A review on solid oxide derived from waste shells as catalyst for biodiesel production

Abstract The waste eggs and mollusk shells are found to be the richest sources of calcium carbonate and have been utilized for various purposes after proper treatments. When calcined at a proper temperature calcium carbonate converts into CaO, which is a metal oxide. Researchers have found that the CaO prepared from the waste shells can be used as catalyst in biodiesel production process. Utilization of waste shells as a source of CaO not only gives an opportunity to use it as catalyst but also adds value to the waste generated. In this paper a brief discussion with recent development on biodiesel production using waste shell derived solid oxide as catalyst is presented.

[1]  Development of heterogeneous catalysts for transesterification of triglycerides , 2008 .

[2]  Yogesh Chandra Sharma,et al.  Application of an Efficient Nonconventional Heterogeneous Catalyst for Biodiesel Synthesis from Pongamia pinnata Oil , 2010 .

[3]  N. Chollacoop,et al.  Waste shells of mollusk and egg as biodiesel production catalysts. , 2010, Bioresource technology.

[4]  A. Gupta,et al.  Biodiesel production from Karanja oil. , 2004 .

[5]  K. Wilson,et al.  Catalysts in Production of Biodiesel: A Review , 2007 .

[6]  K. Wilson,et al.  Li–CaO catalysed tri-glyceride transesterification for biodiesel applications , 2004 .

[7]  H. Herman,et al.  Thermal Spray Processing of FGMs , 1995 .

[8]  J. Pais de Barros,et al.  The shell matrix of the freshwater mussel Unio pictorum (Paleoheterodonta, Unionoida) , 2007, The FEBS journal.

[9]  Ayato Kawashima,et al.  Development of heterogeneous base catalysts for biodiesel production. , 2008, Bioresource technology.

[10]  Ayato Kawashima,et al.  Acceleration of catalytic activity of calcium oxide for biodiesel production. , 2009, Bioresource technology.

[11]  D. Bressler,et al.  Pyrolysis of triglyceride materials for the production of renewable fuels and chemicals. , 2007, Bioresource technology.

[12]  S. Weiner,et al.  Soluble protein of the organic matrix of mollusk shells: a potential template for shell formation , 1975, Science.

[13]  S. Bhatia,et al.  Feasibility of Palm Oil as the Feedstock for Biodiesel Production via Heterogeneous Transesterification , 2008 .

[14]  D. Skala,et al.  Alumina/silica supported K2CO3 as a catalyst for biodiesel synthesis from sunflower oil. , 2009, Bioresource technology.

[15]  Daniel Chateigner,et al.  Mollusc shell microstructures and crystallographic textures , 2000 .

[16]  David L. Kaplan,et al.  Mollusc shell structures: novel design strategies for synthetic materials , 1998 .

[17]  S. Kamarudin,et al.  Preparation of Na doped SiO2 solid catalysts by the sol-gel method for the production of biodiesel from jatropha oil , 2009 .

[18]  Ben Koopman,et al.  Recycling waste oyster shells for eutrophication control , 2004 .

[19]  Xinsheng Zheng,et al.  Shrimp Shell Catalyst for Biodiesel Production , 2009 .

[20]  Hui Sun,et al.  Biodiesel Production from Transesterification of Rapeseed Oil Using KF/Eu 2O 3 as a Catalyst , 2008 .

[21]  E. H. Pryde,et al.  Variables affecting the yields of fatty esters from transesterified vegetable oils , 1984 .

[22]  Ayhan Demirbas,et al.  Biodiesel: A Realistic Fuel Alternative for Diesel Engines , 2007 .

[23]  L. C. Meher,et al.  Technical aspects of biodiesel production by transesterification—a review , 2006 .

[24]  A. Akın,et al.  Transesterification of Canola Oil to Biodiesel Using MgO Loaded with KOH as a Heterogeneous Catalyst , 2009 .

[25]  Metal-Loaded MgAl Oxides for Transesterification of Glyceryl Tributyrate and Palm Oil , 2008 .

[26]  J. Susini,et al.  Structure and composition of the nacre–prisms transition in the shell of Pinctada margaritifera (Mollusca, Bivalvia) , 2008, Analytical and bioanalytical chemistry.

[27]  K. Wada Crystal growth of molluscan shells , 1961 .

[28]  E. Torres,et al.  Biodiesel: an overview , 2005 .

[29]  A. Demirbas,et al.  Biodiesel from waste cooking oil via base-catalytic and supercritical methanol transesterification , 2009 .

[30]  D. Leung,et al.  A review on biodiesel production using catalyzed transesterification , 2010 .

[31]  Tetsuya Shishido,et al.  Preparation of egg-shell type Ni-loaded catalyst by adopting “Memory Effect” of Mg–Al hydrotalcite and its application for CH4 reforming , 2004 .

[32]  Erik Dahlquist,et al.  Biodiesel production from waste cooking oil catalyzed by TiO2-MgO mixed oxides. , 2010, Bioresource technology.

[33]  Hiroshi Miyamoto,et al.  The Carbonic Anhydrase Domain Protein Nacrein is Expressed in the Epithelial Cells of the Mantle and Acts as a Negative Regulator in Calcification in the Mollusc Pinctada fucata , 2005, Zoological science.

