Remoção de Cu(II), Zn(II) e Ni(II) utilizando resíduo de açaí (Euterpe oleracea Mart.) como biossorvente em solução aquosa

Resumo Abstract: Removal of transition metal ions such as Cu(II), Zn(II) and Ni(II) from aqueous solutions was investigated using açaí residual biomass (Euterpe oleracea Mart.) as a biosorbent. The characterization of sample was performed by SEM/EDS image and point of zero charge (pHPCZ). The influence of pH, contact time and initial metal concentration was evaluated. The adsorption process was studied by the models of isotherms of Langmuir and Freundlich. The pseudo first and second order kinetic models were considered to interpret the experimental data. The maximum sorption capacity determined was 15.77, 24.69 and 3.30 mg g-1, respectively for Cu(II), Zn(II) and Ni(II). The biosorption followed pseudo second order kinetic. The adsorption process of the Cu(II), Zn(II) and Ni(II) ions is favorable and spontaneous.

[1]  G. G. Lenzi,et al.  BIOSSORÇÃO DE Pb(II) POR CASCA DE URUCUM (Bixa orellana) EM SOLUÇÕES AQUOSAS: ESTUDO CINÉTICO, EQUILÍBRIO E TERMODINÂMICO , 2016 .

[2]  A. Seolatto,et al.  Adsorption study of Ni(II) and Zn(II) by activated bone char residue. , 2013, Water science and technology : a journal of the International Association on Water Pollution Research.

[3]  V. P. Lemos,et al.  Adsorção Simultânea do Cu (II), Zn (II) e Ni (II) em Argilas da Formação Solimões , 2013 .

[4]  Ying Zhang,et al.  Biosorption of Zinc from Aqueous Solution Using Chemically Treated Rice Husk , 2013, BioMed research international.

[5]  C. Tarley,et al.  Biossorção de cobre utilizando-se o mesocarpo e o endocarpo da macadâmia natural e quimicamente tratados , 2012 .

[6]  J. Filho,et al.  Modified coconut shell fibers: A green and economical sorbent for the removal of anions from aqueous solutions , 2012 .

[7]  M. Sillanpää,et al.  Utilization of agro-industrial and municipal waste materials as potential adsorbents for water treatment—A review , 2010 .

[8]  A. Sari,et al.  Kinetic and equilibrium studies of biosorption of Pb(II) and Cd(II) from aqueous solution by macrofungus (Amanita rubescens) biomass. , 2009, Journal of hazardous materials.

[9]  Jorge L. Brasil,et al.  Pecan nutshell as biosorbent to remove Cu(II), Mn(II) and Pb(II) from aqueous solutions. , 2009, Journal of hazardous materials.

[10]  W. Ngah,et al.  Removal of heavy metal ions from wastewater by chemically modified plant wastes as adsorbents: a review. , 2008, Bioresource technology.

[11]  M. F. R. Rosa,et al.  Uso da casca de coco verde como adsorbente na remoção de metais tóxicos , 2007 .

[12]  B. Zimmermann,et al.  Total oxidant scavenging capacity of Euterpe oleracea Mart. (açaí) seeds and identification of their polyphenolic compounds. , 2006, Journal of agricultural and food chemistry.

[13]  Vagner Roberto Botaro,et al.  Adsorção de metais pesados em serragem de madeira tratada com ácido cítrico , 2006 .

[14]  Yuh-Shan Ho,et al.  Citation review of Lagergren kinetic rate equation on adsorption reactions , 2004, Scientometrics.

[15]  K. Pant,et al.  Equilibrium, kinetics and thermodynamic studies for adsorption of As(III) on activated alumina , 2004 .

[16]  Y. Ho.  Removal of copper ions from aqueous solution by tree fern. , 2003, Water research.

[17]  Mônica R.M.P. Aguiar,et al.  Remoção de metais pesados de efluentes industriais por aluminossilicatos , 2002 .

[18]  Y. Ho,et al.  Pseudo-second order model for sorption processes , 1999 .

[19]  V. Weekman,et al.  Chemical Reaction Engineering , 1974 .

[20]  I. Langmuir.  THE ADSORPTION OF GASES ON PLANE SURFACES OF GLASS, MICA AND PLATINUM. , 1918 .

[21]  Rodrigo Braga Moruzzi,et al.  Remoção do ácido mefenâmico em água utilizando carvão ativado em pó, lama vermelha e oxidação com cloro , 2014 .

[22]  P. Sujatha,et al.  Effective Biosorption of Nickel(II) from Aqueous Solutions Using Trichoderma viride , 2013 .

[23]  S. Das.  Biosorption of chromium and nickel by dried biomass of cyanobacterium Oscillatoria laete-virens , 2012 .

[24]  U. Eduok,et al.  Biosorption of zinc from aqueous solution using coconut (Cocos nucifera L) coir dust , 2012 .

[25]  Luciana Melo Coelho,et al.  Uso de amêndoas de baru (Dypterix alata) para remoção de Ni(ii) em etanol combustível , 2011 .

[26]  Gabriela Huamán Pino,et al.  ASPECTOS FUNDAMENTAIS DA BIOSSORÇÃO DE METAIS NÃO FERROSOS ESTUDO DE CASO , 2011 .

[27]  M. Boniolo,et al.  Biomassa residual para remoção de íons uranilo , 2010 .

[28]  P. Aikpokpodion,et al.  EVALUATION OF TEA BIOMASS FOR NICKEL CONTAMINATED WASTE WATER TREATMENT , 2010 .

[29]  R. F. Nascimento,et al.  Remoção de metais de solução aquosa usando bagaço de caju , 2009 .

[30]  Thiago Faheina Chaves,et al.  Uso da cinza da casca do arroz (CCA) obtida da geração de energia térmica como adsorvente de Zn(II) em soluções aquosas , 2009 .

[31]  J. F. Júnior,et al.  Processo de compostagem a partir de lixo orgânico urbano e caroço de açaí. , 2002 .

[32]  Karl Pomplun,et al.  Über die Adsorption in Lösungen , 2022 .