. , 2006, Nano letters.

[84]  Aram Amassian,et al.  Air-stable n-type colloidal quantum dot solids. , 2014, Nature materials.

[85]  Matthew J. Carnie,et al.  Interface Modification by Ionic Liquid: A Promising Candidate for Indoor Light Harvesting and Stability Improvement of Planar Perovskite Solar Cells , 2018, Advanced Energy Materials.

[86]  Ilke Celik,et al.  A technoeconomic analysis of perovskite solar module manufacturing with low-cost materials and techniques , 2017 .

[87]  Sean P. Dunfield,et al.  From Defects to Degradation: A Mechanistic Understanding of Degradation in Perovskite Solar Cell Devices and Modules , 2020, Advanced Energy Materials.

[88]  Zhe Li,et al.  Organic photovoltaic cells – promising indoor light harvesters for self-sustainable electronics , 2018 .

[89]  Yongfang Li,et al.  Origin of Efficient Inverted Nonfullerene Organic Solar Cells: Enhancement of Charge Extraction and Suppression of Bimolecular Recombination Enabled by Augmented Internal Electric Field. , 2017, The journal of physical chemistry letters.

[90]  C. Ballif,et al.  Instability of p–i–n perovskite solar cells under reverse bias , 2020 .

[91]  T. Kamiya,et al.  Band gap tuning of a-Si:H from 1.55 eV to 2.10 eV by intentionally promoting structural relaxation , 1998 .

[92]  James W. Evans,et al.  Organic solar cells and fully printed super-capacitors optimized for indoor light energy harvesting , 2016 .

[93]  Thuc‐Quyen Nguyen,et al.  Solution‐Processed Semitransparent Organic Photovoltaics: From Molecular Design to Device Performance , 2019, Advanced materials.

[94]  Hongxia Wang,et al.  Alkaline-earth bis(trifluoromethanesulfonimide) additives for efficient and stable perovskite solar cells , 2020 .

[95]  Christoph J. Brabec,et al.  Abnormal strong burn-in degradation of highly efficient polymer solar cells caused by spinodal donor-acceptor demixing , 2017, Nature Communications.

[96]  T. Nozaki,et al.  Silicon nanocrystal hybrid photovoltaic devices for indoor light energy harvesting , 2020, RSC advances.

[97]  Group structure and kinship in beluga whale societies , 2020, Scientific Reports.

[98]  Barbara K. Hughes,et al.  Comparing multiple exciton generation in quantum dots to impact ionization in bulk semiconductors: implications for enhancement of solar energy conversion. , 2010, Nano letters.

[99]  Y. Galagan,et al.  Highly Efficient Perovskite Solar Cells Using Non-Toxic Industry Compatible Solvent System , 2017 .

[100]  Changhwan Shin,et al.  Ultra-thick semi-crystalline photoactive donor polymer for efficient indoor organic photovoltaics , 2019, Nano Energy.

[101]  W. Que,et al.  Recent Progress of Flexible Perovskite Solar Cells , 2019, physica status solidi (RRL) – Rapid Research Letters.

[102]  A. Di Carlo,et al.  Mesoporous perovskite solar cells and the role of nanoscale compact layers for remarkable all-round high efficiency under both indoor and outdoor illumination , 2016 .

[103]  Dong Ha Kim,et al.  Unprecedentedly high indoor performance (efficiency > 34 %) of perovskite photovoltaics with controlled bromine doping , 2020 .

[104]  J. Nelson,et al.  Relationship between Fill Factor and Light Intensity in Solar Cells Based on Organic Disordered Semiconductors: The Role of Tail States , 2020 .

[105]  M. Mildner,et al.  Re-epithelialization and immune cell behaviour in an ex vivo human skin model , 2020, Scientific Reports.

[106]  Hong Lin,et al.  Flexible quintuple cation perovskite solar cells with high efficiency , 2019, Journal of Materials Chemistry A.

[107]  F. Roland,et al.  Global CO2 emissions from dry inland waters share common drivers across ecosystems , 2020, Nature Communications.

[108]  K. Ho,et al.  Performance Characterization of Dye-Sensitized Photovoltaics under Indoor Lighting. , 2017, The journal of physical chemistry letters.

[109]  F. Pelayo García de Arquer,et al.  Monolayer Perovskite Bridges Enable Strong Quantum Dot Coupling for Efficient Solar Cells , 2020 .

[110]  N. Zheng,et al.  Moisture-tolerant and high-quality α-CsPbI3 films for efficient and stable perovskite solar modules , 2020 .

[111]  Jun Liu,et al.  All-polymer indoor photovoltaics with high open-circuit voltage , 2019, Journal of Materials Chemistry A.