Influence of temperature elevation on the sealing performance of a potential buffer material for a high-level radioactive waste repository

Abstract The sealing performance of buffer material in a high-level waste repository depends largely upon the hydraulic conductivity, the swelling pressure, and the dissolution of organic carbon in the buffer material. Temperature effects on these properties were evaluated. The hydraulic conductivity and the swelling pressure of compacted bentonite increase with increasing temperature, but the effect of temperature elevation is not large. The dissolution of organic carbon in bentonite also increases with increasing temperature, but the resultant aqueous concentrations of organic carbon in bentonite suspensions are less than those of deep groundwater in granite. Therefore, the organic carbon dissolved from the bentonite will not cause a significant increase in the organic carbon content of deep groundwater in the repository environment. Overall, temperature effects on the sealing performance of buffer material in a waste repository is not important, if the maximum temperature is maintained below 100°C.

[1]  Yona Chen,et al.  The electron- and γ-irradiation of humic substances , 1977 .

[2]  M. Schnitzer,et al.  EVIDENCE FOR INTERLAMELLAR ADSORPTION OF ORGANIC MATTER BY CLAY IN A PODZOL SOIL , 1971 .

[3]  M. Rabenhorst,et al.  Determination of Organic and Carbonate Carbon in Calcareous Soils Using Dry Combustion , 1988 .

[4]  John A. Cherry,et al.  Contaminant Migration in Saturated Unconsolidated Geologic Deposits , 1982 .

[5]  D. Oscarson,et al.  Diffusion of Iodide in Compacted Bentonite , 1992 .

[6]  R. Gillham,et al.  Diffusion of Strontium and Chloride in Compacted Clay‐based Materials , 1987 .

[7]  Won Jin Cho,et al.  Basic Physicochemical and Mechanical Properties of Domestic Bentonite for Use as a Buffer Material in a High-level Radioactive Waste Repository , 1999 .

[8]  Prapote Boonsinsuk,et al.  Formulation of backfill material for a nuclear fuel waste disposal vault , 1986 .

[9]  Jae Owan Lee,et al.  The temperature effects on hydraulic conductivity of compacted bentonite , 1999 .

[10]  D. W. Nelson,et al.  Total Carbon, Organic Carbon, and Organic Matter , 1983, SSSA Book Series.

[11]  D. W. Nelson,et al.  Total Carbon, Organic Carbon, and Organic Matter 1 , 1982 .

[12]  D. Crerar,et al.  Migration of Radioactive Wastes: Radionuclide Mobilization by Complexing Agents , 1978, Science.

[13]  I. H. Rorison,et al.  Chemical Analysis of Ecological Materials. , 1974 .

[14]  M. Kirschbaum,et al.  The temperature dependence of soil organic matter decomposition, and the effect of global warming on soil organic C storage , 1995 .

[15]  M. M. Mortland Mechanisms of Adsorption of Nonhumic Organic Species by Clays , 1986 .

[16]  Tomasz Hueckel,et al.  Stress and pore pressure in saturated clay subjected to heat from radioactive waste: a numerical simulation , 1992 .

[17]  R. N. Yong,et al.  Temperature Dependence of Soil Water Potential , 1992 .

[18]  Jr Smith Engineered barrier development for a nuclear waste repository in basalt , 1980 .

[19]  K. Bunzl,et al.  Effect of microbial biomass reduction by gamma-irradiation on the sorption of137Cs,85Sr,139Ce,57Co,109Cd,65Zn,103Ru,95mTc and131I by soils , 1988, Radiation and environmental biophysics.

[20]  P. Huang,et al.  Interactions of soil minerals with natural organics and microbes , 1986 .