Nondestructive evaluation of acoustic properties of fuel cell proton-exchange membranes by vector contrast acoustic microscopy

In recent years, the interest in the research and development of "green energy" has increased dramatically, with numerous research grants and investment in the areas of wind power, solar power and fuel cell technology. We present results obtained from the evaluation of the acoustic properties of proton-exchange membranes used in hydrogen fuel cells, which relate directly to the microelastic properties of such membranes. These properties play an important role in the durability and applicability as well as the efficiency of such membranes. DuPont Nafion membranes are the most commonly used polymeric membranes in hydrogen/oxygen fuel cells and are therefore used as examples in this study. The microscope used in this non-destructive characterization study is a vector-contrast version of the scanning acoustic microscope which yields images in magnitude- and phase contrast.

[1]  M. Prasad Mapping impedance microstructures in rocks with acoustic microscopy , 2001 .

[2]  M. Seul,et al.  Preparation of surfactant multilayer films on solid substrates by deposition from organic solution , 1990 .

[3]  Wolfgang Grill,et al.  Effects of solvent vapor pressure and spin-coating speed on morphology of thin polymer blend films , 2008, SPIE Smart Structures and Materials + Nondestructive Evaluation and Health Monitoring.

[4]  C. Petrillo,et al.  Structure and acoustic properties of hydrated nafion membranes. , 2009, The journal of physical chemistry. B.

[5]  C. Quate,et al.  Acoustic microscope—scanning version , 1974 .

[6]  J. Katz,et al.  Scanning Acoustic Microscopy Study of Human Cortical and Trabecular Bone , 2001, Annals of Biomedical Engineering.

[7]  C. Laforsch,et al.  An acoustic microscopy technique reveals hidden morphological defenses in Daphnia. , 2004, Proceedings of the National Academy of Sciences of the United States of America.

[8]  G. Pharr,et al.  The elastic properties of trabecular and cortical bone tissues are similar: results from two microscopic measurement techniques. , 1999, Journal of biomechanics.

[9]  W. Grill,et al.  Determination of the velocity of sound with high resolution by ultrasonic imaging of wedge shaped objects in transmission with vector contrast , 2008, SPIE Smart Structures and Materials + Nondestructive Evaluation and Health Monitoring.

[10]  Joachim Wesner,et al.  Scanning Ultrasonic Microscopy with Phase Contrast , 1996 .

[11]  J. Weidner,et al.  Diffusion of water in Nafion 115 membranes , 2000 .

[12]  E. T. Ahmed Mohamed,et al.  Determination of sound velocity and acoustic impedance of thin chitosan films by phase-sensitive acoustic microscopy , 2010, Smart Structures and Materials + Nondestructive Evaluation and Health Monitoring.

[13]  Advances in phase‐sensitive acoustic microscopy studies of polymer blend films: annealing effects and micro‐elastic characterization of PS/PMMA blends , 2010, Journal of microscopy.

[14]  W. Grill,et al.  Characterization of polymer thin films by phase‐sensitive acoustic microscopy and atomic force microscopy: a comparative review , 2005, Journal of microscopy.

[15]  E. T. Ahmed Mohamed,et al.  Determination of mechanical properties of layered materials with vector-contrast scanning acoustic microscopy by polar diagram image representation , 2008, SPIE Smart Structures and Materials + Nondestructive Evaluation and Health Monitoring.