论文信息 - Phosphine-Catalyzed Highly Enantioselective [3 + 3] Cycloaddition of Morita—Baylis—Hillman Carbonates with C,N-Cyclic Azomethine Imines.

Phosphine-Catalyzed Highly Enantioselective [3 + 3] Cycloaddition of Morita—Baylis—Hillman Carbonates with C,N-Cyclic Azomethine Imines.

The asymmetric [3 + 3] cycloaddition of C,N-cyclic azomethine imines with aryl-substituted Morita—Hillman carbonates (II, IV) is developed using a spirocyclic chiral phosphine as the catalyst.

[1] Yang Liu,et al. Phosphine-catalyzed highly enantioselective [3 + 3] cycloaddition of Morita-Baylis-Hillman carbonates with C,N-cyclic azomethine imines. , 2015, Journal of the American Chemical Society.