Reactive ion etch damage on GaN and its recovery

Surface properties of GaN subjected to reactive ion etching and their impact on device performance have been investigated by transport, optical, and surface potential measurements. Different etching conditions were studied to minimize plasma-induced damage. Higher etch rates could be obtained at high powers and low pressures, with the accompanying roughening of the surface. Surface potential for the as-grown samples was found to be in the range of 0.5–0.7V using scanning Kevin probe microscopy. However, after etching at a power level of 300W, the surface potential decreased to 0.1–0.2V. An almost linear reduction was observed with increasing power. Additionally, the intensity of the near band edge photoluminescence decreased and the free carrier density increased after etching. These results suggest that the changes in the surface potential may originate from the formation of possible nitrogen vacancies and other surface oriented defects. To recover the etched surface, N2 plasma, rapid thermal annealing, ...

[1]  S. Chua,et al.  Vacancy effects on plasma-induced damage to n-type GaN , 2001 .

[2]  Hoi Wai Choi,et al.  Plasma-induced damage to n-type GaN , 2000 .

[3]  Toh-Ming Lu,et al.  Mechanisms for plasma and reactive ion etch-front roughening , 2000 .

[4]  Soo Jin Chua,et al.  Characterization of inductively coupled plasma etched surface of GaN using Cl2/BCl3 chemistry , 2001 .

[5]  Shiro Sakai,et al.  Effect of reactive ion etching on the yellow luminescence of GaN , 1999 .

[6]  M. Khan,et al.  The effects of reactive ion etching-induced damage on the characteristics of ohmic contacts to n-Type GaN , 1998 .

[7]  H. Morkoç,et al.  Transient photovoltage in GaN as measured by atomic force microscope tip , 2004 .

[8]  R. J. Shul,et al.  Dry etch damage in InN, InGaN, and InAlN , 1995 .

[9]  R. J. Shul,et al.  Depth and thermal stability of dry etch damage in GaN Schottky diodes , 1999 .

[10]  Jinn-Kong Sheu,et al.  Inductively coupled plasma etching of GaN using Cl2/Ar and Cl2/N2 gases , 1999 .

[11]  A. Kahn,et al.  Investigation of the chemistry and electronic properties of metal/gallium nitride interfaces , 1998 .

[12]  Kow-Ming Chang,et al.  The Variation of Ohmic Contacts and Surface Characteristics on p-GaN Induced by Reactive Ion Etching , 2002 .

[13]  In-Hwan Lee,et al.  Dry etch damage in n-type GaN and its recovery by treatment with an N2 plasma , 2000 .

[14]  Z. J. Yang,et al.  Etching damage and its recovery in n-GaN by reactive ion etching , 2003 .

[15]  I. Adesida,et al.  Plasma-induced damage study for n-GaN using inductively coupled plasma reactive ion etching , 2001 .

[16]  H. Temkin,et al.  Plasma etching of AlN/AlGaInN superlattices for device fabrication , 2002 .

[17]  Pierre Gibart,et al.  XPS study of Au/GaN and Pt/GaN contacts , 1997 .

[18]  J. Lee,et al.  ETCH CHARACTERISTICS OF GAN USING INDUCTIVELY COUPLED CL2/AR AND CL2/BCL3 PLASMAS , 1998 .

[19]  M. T. Kim Kinetics of etching in inductively coupled plasmas , 2004 .

[20]  A. Motayed,et al.  Electrical characteristics of AlxGa1−xN Schottky diodes prepared by a two-step surface treatment , 2004 .

[21]  J. Chyi,et al.  Reactive ion etching of GaN/InGaN using BCl3 plasma , 2003 .

[22]  H. Morkoç,et al.  Improvement of n-GaN Schottky diode rectifying characteristics using KOH etching , 2003 .

[23]  H. Grubin The physics of semiconductor devices , 1979, IEEE Journal of Quantum Electronics.

[24]  H. Morkoç,et al.  Surface band bending in as-grown and plasma-treated n-type GaN films using surface potential electric force microscopy , 2004 .

[25]  R. Cheung,et al.  Reactive ion etch-induced effects on the near-band-edge luminescence in GaN , 1999 .

[26]  C. Eddy,et al.  The influence of CH4/H2/Ar plasma etching on the conductivity of n‐type gallium nitride , 1995 .