Microstructure and Corrosion Behavior of Laser Synthesized Cobalt Based Powder on Ti-6Al-4V

The corrosion behavior of titanium alloys when used for various dynamic offshore components has been a major concern of titanium drilling risers in deepwater energy extraction. A way of achieving specified requirement is the development of coatings suitable to protect the base material against corrosion. In this work, laser cladding technique which is known as a leading edge due to its distinctive properties and outcomes was used in synthesizing Co-based powder on titanium alloy. The processing parameters used were laser power of 900W; scan speed of 0.6 to 1.2 m/min; powderfeedrate1.0g/min;beamspotsize3mm;gasflowrate1.2L/min.The effects of cobalt addition and laser parameters on corrosion behavior of laser clad Ti6AL4V coating in 0.5M sulfuric medium were investigated using linear potentiodynamic polarization. The changes in microstructure and corrosion behavior were analyzed using scanning electron microscopy (SEM) while the X –ray diffraction (XRD) indicates the intermetallics in the coatings. Results showed that the coatings displayed good metallurgical bonding with dendritic formations between the coatings and the substrate. The anodic current density increased with lower scan speed. However, the corrosion current densities of laser-clad samples were lower than Ti6Al4V alloy.

[1]  J. Li,et al.  Corrosion behaviors of TiNi/Ti2Ni matrix coatings in the environment rich in Cl ions , 2017 .

[2]  F. Weng,et al.  Microstructures and wear properties of laser cladding Co-based composite coatings on Ti–6Al–4V , 2015 .

[3]  A. Robin,et al.  Improving corrosion resistance of Ti-6Al-4V alloy through plasma-assisted PVD deposited nitride coatings , 2014 .

[4]  P. Olubambi,et al.  Tribocorrosion characteristics of laser deposited Ti–Ni–ZrO2 composite coatings on AISI 316 stainless steel , 2014 .

[5]  Xiang Hong,et al.  Tribological properties and wear prediction model of TiC particles reinforced Ni-base alloy composite coatings , 2014 .

[6]  M. Hosseini,et al.  Corrosion resistance of Ni–Co alloy and Ni–Co/SiC nanocomposite coatings electrodeposited by sediment codeposition technique , 2014 .

[7]  M. Shukla,et al.  Scanning velocity influence on microstructure, microhardness and wear resistance performance of laser deposited Ti6Al4V/TiC composite , 2013 .

[8]  Sumsun Naher,et al.  High speed laser surface modification of Ti-6Al-4V , 2012 .

[9]  Seung‐Hwan Lee,et al.  Effect of cobalt on the corrosion resistance of low alloy steel in sulfuric acid solution , 2011 .

[10]  Bekir Sami Yilbas,et al.  Laser produced melt pool: Influence of laser intensity parameter on flow field in melt pool , 2011 .

[11]  Kangwei Zhang,et al.  Hot corrosion behaviour of a cobalt-base super-alloy K40S with and without NiCrAlYSi coating , 2011 .

[12]  Li-kai Shi,et al.  Characterization on laser clad nickel based alloy coating on pure copper , 2008 .

[13]  B. Elsener,et al.  Serum effect on the electrochemical behaviour of titanium, Ti6Al4V and Ti6Al7Nb alloys in sulphuric acid and sodium hydroxide , 2004 .

[14]  T. N. Baker Laser surface modification of titanium alloys , 2010 .