[34]  E. Dinjus,et al.  Green fuels - sustainable solutions for transportation , 2009 .

[35]  W. Cook Dental polyelectrolyte cements. I. Chemistry of the early stages of the setting reaction. , 1982, Biomaterials.

[36]  Yujun Wang,et al.  Calcium Ethoxide as a Solid Base Catalyst for the Transesterification of Soybean Oil to Biodiesel , 2008 .

[37]  M. L. Sanz,et al.  Egg shell as catalyst of lactose isomerisation to lactulose , 2005 .

[38]  Rainer Höfer,et al.  Sustainable Solutions for Modern Economies , 2009 .

[39]  G. Sunita,et al.  Synthesis of biodiesel over zirconia-supported isopoly and heteropoly tungstate catalysts , 2008 .

[40]  H. Sakugawa,et al.  Transesterification of soybean oil using combusted oyster shell waste as a catalyst. , 2009, Bioresource technology.

[41]  M. Fouchereau-Péron,et al.  CGRP REGULATES THE ACTIVITY OF MANTLE CELLS AND HEMOCYTES IN ABALONE PRIMARY CELL CULTURES (HALIOTIS TUBERCULATA) , 2007 .

[42]  Xinsheng Zheng,et al.  Biont shell catalyst for biodiesel production , 2009 .

[43]  A. Demirbas,et al.  Progress and recent trends in biodiesel fuels , 2009 .

[44]  M. Harith,et al.  Elemental and Ultrastructural Analysis of the Eggshell: Ca, Mg and Na Distribution During Embryonic Development via LIBS and SEM Techniques , 2006 .

[45]  M. Balat,et al.  Biodiesel Fuel from Triglycerides via Transesterification—A Review , 2009 .

[46]  T. Diamantstein,et al.  Mucopolysaccharides as a Localized Factor of Egg-shell Stability , 1965, Nature.

[47]  Maniam Gaanty Pragas,et al.  Biodiesel from Adsorbed Waste Oil on Spent Bleaching Clay using CaO as a Heterogeneous Catalyst , 2009 .

[48]  A. Heuer,et al.  Eggshell Mineralization: A Case Study of a Bioprocessing Strategy , 1992 .

[49]  Ashim Jyoti Thakur,et al.  Solid oxide derived from waste shells of Turbonilla striatula as a renewable catalyst for biodiesel , 2011 .

[50]  J. García‐Ruiz,et al.  Influence of the microstructure on the shell strength of eggs laid by hens of different ages , 2002, British poultry science.

[51]  Gaanty Pragas Maniam,et al.  Biodiesel production via transesterification of palm olein using waste mud crab (Scylla serrata) shell as a heterogeneous catalyst. , 2009, Bioresource technology.

[52]  Birol Engin,et al.  Temperature effects on egg shells investigated by XRD, IR and ESR techniques , 2006 .

[53]  Wenlei Xie,et al.  Synthesis of Biodiesel from Soybean Oil using Heterogeneous KF/ZnO Catalyst , 2006 .

[54]  Jinghong Fan,et al.  Research of Nanostructure of Bivalva Shell , 2005 .

[55]  Yun Guo,et al.  A novel solid superbase of Eu2O3/Al2O3 and its catalytic performance for the transesterification of soybean oil to biodiesel , 2007 .

[56]  Ayhan Demirbas,et al.  Progress and recent trends in biofuels , 2007 .

[57]  I. Weiss,et al.  The distribution of chitin in larval shells of the bivalve mollusk Mytilus galloprovincialis. , 2006, Journal of structural biology.

[58]  L. Ozimek,et al.  Chemical composition of chicken eggshell and shell membranes. , 2003, Poultry science.

[59]  Ali O. Al-Shyoukh,et al.  Experimental evaluation of the transesterification of waste palm oil into biodiesel. , 2002, Bioresource technology.

[60]  Baoxin Li,et al.  Application of waste eggshell as low-cost solid catalyst for biodiesel production. , 2009, Bioresource technology.

[61]  Y. Taufiq-Yap,et al.  Calcium-based mixed oxide catalysts for methanolysis of Jatropha curcas oil to biodiesel. , 2011 .

[62]  S. Wongkasemjit,et al.  An Innovative Synthesis of Calcium Zeolite Type A Catalysts from Eggshells via the Sol–Gel Process , 2011 .

[63]  Wenlei Xie,et al.  Catalytic Properties of Lithium-Doped ZnO Catalysts Used for Biodiesel Preparations , 2007 .

[64]  C. Pundir,et al.  Chemical activation of egg shell membrane for covalent immobilization of enzymes and its evaluation as inert support in urinary oxalate determination. , 2009, Talanta.

[65]  Jürgen Krahl,et al.  The Biodiesel Handbook , 2005 .

[66]  Frédéric Marin,et al.  Molluscan shell proteins , 2004 .

[67]  S. Weiner,et al.  Structure of the nacreous organic matrix of a bivalve mollusk shell examined in the hydrated state using cryo-TEM. , 2001, Journal of structural biology.

[68]  Ivan V. Kozhevnikov,et al.  Heteropoly acids as catalysts for liquid-phase esterification and transesterification , 2008 .

[69]  A. Sirivat,et al.  An innovative CaSiO3 dielectric material from eggshells by sol–gel process , 2011 .